44.0
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 12.01.2017 *
Version number 24
Revision: 12.01.2017
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: BETOCRETE-CP 350 CI · Article number: 206445 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Concrete/Mortar admixtures · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: guido.herfort@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS05 corrosion Eye Dam. 1 H318 Causes serious eye damage. GHS07 Skin Irrit. 2 H315 Causes skin irritation. STOT SE 3 H335 May cause respiratory irritation. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS05, GHS07 · Signal word Danger · Hazard-determining components of labelling: Cement, portland, chemicals calcium dihydroxide · Hazard statements H315 Causes skin irritation. H318 Causes serious eye damage. H335 May cause respiratory irritation. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves / eye protection / face protection. (Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 12.01.2017
Trade name: BETOCRETE-CP 350 CI (Contd. of page 1)
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: mixture of cement and filler materials · Dangerous components: CAS: 65997-15-1 Cement, portland, chemicals EINECS: 266-043-4 Eye Dam. 1, H318; Skin Irrit. 2, H315; STOT SE 3, H335
25-50%
CAS: 497-19-8 sodium carbonate EINECS: 207-838-8 Eye Irrit. 2, H319 CAS: 1305-62-0 calcium dihydroxide EINECS: 215-137-3 Eye Dam. 1, H318;
25-50% 2.5-10% Skin Irrit. 2, H315; STOT SE 3, H335
CAS: 77-92-9 1,2,3-Propanetricarboxylic acid, 2-hydroxyEINECS: 201-069-1 Eye Irrit. 2, H319
< 2.5%
CAS: 532-32-1 sodium benzoate EINECS: 208-534-8 Eye Irrit. 2, H319 · Additional information For the wording of the listed hazard phrases refer to section 16.
< 1%
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact Instantly wash with water and soap and rinse thoroughly. · After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Show the pack or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents Product is not inflammable. · 5.2 Special hazards arising from the substance or mixture No further relevant information available. (Contd. on page 3) GB
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Trade name: BETOCRETE-CP 350 CI (Contd. of page 2)
· 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Wear protective clothing. Avoid eye- and skin contact. Ensure adequate ventilation Avoid causing dust. Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Ensure adequate ventilation. Pick up the product mechanically, avoid dust formation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Use only in well ventilated areas. Keep away from children. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Do not leave open containers. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Protect from humidity and keep away from water. Keep container tightly sealed. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 65997-15-1 Cement, portland, chemicals (25-50%) WEL Long-term value: 10* 4** mg/m³ *inhalable dust **respirable dust 1305-62-0 calcium dihydroxide (2.5-10%) WEL Long-term value: 5 mg/m³ · Additional information: The lists that were valid during the compilation were used as basis. (Contd. on page 4) GB
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Trade name: BETOCRETE-CP 350 CI (Contd. of page 3)
· 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Vacuum clean contaminated clothing. Do not blow or brush off contamination. Avoid contact with the eyes and skin. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: Use respiratory protective equipment at formation of dust. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing. *
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Powder Colour: Grey · Smell: like cement · Change in condition Melting point/freezing point: Not determined Initial boiling point and boiling range: not apply · Flash point:
Not applicable
· Self-inflammability:
Product is not selfigniting.
· Explosive properties:
Product is not explosive.
· Density
not determine
· Settled apparent density
1.08 kg/m³
· Solubility in / Miscibility with Water:
miscible
· Viscosity: dynamic: kinematic: · 9.2 Other information
Not applicable. Not applicable. No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. (Contd. on page 5) GB
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Trade name: BETOCRETE-CP 350 CI (Contd. of page 4)
· 10.6 Hazardous decomposition products: No dangerous decomposition products known *
SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 497-19-8 sodium carbonate Oral LD50 2800 mg/kg (rats) Dermal LD50 >2000 mg/kg (rats) Inhalative LC50 2h / 2.3 mg/l (rats) 1305-62-0 calcium dihydroxide Oral LD50 7340 mg/kg (rats) 77-92-9 1,2,3-Propanetricarboxylic acid, 2-hydroxyOral LD50 11700 mg/kg (rats) LD50 5040 mg/kg (Maus) Inhalative LC 50 883 mg/l (rats) · Primary irritant effect: · Skin corrosion/irritation Causes skin irritation. · Serious eye damage/irritation Causes serious eye damage. · Respiratory or skin sensitisation Based on available data, the classification criteria are not met. · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure May cause respiratory irritation. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met.
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 497-19-8 sodium carbonate LC50/96h 300 mg/l (Lepomis macrochius) EC50 24h / 347 mg/l (Daphnia magna) 77-92-9 1,2,3-Propanetricarboxylic acid, 2-hydroxyLC50/96h 440 - 706 mg/l (haltoxicitás (Goldorfe, 96h)) EC0 >10000 mg/l (bacterial toxicity) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. (Contd. on page 6) GB
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Trade name: BETOCRETE-CP 350 CI (Contd. of page 5)
· vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. *
SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Smaller quantities can be disposed with household garbage. · European waste catalogue 17 00 00 CONSTRUCTION AND DEMOLITION WASTES (INCLUDING EXCAVATED SOIL FROM CONTAMINATED SITES) 17 01 00 concrete, bricks, tiles and ceramics 17 01 07 mixtures of concrete, bricks, tiles and ceramics other than those mentioned in 17 01 06 ( 3 ) For the purpose of this entry, transition metals are: scandium, vanadium, manganese, cobalt, copper, yttrium, niobium, hafnium, tungsten, titanium · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations.
SECTION 14: Transport information · 14.1 UN-Number · ADR, ADN, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, ADN, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards: · Marine pollutant:
No
· 14.6 Special precautions for user
Not applicable.
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · UN "Model Regulation":
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · National regulations · Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. The classification based on german instructions. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. GB
(Contd. on page 7)
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Trade name: BETOCRETE-CP 350 CI (Contd. of page 6)
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H315 Causes skin irritation. H318 Causes serious eye damage. H319 Causes serious eye irritation. H335 May cause respiratory irritation. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
· * Data compared to the previous version altered. GB