50.0.4
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 24.02.2020 *
Version number 14
Revision: 24.02.2020
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASODUR-LE (B-Komponente) · Article number: 205797B · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Epoxy coating · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: SDB@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS05 corrosion Skin Corr. 1A Eye Dam. 1
H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage.
GHS09 environment Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. GHS07 Acute Tox. 4 Acute Tox. 4 Skin Sens. 1
H302 Harmful if swallowed. H332 Harmful if inhaled. H317 May cause an allergic skin reaction.
· 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS05, GHS07, GHS09 (Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 24.02.2020
Trade name: ASODUR-LE (B-Komponente) (Contd. of page 1)
· Signal word Danger
· Hazard-determining components of labelling: m-phenylenebis(methylamine) 2,2,4-trimethylhexan-1,6-diamine phenol 3-aminomethyl-3,5,5-trimethylcyclohexylamine Phenol, methylstyrenated · Hazard statements H302+H332 Harmful if swallowed or if inhaled. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. · Precautionary statements P260 Do not breathe dusts or mists. P273 Avoid release to the environment. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Hardener, aminformulation · Dangerous components: CAS: 1477-55-0 m-phenylenebis(methylamine) 25-50% EINECS: 216-032-5 Skin Corr. 1B, H314; Acute Tox. 4, H302; Acute Tox. 4, H332; Skin Sens. 1, H317; Aquatic Chronic 3, H412 CAS: 61788-44-1 phenol EINECS: 262-975-0 Aquatic Chronic 2, H411;
25-50% Skin Irrit. 2, H315; Skin Sens. 1, H317
CAS: 25513-64-8 2,2,4-trimethylhexan-1,6-diamine EINECS: 247-063-2 Skin Corr. 1A, H314; Eye Dam. 1, H318; Sens. 1, H317; Aquatic Chronic 3, H412
10-25% Acute Tox. 4, H302; Skin
CAS: 68512-30-1 Phenol, methylstyrenated EINECS: 270-966-8 Acute Tox. 4, H312; Skin Irrit. 2, H315; Skin Sens. 1, H317; Aquatic Chronic 3, H412
10-25%
CAS: 69-72-7 Salicylic acid EINECS: 200-712-3 Eye Dam. 1, H318;
2.5-10% Acute Tox. 4, H302
CAS: 2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine 2.5-10% EINECS: 220-666-8 Skin Corr. 1B, H314; Eye Dam. 1, H318; Acute Tox. 4, H302; Acute Tox. 4, H312; Skin Sens. 1, H317; Aquatic Chronic 3, H412
(Contd. on page 3) GB
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Trade name: ASODUR-LE (B-Komponente)
· Additional information For the wording of the listed hazard phrases refer to section 16. *
(Contd. of page 2)
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. Instantly remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. In case of unconsciousness bring patient into stable side position for transport. Supply fresh air and call for doctor for safety reasons. · After skin contact If symptoms appearance, call the doctor. Instantly wash with water and soap and rinse thoroughly. Wash with water and soap. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. · After swallowing Do not induce vomiting; instantly call for medical help. Instantly call for doctor. Drink copious amounts of water and provide fresh air. Instantly call for doctor. Show the pack or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available.
SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · For safety reasons unsuitable extinguishing agents Water with a full water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. Burst- and explosion-danger by increasing pressure. In case of fire chill the container with water spray. GB
(Contd. on page 4)
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Trade name: ASODUR-LE (B-Komponente) (Contd. of page 3)
SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Cleaning may be carried out only with skilled persons. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding, inflammable material (sand, diatomite, acid binders, universal binder). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. *
SECTION 7: Handling and storage · 7.1 Precautions for safe handling Work with fresh air supply, keep doors and windows open. Avoid splashes. Do not spray on hot surfaces. Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Keep away from children. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Do not leave open containers. · Information about storage in one common storage facility: Store away from foodstuffs. Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. Store in a locked cabinet and out of the reach of children. · 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures Clean skin only with cleaning agent especially for epoxy resin. Don't use solvent for skin cleaning! Clean clothes which are contaminate with epoxi resin before unsing again. The usual precautionary measures should be adhered to in handling the chemicals. Keep away from foodstuffs, beverages and food.
(Contd. on page 5) GB
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Trade name: ASODUR-LE (B-Komponente) (Contd. of page 4)
Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: Filter A/P2. In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. · Protection of hands: Nitrile coated protective gloves (category III, material strength: 0,425 mm break through time > 480 Min (eg. Ansell Chemical Protective gloves Sol-Vex® 37-900) Do not reuse one-way-gloves Hand Protection: Nitril-rubber-latex-gloves. In case of wearing synthetic protective gloves use cotton-gloves as underwear. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Not suitable are gloves made of the following materials: Leather gloves Strong gloves · Eye protection: Tightly sealed safety glasses. In case of splashing use protecting basket-glasses. · Body protection: Acid resistant protective clothing Alkaline resistant protective clothing Apron Use an Overall of heavy cotton or non-returnable Tyvek/Saranex 23 P vleece. Contaminated protection clothes must be cleaned carefully before reuse. *
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Fluid Colour: Yellowish · Smell: Amine-like · Odour threshold: Not determined. · pH-value:
Not determined. (Contd. on page 6) GB
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Trade name: ASODUR-LE (B-Komponente) (Contd. of page 5)
· Change in condition Melting point/freezing point: Not determined Initial boiling point and boiling range: >200 °C
· Flash point:
>100 °C
· Inflammability (solid, gaseous)
Not applicable.
· Decomposition temperature:
Not determined.
· Self-inflammability:
Product is not selfigniting.
· Explosive properties:
Product is not explosive.
· Critical values for explosion: Lower: Upper:
Not determined. Not determined.
· Steam pressure:
· Density at 20 °C · Relative density · Vapour density · Evaporation rate
1.06 g/cm³ (ISO 2811-2) Not determined. Not determined. Not determined.
· Solubility in / Miscibility with Water:
Not miscible or difficult to mix
· Partition coefficient: n-octanol/water:
· Viscosity: dynamic at 20 °C: kinematic: · 9.2 Other information
399 mPas (ISO 3219) Not determined. No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions Exothermic reaction · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: Acids Strong oxidationresorts · 10.6 Hazardous decomposition products: In case of fire: Poisonous gases/vapours Corrosive gases/vapours
SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Harmful if swallowed or if inhaled. (Contd. on page 7) GB
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Trade name: ASODUR-LE (B-Komponente) (Contd. of page 6)
· LD/LC50 values that are relevant for classification: 1477-55-0 m-phenylenebis(methylamine) Oral LD50 930 mg/kg (rats) Dermal LD50 >3,100 mg/kg (rabbit) (OECD 402) 61788-44-1 phenol Oral LD50 Dermal LD50
>2,000 mg/kg (rats) >2,000 mg/kg (rats)
25513-64-8 2,2,4-trimethylhexan-1,6-diamine Oral LD50 910 mg/kg (rats) EC/LC50 (24h) 31.5 mg/l (Daphnia magna) 68512-30-1 Phenol, methylstyrenated Oral LD50 3,600 mg/kg (rabbit) >2,000 mg/kg (rats) Dermal LD50 2,000 mg/kg (rabbit) >2,000 mg/kg (rats) 69-72-7 Salicylic acid Oral LD50 891 mg/kg (rats) Dermal LD50 >2,000 mg/kg (rats) 2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine Oral LD50 1,030 mg/kg (rats) (OECD 401) Dermal LD50 1,840 mg/kg (rabbit) >2,000 mg/kg (rats) · Primary irritant effect: · Skin corrosion/irritation Causes severe skin burns and eye damage. · Serious eye damage/irritation Causes serious eye damage. · Respiratory or skin sensitisation May cause an allergic skin reaction. · Additional toxicological information: Sensitizing · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. *
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 1477-55-0 m-phenylenebis(methylamine) LC50/96h 87.6 mg/l (fish toxicity) >100 mg/l (rainbow trout)
(Contd. on page 8) GB
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Trade name: ASODUR-LE (B-Komponente) (Contd. of page 7)
>100 mg/l (Zebrafisch) EC50 (48h) 15.2 mg/l (Daphnia magna) EC/LC50 (72h) 20.3 mg/l (algae toxicity) 61788-44-1 phenol EC50 (48h) 1-10 mg/l (Daphnia magna) EC/LC50 (72h) 3.14 mg/l (Scenedesmus subspicatus) LL50 14.8 mg/l (fish toxicity) 25513-64-8 2,2,4-trimethylhexan-1,6-diamine LC50 (48h) 174 mg/l (Leuciscus idus) EC/LC50 (17h) 89 mg/l (Pseudomas putida) ERC50 43.5 mg/l (Scenedesmus subspicatus) 68512-30-1 Phenol, methylstyrenated EL 50 870 mg/l (Daphnia magna) >100 mg/l (Scenedesmus subspicatus) LL50 25.8 mg/l (fish toxicity) 69-72-7 Salicylic acid LC50/96h 1,380 mg/l (fish toxicity) EC50 (48h) 870 mg/l (Daphnia magna) EC/LC50 (72h) >100 mg/l (algae toxicity) 2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine LC50/96h 110 mg/l (Leuciscus idus) EC50 (48h) 23 mg/l (Daphnia magna) EC/10/18h 1,120 mg/l (Pseudomas putida) ERC50 >50 mg/l (Scenedesmus subspicatus) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. *
SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must be specially treated under adherence to official regulations. Cured materials which mixed with epoxy resin can put to the houshold-rubbish, after consulting the waste diposal. Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
(Contd. on page 9) GB
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Trade name: ASODUR-LE (B-Komponente) (Contd. of page 8)
· European waste catalogue 08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS 08 01 00 wastes from MFSU and removal of paint and varnish 08 01 11* waste paint and varnish containing organic solvents or other hazardous substances · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. *
SECTION 14: Transport information · 14.1 UN-Number · ADR, IMDG, IATA · 14.2 UN proper shipping name · ADR · IMDG · IATA
UN2735 2735 AMINES, LIQUID, CORROSIVE, N.O.S. (mphenylenebis(methylamine), 2,2,4-trimethylhexan1,6-diamine), ENVIRONMENTALLY HAZARDOUS AMINES, LIQUID, CORROSIVE, N.O.S. (mphenylenebis(methylamine), 2,2,4-trimethylhexan1,6-diamine), MARINE POLLUTANT AMINES, LIQUID, CORROSIVE, N.O.S. (mphenylenebis(methylamine), 2,2,4-trimethylhexan1,6-diamine)
· 14.3 Transport hazard class(es) · ADR, IMDG
· Class · Label
8 Corrosive substances. 8
· IATA
· 14.4 Packing group · ADR, IMDG, IATA
II
· 14.5 Environmental hazards:
· Special marking (ADR):
Product contains environmentally hazardous substances: phenol No Symbol (fish and tree) Symbol (fish and tree)
· 14.6 Special precautions for user · Kemler Number:
Warning: Corrosive substances. 80
· Marine pollutant:
(Contd. on page 10) GB
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Trade name: ASODUR-LE (B-Komponente) (Contd. of page 9)
· EMS Number: · Segregation groups · Stowage Category · Segregation Code
F-A,S-B Alkalis A SG35 Stow "separated from" SGG1-acids
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · Transport/Additional information: · ADR · Limited quantities (LQ) · Excepted quantities (EQ) · Transport category · Tunnel restriction code · IMDG · Limited quantities (LQ) · Excepted quantities (EQ)
· UN "Model Regulation":
1L Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml 2 E 1L Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml UN 2735 AMINES, LIQUID, CORROSIVE, N.O.S. (M-PHENYLENEBIS(METHYLAMINE), 2,2,4TRIMETHYLHEXAN-1,6-DIAMINE), 8, II, ENVIRONMENTALLY HAZARDOUS
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · Seveso category E2 Hazardous to the Aquatic Environment · Qualifying quantity (tonnes) for the application of lower-tier requirements 200 t · Qualifying quantity (tonnes) for the application of upper-tier requirements 500 t · REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3 · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H332 Harmful if inhaled. H411 Toxic to aquatic life with long lasting effects.
(Contd. on page 11) GB
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H412 Harmful to aquatic life with long lasting effects.
(Contd. of page 10)
· Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity - oral – Category 4 Skin Corr. 1A: Skin corrosion/irritation – Category 1A Skin Corr. 1B: Skin corrosion/irritation – Category 1B Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Skin Sens. 1: Skin sensitisation – Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered.
GB