61.0.6
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Safety data sheet according to UK REACH Printing date 25.07.2025 *
Version number 28
Revision: 25.07.2025
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASO-R005 · UFI: 6DME-QK73-700Y-0KH7 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Cleaning agent/ Cleaner · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Detmold, Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 Internet: www.schomburg.de · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-mail: SDB@schomburg.de · 1.4 Emergency telephone number: Poison centre Berlin (24 hours) German & English Tel: ++49 (0)30/30686700
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS05 corrosion Met. Corr.1 H290 May be corrosive to metals. Skin Corr. 1B H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage. GHS07 Acute Tox. 4 H302 Harmful if swallowed. Acute Tox. 4 H332 Harmful if inhaled. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the GB CLP regulation. · Hazard pictograms GHS05, GHS07 · Signal word Danger (Contd. on page 2) GB
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Safety data sheet according to UK REACH Printing date 25.07.2025
Trade name: ASO-R005 (Contd. of page 1)
· Hazard-determining components of labelling: formic acid · Hazard statements H290 May be corrosive to metals. H302+H332 Harmful if swallowed or if inhaled. H314 Causes severe skin burns and eye damage. · Precautionary statements P260 Do not breathe dusts or mists. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · Additional information: EUH071 Corrosive to the respiratory tract. · 2.3 Other hazards not applicable · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Aqueous solution of an organic acid. · Dangerous components: CAS: 64-18-6 formic acid 25-50% EINECS: 200-579-1 Flam. Liq. 3, H226; Acute Tox. 3, H331; Met. Corr.1, Index number: 607-001-00-0 H290; Skin Corr. 1A, H314; Eye Dam. 1, H318; Acute Tox. 4, H302, EUH071 ATE: LD50 oral: 500 mg/kg LC50/4 h inhalative: 7.4 mg/l Specific concentration limits: Flam. Liq. 3; H226: C ≥ 85 % Skin Corr. 1A; H314: C ≥ 90 % Skin Corr. 1B; H314: 10 % ≤ C < 90 % Skin Irrit. 2; H315: 2 % ≤ C < 10 % Eye Dam. 1; H318: C ≥ 10 % Eye Irrit. 2; H319: 2 % ≤ C < 10 % · Additional information For the wording of the listed hazard phrases refer to section 16. *
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Instantly remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). (Contd. on page 3) GB
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Trade name: ASO-R005 (Contd. of page 2)
Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact Instantly wash with water and soap and rinse thoroughly. Immediate medical treatment necessary. Failure to treat burns can prevent wounds from healing. Change immediately contaminated clothes. · After eye contact Gently rinse the eyes under running water for at least 10 minutes with the eyelids open. If possible, remove any contact lenses and continue rinsing. Consult a doctor. · After swallowing Show the packaging or the label to the doctor. Drink copious amounts of water. Avert vomiting. Instantly call for doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. *
SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. Use fire fighting measures that suit the environment. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. · 5.3 Advice for firefighters · Protective equipment: Wear PVC-boots, protective gloves and clothing. Wear self-contained breathing apparatus. · Additional information Collect contaminated fire fighting water separately. It must not enter drains. Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. Burst- and explosion-danger by increasing pressure. In case of fire chill the container with water spray.
SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. Wear protective clothing. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. · 6.3 Methods and material for containment and cleaning up: Use neutralising agent. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. GB
(Contd. on page 4)
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Trade name: ASO-R005 (Contd. of page 3)
SECTION 7: Handling and storage · 7.1 Precautions for safe handling Keep away from heat and direct sunlight. Ensure good ventilation/extraction at the workplace. Prevent formation of aerosols. Keep out of the reach of children · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Store only in the original container. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Protect from frost. Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Store in a locked cabinet and out of the reach of children. · 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 64-18-6 formic acid (25-50%) WEL Long-term value: 9.6 mg/m³, 5 ppm · Regulatory information WEL: EH40/2020 · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Do not inhale gases / fumes / aerosols. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. · Hand protection Hand Protection: Nitril-rubber-latex-gloves. Only use chemical-protective gloves with CE-labelling of category III. In case of wearing synthetic protective gloves use cotton-gloves as underwear. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. (Contd. on page 5) GB
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Trade name: ASO-R005 (Contd. of page 4)
· Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Not suitable are gloves made of the following materials: Leather gloves. Gloves made of thick fabric. · Eye/face protection Suitable safety goggles in accordance with DIN EN 166. In case of splashing use protecting basket-glasses. · Body protection: Acid resistant protective clothing Apron Protective work clothing. *
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Liquid · Colour: Colourless · Smell: Pungent · Odour threshold: Not determined. · Melting point/freezing point: -13 °C · Boiling point or initial boiling point and boiling range >100 °C (64-18-6 formic acid) · Flammability Not applicable. · Lower and upper explosion limit · Lower: 14.9 Vol % (64-18-6 formic acid) · Upper: 47.6 Vol % (64-18-6 formic acid) · Flash point: 62 °C (64-18-6 formic acid) · Auto-ignition temperature: >500 °C (64-18-6 formic acid) · Decomposition temperature: Not determined. · pH at 20 °C 2.2 · Viscosity: · Kinematic viscosity Not determined. · dynamic at 20 °C: 1.6 mPas · Solubility · Water: miscible · Partition coefficient n-octanol/water (log value) Not determined. · Steam pressure at 20 °C: 21 hPa (64-18-6 formic acid) · Density and/or relative density · Density at 20 °C 1.2 g/cm³ · Relative density 1.6 · Vapour density Not determined. · 9.2 Other information · Appearance: · Form: Fluid · Important information on protection of health and environment, and on safety. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Solvent separation test · Solids content: >20-60 % (Contd. on page 6) GB
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Trade name: ASO-R005 (Contd. of page 5)
· Change in condition · Evaporation rate · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Not determined.
Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void May be corrosive to metals. Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known *
SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Harmful if swallowed or if inhaled. · LD/LC50 values that are relevant for classification: 64-18-6 formic acid Oral LD50 500 mg/kg (ATE) 730 mg/kg (rats) (OECD 401) Inhalative LC50/4 h 7.4 mg/l (ATE) 7.85 mg/l (rats) (OECD 403) · Primary irritant effect: · Skin corrosion/irritation Causes severe skin burns and eye damage. · Serious eye damage/irritation Causes serious eye damage. · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed. GB
(Contd. on page 7)
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Trade name: ASO-R005 (Contd. of page 6)
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 64-18-6 formic acid LC50/96h 1,720 mg/l (fish toxicity) EC/LC50 (48h) 365 mg/l (Daphnia magna) (OECD 202) EC/LC50 (17h) 46.7 mg/l (bacterial toxicity) ERC50 1,240 mg/l /72h (Pseudokirchneriella subcapitata) LOEC ≥100 mg/l /21d (Daphnia magna) (OECD 211) NOEC ≥100 mg/l /21d (Daphnia magna) (OECD 211) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Endocrine disrupting properties The product does not contain substances with endocrine disrupting properties. · 12.7 Other adverse effects · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. Must not reach sewage water or drainage ditch undiluted or unneutralised. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleaning agent: Water, if necessary with cleaning agent. SECTION 14: Transport information · 14.1 UN number or ID number · ADR, IMDG, IATA
UN3412
· 14.2 UN proper shipping name · ADR · IMDG, IATA
3412 FORMIC ACID FORMIC ACID
· 14.3 Transport hazard class(es) · ADR, IMDG, IATA
· Class
8 Corrosive substances. (Contd. on page 8) GB
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Trade name: ASO-R005 (Contd. of page 7)
· Label
8
· 14.4 Packing group · ADR, IMDG, IATA
II
· 14.5 Environmental hazards:
Not applicable.
· 14.6 Special precautions for user · Kemler Number: · EMS Number: · Segregation groups · Stowage Category · Stowage Code
Warning: Corrosive substances. 80 F-A,S-B (SGG1) Acids A SW2 Clear of living quarters.
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. · Transport/Additional information: · ADR · Limited quantities (LQ) · Excepted quantities (EQ) · Transport category · IMDG · Limited quantities (LQ) · Excepted quantities (EQ)
· UN "Model Regulation":
1L Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml 2 1L Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml UN 3412 FORMIC ACID, 8, II
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Poisons Act · Regulated explosives precursors None of the ingredients is listed. · Regulated poisons None of the ingredients is listed. · Reportable explosives precursors None of the ingredients is listed. · Reportable poisons 64-18-6 formic acid: 25% · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Reasons for alterations None · Relevant phrases H226 Flammable liquid and vapour. (Contd. on page 9) GB
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Trade name: ASO-R005 (Contd. of page 8)
H290 May be corrosive to metals. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H318 Causes serious eye damage. H319 Causes serious eye irritation. H331 Toxic if inhaled. EUH071 Corrosive to the respiratory tract. · Department issuing data specification sheet: Environment protection department. · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative ATE: Acute toxicity estimate values Flam. Liq. 3: Flammable liquids – Category 3 Met. Corr.1: Corrosive to metals – Category 1 Acute Tox. 4: Acute toxicity – Category 4 Acute Tox. 3: Acute toxicity – Category 3 Skin Corr. 1A: Skin corrosion/irritation – Category 1A Skin Corr. 1B: Skin corrosion/irritation – Category 1B Eye Dam. 1: Serious eye damage/eye irritation – Category 1
· * Data compared to the previous version altered. GB