60.1.19
Page 1/9 SDS编号: 206446
化化化化化化术术化术 根根 GB/T 16483-2008, GB/T 17519-2013
Printing date 14.05.2025
Version number 40
Revision: 14.05.2025
1 Identification of the substance/mixture and of the company/undertaking · Product identifier · Trade name: BETOCRETE-CP360-WP · Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Concrete/Mortar admixtures · Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Detmold, Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 Internet: www.schomburg.de · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-mail: SDB@schomburg.de · Emergency telephone number: Poison centre Berlin (24 hours) German & English Tel: ++49 (0)30/30686700 2 Hazards identification · Classification of the substance or mixture GHS05 corrosion Eye Dam. 1 H318 Causes serious eye damage. GHS07 Skin Irrit. 2 H315 Causes skin irritation. STOT SE 3 H335 May cause respiratory irritation. Acute Tox. 5 H333 May be harmful if inhaled. · Emergency overview: Grey, Powder, May be harmful if inhaled. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation. · Label elements · GHS label elements The product is classified and labelled according to the Globally Harmonised System (GHS). · Hazard pictograms GHS05, GHS07 (Contd. on page 2) CN/EN
Page 2/9 SDS编号: 206446
Trade name: BETOCRETE-CP360-WP (Contd. of page 1)
· Signal word Danger · Hazard-determining components of labelling: Cement, portland, chemicals (25-50 %) calcium dihydroxide (2.5-10 %) · Hazard statements May be harmful if inhaled. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation. · Precautionary statements · Prevention Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves / eye protection / face protection. · Response IF INHALED: Call a POISON CENTER/doctor if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. · Storage Store locked up. · Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. · Other hazards Not anwendbar. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. 3 Composition/information on ingredients · Chemical characterisation: Mixtures · Description: mixture of cement and filler materials Product based on cement and mineral filler. · Dangerous components: 497-19-8 sodium carbonate Serious eye damage/irritation – Category 2A, H319; Acute Tox. 5, H303; Acute Tox. 5, H313
25-50%
65997-15-1 Cement, portland, chemicals Eye Dam. 1, H318; Skin Irrit. 2, H315; STOT SE 3, H335
91051-01-3 Fatty acids, C16-18, zinc salts Acute Tox. 5, H313; Acute Tox. 5, H333
2.5-10%
110-17-8 fumaric acid Serious eye damage/irritation – Category 2A, H319
1305-62-0 calcium dihydroxide Eye Dam. 1, H318; H313
2.5-10% Skin Irrit. 2, H315; STOT SE 3, H335; Acute Tox. 5,
68153-66-2 Kaliumstearat <2.5% Acute Tox. 5, H303 · Additional information The chromate content in the cement is less than 2 ppm, so that the classification with H317 or EUH203 is not applicable (see 1907/2006/EC, Annex XVII (47)). (Contd. on page 3) CN/EN
Page 3/9 SDS编号: 206446
Trade name: BETOCRETE-CP360-WP (Contd. of page 2)
For the wording of the listed hazard phrases refer to section 16. 4 First aid measures · Description of first aid measures · General information Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact In case of contact with skin, remove mechanically, wash thoroughly with plenty of soap and water. Instantly wash with water and soap and rinse thoroughly. · After eye contact Gently rinse the eyes under running water for at least 10 minutes with the eyelids open. If possible, remove any contact lenses and continue rinsing. Consult a doctor. · After swallowing Show the packaging or the label to the doctor. Drink copious amounts of water. Avert vomiting. Instantly call for doctor. · Most important symptoms and effects, both acute and delayed No further relevant information available. · Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Firefighting measures · Extinguishing media · Suitable extinguishing agents Product is not inflammable. Use fire fighting measures that suit the environment. · Special hazards arising from the substance or mixture No further relevant information available. · Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. 6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Avoid eye- and skin contact. Ensure adequate ventilation Avoid causing dust. Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. Wear protective clothing. · Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. (Contd. on page 4) CN/EN
Page 4/9 SDS编号: 206446
Trade name: BETOCRETE-CP360-WP (Contd. of page 3)
· Methods and material for containment and cleaning up: Ensure adequate ventilation. Pick up the product mechanically, avoid dust formation. · Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. 7 Handling and storage · Precautions for safe handling Use only in well ventilated areas. Keep away from heat and direct sunlight. Prevent formation of dust. Keep out of the reach of children · Information about protection against explosions and fires: No special measures required. · Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Do not leave open containers. Store only in the original container. Store in a dry place. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Protect from humidity and keep away from water. Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Store in a locked cabinet and out of the reach of children. · Specific end use(s) No further relevant information available. *
8 Exposure controls/personal protection · Control parameters · Components with critical values that require monitoring at the workplace: 497-19-8 sodium carbonate (25-50%) OEL (China) Short-term value: 6 mg/m³ Long-term value: 3 mg/m³ 1305-62-0 calcium dihydroxide (2.5-10%) PEL (Taiwan) Long-term value: 5 mg/m³ IOELV (European Union) Short-term value: 4 mg/m³ Long-term value: 1 mg/m³ Respirable fraction · Regulatory information OEL (China): 工工场工工工工工场场工工工场 PEL (Taiwan): 勞工工勞勞工勞勞勞勞勞勞 IOELV (European Union): (EU) 2019/1831 · Additional information: The lists that were valid during the compilation were used as basis. · Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. (Contd. on page 5) CN/EN
Page 5/9 SDS编号: 206446
Trade name: BETOCRETE-CP360-WP (Contd. of page 4)
Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Vacuum clean contaminated clothing. Do not blow or brush off contamination. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: Dust mask. Filter P2. In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. · Protection of hands: In case of wearing synthetic protective gloves use cotton-gloves as underwear. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves Gloves made of: Natural latex, polychloroprene, nitrile rubber. (Chemical protection gloves of category 3, recognisable by the CE mark with four-digit test number). The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Not suitable are gloves made of the following materials: Leather gloves Strong gloves · Eye protection: In case of dust formation or risk of splashing: safety goggles Suitable safety goggles in accordance with DIN EN 166. · Body protection: Protective work clothing. 9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Physical state Solid material. · Colour: Grey · Smell: like cement · Odour threshold: Not determined. · Melting point/freezing point: Not determined · Initial boiling point and boiling range: not apply · Inflammability (solid, gaseous) Not determined. · Critical values for explosion: · Lower: Not determined. · Upper: Not determined. · Flash point: Not applicable · Decomposition temperature: Not determined. · pH-value at 20 °C: 11 (1%) · Viscosity: · kinematic: Not applicable. · dynamic: Not applicable. (Contd. on page 6) CN/EN
Page 6/9 SDS编号: 206446
Trade name: BETOCRETE-CP360-WP (Contd. of page 5)
· Solubility in / Miscibility with · Water: · Partition coefficient: n-octanol/water: · Steam pressure: · Vapour pressure: · Density · Relative density · Settled apparent density · Vapour density · Particle characteristics
miscible Not determined. Not applicable. bulk density Not determined. 0.78 kg/dm³ Not applicable. Not determined.
· Other information · Appearance: · Form: Powder · Important information on protection of health and environment, and on safety. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Change in condition · Evaporation rate Not applicable.
10 Stability and reactivity · Reactivity No further relevant information available. · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions No dangerous reactions known · Conditions to avoid No further relevant information available. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: No dangerous decomposition products known 11 Toxicological information · Information on toxicological effects · Acute toxicity · LD/LC50 values that are relevant for classification: 497-19-8 sodium carbonate Oral LD50 2,800 mg/kg (rats) Dermal LD50 >2,000 mg/kg (Kan) (EPA 16 CFR 1500.40) Inhalative LC50 2,300 mg/m³ /2h (rats) 91051-01-3 Fatty acids, C16-18, zinc salts Oral LD50 >5,000 mg/kg (rats) (OECD 401 (analogy)) Dermal LD50 >2,000 mg/kg (Kan) Inhalative LC50/4 h >50 mg/l (rats) 110-17-8 fumaric acid Oral LD50 7,200-15,800 mg/kg (rats) Dermal LD50 20,000 mg/kg (rabbit) 1305-62-0 calcium dihydroxide Oral LD50 7,340 mg/kg (rats) (Contd. on page 7) CN/EN
Page 7/9 SDS编号: 206446
Trade name: BETOCRETE-CP360-WP (Contd. of page 6)
Dermal
LD50
>2,500 mg/kg (Kan) (OECD 402)
68153-66-2 Kaliumstearat Oral LD50 >2,000 mg/kg (rats) · Primary irritant effect: · Skin corrosion/irritation Irritant for skin and mucous membranes. The product has an irritate-effect. · Serious eye damage/irritation Strong irritant with the danger of severe eye injury. Irritant effect. · Respiratory or skin sensitisation No sensitizing effect known. · Additional toxicological information: The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for Preparations as issued in the latest version: Irritant 12 Ecological information · Toxicity · Aquatic toxicity: 497-19-8 sodium carbonate LC50/96h 300 mg/l (Lepomis macrochirus) EC50 (48h) 200-227 mg/l (water flea (Ceriodaphnia spec) 91051-01-3 Fatty acids, C16-18, zinc salts LC50/96h >10,000 mg/l (zebra danio) (67/548/EWG) EC10 3.31 mg/l /72h (Pseudokirchneriella subcapitata) (OECD 201) EC50 (48h) >100 mg/l (Daphnia magna) (OECD 202) EC50 >100 mg/l /72h (Pseudokirchneriella subcapitata) (OECD 201) NOEC (static) 1,560 mg/l /0.5h (Photobacterium phosphoreum) (DIN 38412 T 34) 19.3 mg/l /72h (Pseudokirchneriella subcapitata) (OECD 201) 1305-62-0 calcium dihydroxide EC50 (48h) 49.1 mg/l (Daphnia magna) 68153-66-2 Kaliumstearat LC50 >100 mg/l (fish toxicity) · Persistence and degradability No further relevant information available. · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. CN/EN
(Contd. on page 8)
Page 8/9 SDS编号: 206446
Trade name: BETOCRETE-CP360-WP (Contd. of page 7)
13 Disposal considerations · Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleaning agent: Water, if necessary with cleaning agent. *
14 Transport information · UN-Number · ADR, ADN, IMDG, IATA
Void
· UN proper shipping name · ADR, ADN, IMDG, IATA
· Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· Packing group · ADR, IMDG, IATA
· Environmental hazards: · Marine pollutant:
No
· Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable.
*
· Special precautions for user
Not applicable.
· UN "Model Regulation":
15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture · Regulations on the Control over Safety of Hazardous Chemicals · Inventory of Hazardous Chemicals None of the ingredients is listed. · Regulations for Environmental Management on the First Import of Chemicals and the Import and Export of Toxic Chemicals · Chinese Chemical Inventory of Existing Chemical Substances 497-19-8 sodium carbonate 65997-15-1 Cement, portland, chemicals 14808-60-7 Silicon dioxide (SiO2) 91051-01-3 Fatty acids, C16-18, zinc salts 110-17-8 fumaric acid 1305-62-0 calcium dihydroxide 68153-66-2 Kaliumstearat (Contd. on page 9) CN/EN
Page 9/9 SDS编号: 206446
Trade name: BETOCRETE-CP360-WP (Contd. of page 8)
9084-06-4 Sodium Salt of the Naftalensulphonic Acid, Polimer with Formalhyde 532-32-1 sodium benzoate 67701-03-5 Fatty acids, C16-18 · GHS label elements The product is classified and labelled according to the Globally Harmonised System (GHS). · Hazard pictograms GHS05, GHS07 · Signal word Danger · Hazard-determining components of labelling: Cement, portland, chemicals (25-50 %) calcium dihydroxide (2.5-10 %) · Hazard statements May be harmful if inhaled. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation. · Precautionary statements · Prevention Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves / eye protection / face protection. · Response IF INHALED: Call a POISON CENTER/doctor if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. · Storage Store locked up. · Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Department issuing data specification sheet: Department EHS (Environment-Health-Safety) · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 5: Acute toxicity – Category 5 Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Serious eye damage/irritation – Category 2A: Serious eye damage/eye irritation – Category 2A STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
· * Data compared to the previous version altered. CN/EN