60.1.19
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Safety data sheet according to UK REACH Printing date 20.05.2025
Version number 19 (replaces version 18)
Revision: 20.05.2025
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: INDUFLEX-PU · UFI: 1WY0-D07X-Y008-Y0KA · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Spacings sealent · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Detmold, Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 Internet: www.schomburg.de · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-mail: SDB@schomburg.de · 1.4 Emergency telephone number: Poison centre Berlin (24 hours) German & English Tel: ++49 (0)30/30686700 SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS07 Skin Sens. 1 H317 May cause an allergic skin reaction. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the GB CLP regulation. · Hazard pictograms GHS07 · Signal word Warning · Hazard-determining components of labelling: diphenylmethane-4,4'-di-isocyanante m-tolylidene diisocyanate Pentamethylpiperidylsebacat 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate hardener LI (Isophorondiamine) · Hazard statements H317 May cause an allergic skin reaction. (Contd. on page 2) GB
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Trade name: INDUFLEX-PU (Contd. of page 1)
· Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves. P302+P352 IF ON SKIN: Wash with plenty of water. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Additional information: EUH204 Contains isocyanates. May produce an allergic reaction. EUH211 Warning! Hazardous respirable droplets may be formed when sprayed. Do not breathe spray or mist. · 2.3 Other hazards Not anwendbar. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Reactive Polurethane-Polymer with fillers. · Dangerous components: CAS: 77703-56-1 ELINCS: 416-600-4
4,4'-METHYLENEBIS(1-BUTYL-3-PHENYLUREA) Aquatic Chronic 4, H413
2.5-10%
CAS: 13463-67-7
titanium dioxide Carc. 2, H351
CAS: 932742-30-8
hardener LI (Isophorondiamine) Skin Sens. 1, H317; Aquatic Chronic 3, H412
<0.5%
EC number: 915-687-0
Pentamethylpiperidylsebacat Aquatic Acute 1, H400; Aquatic Chronic 1, H410; Sens. 1A, H317
<0.5% Skin
CAS: 101-68-8 diphenylmethane-4,4'-di-isocyanante EINECS: 202-966-0 Resp. Sens. 1, H334; Carc. 2, H351; STOT RE 2, H373; Index number: 615-005-00-9 Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335, EUH204 Specific concentration limits: Eye Irrit. 2; H319: C ≥ 5 % Skin Irrit. 2; H315: C ≥ 5 % Resp. Sens. 1; H334: C ≥ 0.1 % STOT SE 3; C ≥ 5 %
CAS: 4098-71-9 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate <0.5% EINECS: 223-861-6 Acute Tox. 3, H331; Resp. Sens. 1, H334; Aquatic Index number: 615-008-00-5 Chronic 2, H411; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335, EUH204 Specific concentration limits: Resp. Sens. 1; H334: C ≥ 0.5 % Skin Sens. 1; H317: C ≥ 0.5 % CAS: 26471-62-5 m-tolylidene diisocyanate EINECS: 247-722-4 Acute Tox. 2, H330; Resp. Sens. 1, H334; Carc. 2, Index number: 615-006-00-4 H351; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335; Aquatic Chronic 3, H412, EUH204 Specific concentration limit: Resp. Sens. 1; H334: C ≥ 0.1 % · Additional information For the wording of the listed hazard phrases refer to section 16.
GB
(Contd. on page 3)
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Trade name: INDUFLEX-PU (Contd. of page 2)
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist. · After skin contact If skin irritation continues, consult a doctor. · After eye contact Gently rinse the eyes under running water for at least 10 minutes with the eyelids open. If possible, remove any contact lenses and continue rinsing. Consult a doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Show the packaging or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. Use fire fighting measures that suit the environment. · For safety reasons unsuitable extinguishing agents Water with a full water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. Burst- and explosion-danger by increasing pressure. In case of fire chill the container with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Use breathing protection against the effects of fumes/dust/aerosol. Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. Wear protective clothing. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. (Contd. on page 4) GB
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Trade name: INDUFLEX-PU (Contd. of page 3)
· 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Keep away from heat and direct sunlight. Ensure good ventilation/extraction at the workplace. Prevent formation of aerosols. Keep out of the reach of children · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Store only in the original container. The Product reacts with water and CO2-Gas will be given off. In tight closed containers pressure may arise and the cover can burst. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Protect from frost. Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Store in a locked cabinet and out of the reach of children. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 101-68-8 diphenylmethane-4,4'-di-isocyanante (<0.5%) WEL Short-term value: 0.07 mg/m³ Long-term value: 0.02 mg/m³ Sen; as -NCO 4098-71-9 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate (<0.5%) WEL Short-term value: 0.07 mg/m³ Long-term value: 0.02 mg/m³ Sen; as -NCO 26471-62-5 m-tolylidene diisocyanate (<0.5%) WEL Short-term value: 0.07 mg/m³ Long-term value: 0.02 mg/m³ Sen; as -NCO · Regulatory information WEL: EH40/2020 · Ingredients with biological limit values: 101-68-8 diphenylmethane-4,4'-di-isocyanante (<0.5%) BMGV 1 µmol creatinine/mol Medium: urine Sampling time: At the end of the period od exposure Parameter: isocyanate-derived diamine (Contd. on page 5) GB
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Trade name: INDUFLEX-PU (Contd. of page 4)
4098-71-9 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate (<0.5%) BMGV 1 µmol creatinine/mol Medium: urine Sampling time: At the end of the period od exposure Parameter: isocyanate-derived diamine · Regulatory information BMGV: EH40/2020 · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. When the material is hardened on the skin, remove it carfully mechanically. · Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. · Hand protection In case of wearing synthetic protective gloves use cotton-gloves as underwear. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves Gloves made of: Natural latex, polychloroprene, nitrile rubber. (Chemical protection gloves of category 3, recognisable by the CE mark with four-digit test number). The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Not suitable are gloves made of the following materials: Leather gloves Strong gloves · Eye/face protection Suitable safety goggles in accordance with DIN EN 166. · Body protection: Protective work clothing. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Liquid · Colour: According to product specification · Smell: Odourless · Odour threshold: Not determined. · Melting point/freezing point: Not determined (Contd. on page 6) GB
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Trade name: INDUFLEX-PU (Contd. of page 5)
· Boiling point or initial boiling point and boiling range · Flammability · Lower and upper explosion limit · Lower: · Upper: · Flash point: · Decomposition temperature: · pH · Viscosity: · Kinematic viscosity · dynamic: · Solubility · Water: · Partition coefficient n-octanol/water (log value) · Steam pressure at 20 °C: · Density and/or relative density · Density at 20 °C · Relative density · Vapour density
Not determined Not applicable. Not determined. Not determined. >150 °C Not determined. Mixture is non-soluble (in water). Not determined. Not determined. Not miscible or difficult to mix Not determined. 0 hPa 1.36 g/cm³ Not determined. Not determined.
· 9.2 Other information · Appearance: · Form: Pasty · Important information on protection of health and environment, and on safety. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Change in condition · Evaporation rate Not determined. · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. (Contd. on page 7) GB
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Trade name: INDUFLEX-PU (Contd. of page 6)
· 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 77703-56-1 4,4'-METHYLENEBIS(1-BUTYL-3-PHENYLUREA) Oral LD50 >2,000 mg/kg (rats) (OECD 401) 13463-67-7 titanium dioxide Oral LD50 >5,000 mg/kg (rats) Dermal LD50 >10,000 mg/kg (rabbit) Inhalative LC50/4 h 6.8 mg/l (rats) 932742-30-8 hardener LI (Isophorondiamine) Oral LD50 >2,000 mg/kg (rats) (OECD 423) Dermal LD50 >2,000 mg/kg (rats) (OECD 402) Pentamethylpiperidylsebacat Oral LD50 3,230 mg/kg (rats) (OECD 423) Dermal LD50 >3,170 mg/kg (rats) (OECD 402) 101-68-8 diphenylmethane-4,4'-di-isocyanante Oral LD50 >2,000 mg/kg (rats) (84/449/EWG, B.1) Dermal LD50 >9,400 mg/kg (rabbit) (OECD 402) EC/LC50 (24h) >1,000 mg/l (Daphnia magna) (OECD 202) 4098-71-9 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate Oral LD50 4,814 mg/kg (rats) (OECD 401) Dermal LD50 >7,000 mg/kg (rats) (OECD 402) 26471-62-5 m-tolylidene diisocyanate Oral LD50 5,110 mg/kg (rats) (OECD 401) Dermal LD50 >9,400 mg/kg (rabbit) (OECD 402) Inhalative LC50/4 h 0.107 mg/l (rats) (OECD 403) · Primary irritant effect: Slight irritant action possible. No irritant action known. · Skin corrosion/irritation Slight irritant effect possible. · Serious eye damage/irritation Light irritate-effect is possible. Irritate-effect is possible. · Respiratory or skin sensitisation May cause an allergic skin reaction. · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed. GB
(Contd. on page 8)
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Trade name: INDUFLEX-PU (Contd. of page 7)
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 77703-56-1 4,4'-METHYLENEBIS(1-BUTYL-3-PHENYLUREA) LC50/96h >250 mg/l (zebra danio) EC50 >100 mg/l /48h (Daphnia magna) >100 mg/l /72h (Pseudokirchneriella subcapitata) 13463-67-7 titanium dioxide LC 0 48 mg/l (Leuciscus idus) EC0 30 mg/l (Daphnia magna) 24 mg/l (Pseudomonas flourescens) 932742-30-8 hardener LI (Isophorondiamine) EC 50 180.4 mg/kg /72h (Pseudokirchneriella subcapitata) (OECD 201) LC50/96h 87.2 mg/l (rainbow trout) (OECD 203) EC50 (48h) >100 mg/l (Daphnia magna) (OECD 202) EC50 180.4 mg/l /72h (Pseudokirchneriella subcapitata) (OECD 201) Pentamethylpiperidylsebacat EC 50 1.68 mg/kg /72h (Desmodesmus subspicatus) (OECD 201) LC50/96h 0.9 mg/l (zebra danio) (OECD 203) EC50 1.68 mg/l /72h (Desmodesmus subspicatus) (OECD 201) 101-68-8 diphenylmethane-4,4'-di-isocyanante LC50/96h >1,000 mg/l (zebra danio) (OECD 403) EC50 (3h) >100 mg/l (Atmungshem. von kommunalem Belebtschlamm) (OECD 209) ERC50 >1,640 mg/l (Scenedesmus subspicatus) ((72 h) OECD 201) NOEC >1,000 mg/kg (Avena sativa) (OECD 208 (14 d)) >1,000 mg/kg (Eisenia fetida) (OECD 207 (14 d)) >1,000 mg/kg (Lactuca sativa) (OECD 208 (14 d)) NOEC >10 mg/l (Daphnia magna) ((21 d) OECD 202) 4098-71-9 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate EC50 27 mg/l (Daphnia magna) >70 mg/l (Scenedesmus subspicatus) 26471-62-5 m-tolylidene diisocyanate EC50 4,300 mg/l /96h (Chlorella vulgaris) (OECD 201) 12.5 mg/l /48h (Daphnia magna) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Endocrine disrupting properties The product does not contain substances with endocrine disrupting properties. · 12.7 Other adverse effects · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. (Contd. on page 9) GB
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Trade name: INDUFLEX-PU (Contd. of page 8)
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information · 14.1 UN number or ID number · ADR, ADN, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, ADN, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards: · Marine pollutant:
No
· 14.6 Special precautions for user
Not applicable.
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. · UN "Model Regulation":
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Poisons Act · Regulated explosives precursors None of the ingredients is listed. · Regulated poisons None of the ingredients is listed. · Reportable explosives precursors None of the ingredients is listed. · Reportable poisons None of the ingredients is listed. · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. (Contd. on page 10) GB
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Trade name: INDUFLEX-PU (Contd. of page 9)
· National regulations · Technical instructions (air): · Class Share in % · I 0.4 · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H330 Fatal if inhaled. H331 Toxic if inhaled. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. H413 May cause long lasting harmful effects to aquatic life. EUH204 Contains isocyanates. May produce an allergic reaction. · Department issuing data specification sheet: Environment protection department. · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 2: Acute toxicity – Category 2 Acute Tox. 3: Acute toxicity – Category 3 Acute Tox. 4: Acute toxicity – Category 4 Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Resp. Sens. 1: Respiratory sensitisation – Category 1 Skin Sens. 1: Skin sensitisation – Category 1 Skin Sens. 1A: Skin sensitisation – Category 1A Carc. 2: Carcinogenicity – Category 2 STOT SE 3: Specific target organ toxicity (single exposure) – Category 3 STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2 Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3 Aquatic Chronic 4: Hazardous to the aquatic environment - long-term aquatic hazard – Category 4
· * Data compared to the previous version altered. GB