48.0.13
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 10.12.2018 *
Version number 28
Revision: 10.12.2018
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASODUR-K-900 (B-Komp.) · Article number: 205070B · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Epoxy coating · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: guido.herfort@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS05 corrosion Skin Corr. 1B Eye Dam. 1
H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage.
GHS09 environment Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. GHS07 Acute Tox. 4 Acute Tox. 4 Skin Sens. 1
H302 Harmful if swallowed. H332 Harmful if inhaled. H317 May cause an allergic skin reaction.
· 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS05, GHS07, GHS09 · Signal word Danger · Hazard-determining components of labelling: Benzyl alcohol 4,4'Isopropylendiphenol, oligomeric reaction products with 1- chlorine-2,3-epoxypropane reaction products -phenylenbis (methylamine) m-phenylenebis(methylamine) (Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 10.12.2018
Trade name: ASODUR-K-900 (B-Komp.) (Contd. of page 1)
3-aminomethyl-3,5,5-trimethylcyclohexylamine phenol · Hazard statements H302+H332 Harmful if swallowed or if inhaled. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. · Precautionary statements P260 Do not breathe dusts or mists. P273 Avoid release to the environment. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Mixture consisting of the following components. · Dangerous components: CAS: 100-51-6 Benzyl alcohol EINECS: 202-859-9 Acute Tox. 4, H302; Acute Tox. 4, H332; Eye Irrit. 2, H319
25-50%
CAS: 113930-69-1 4,4'Isopropylendiphenol, oligomeric reaction products with 1- chlorine- 10-25% 2,3-epoxypropane reaction products -phenylenbis (methylamine) Skin Corr. 1B, H314; Eye Dam. 1, H318; Aquatic Chronic 2, Skin Sens. 1, H317 H411; CAS: 1477-55-0 m-phenylenebis(methylamine) EINECS: 216-032-5 Skin Corr. 1B, H314; Acute Tox. 4, H302; Acute Tox. 4, H332; Skin Sens. 1, H317; Aquatic Chronic 3, H412
10-25%
CAS: 61788-44-1
phenol Aquatic Chronic 2, H411;
Skin Irrit. 2, H315; Skin Sens. 1, H317
CAS: 2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine EINECS: 220-666-8 Skin Corr. 1B, H314; Acute Tox. 4, H302; Acute Tox. 4, H312; Skin Sens. 1, H317; Aquatic Chronic 3, H412 CAS: 69-72-7 Salicylic acid EINECS: 200-712-3 Eye Dam. 1, H318 · Additional information For the wording of the listed hazard phrases refer to section 16. *
2.5-10%
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Instantly remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. (Contd. on page 3) GB
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Trade name: ASODUR-K-900 (B-Komp.) (Contd. of page 2)
Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation In case of unconsciousness bring patient into stable side position for transport. Supply fresh air and call for doctor for safety reasons. · After skin contact Instantly wash with water and soap and rinse thoroughly. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. · After swallowing Do not induce vomiting; instantly call for medical help. Show the pack or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · For safety reasons unsuitable extinguishing agents Water with a full water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. Burst- and explosion-danger by increasing pressure. In case of fire chill the container with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Ensure adequate ventilation. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. (Contd. on page 4) GB
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Trade name: ASODUR-K-900 (B-Komp.) (Contd. of page 3)
Keep away from children. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. Store in a locked cabinet and out of the reach of children. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: Self-contained breathing apparatus must be used in case of bad fresh-air-supply or no adequate removal suction is available. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing. Contaminated protection clothes must be cleaned carefully before reuse.
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Fluid Colour: Colourless · Smell: Amine-like · Odour threshold: Not determined. · pH-value:
Not determined. (Contd. on page 5) GB
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Trade name: ASODUR-K-900 (B-Komp.) (Contd. of page 4)
· Change in condition Melting point/freezing point: Not determined Initial boiling point and boiling range: Not determined · Flash point:
94 °C
· Inflammability (solid, gaseous)
Not applicable.
· Decomposition temperature:
Not determined.
· Self-inflammability:
Product is not selfigniting.
· Explosive properties:
Product is not explosive.
· Critical values for explosion: Lower: Upper:
Not determined. Not determined.
· Steam pressure:
· Density at 20 °C · Relative density · Vapour density · Evaporation rate
1.06 g/cm³ Not determined. Not determined. Not determined.
· Solubility in / Miscibility with Water:
Not miscible or difficult to mix
· Partition coefficient: n-octanol/water:
· Viscosity: dynamic at 20 °C: kinematic: · 9.2 Other information
135 mPas Not determined. No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known *
SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Harmful if swallowed or if inhaled. · LD/LC50 values that are relevant for classification: 100-51-6 Benzyl alcohol Oral LD50 1,570 mg/kg (rats) Inhalative LC50 11 mg/l 1477-55-0 m-phenylenebis(methylamine) Oral LD50 930 mg/kg (rats) Dermal LD50 >3,100 mg/kg (rabbit) (Contd. on page 6) GB
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Trade name: ASODUR-K-900 (B-Komp.) (Contd. of page 5)
61788-44-1 phenol Oral LD50 >2,000 mg/kg (rats) Dermal LD50 >2,000 mg/kg (rats) 2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine Oral LD50 1,030 mg/kg (rats) Dermal LD50 1,840 mg/kg (rats) 69-72-7 Salicylic acid Oral LD50 >2,000 mg/kg (rabbit) LD50 891 mg/kg (rats) · Primary irritant effect: · Skin corrosion/irritation Causes severe skin burns and eye damage. · Serious eye damage/irritation Causes serious eye damage. · Respiratory or skin sensitisation May cause an allergic skin reaction. · Additional toxicological information: Sensitizing · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. *
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 61788-44-1 phenol LC50/96h 14.8 mg/l (fish toxicity) ERC50 3.14 mg/l (algae toxicity) 69-72-7 Salicylic acid LC50/96h 1,380 mg/l (fish toxicity) EC50 (48h) 870 mg/l (Daphnia magna) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Ecotoxical effects: · Remark: Harmful to fish · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. Must not reach sewage water or drainage ditch undiluted or unneutralised. Danger to drinking water if even small quantities leak into soil. Harmful to aquatic organisms · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. (Contd. on page 7) GB
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Trade name: ASODUR-K-900 (B-Komp.) (Contd. of page 6)
· 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS 08 01 00 wastes from MFSU and removal of paint and varnish 08 01 11 waste paint and varnish containing organic solvents or other dangerous substances · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. *
SECTION 14: Transport information · 14.1 UN-Number · ADR, IMDG, IATA · 14.2 UN proper shipping name · ADR · IMDG, IATA
UN2735 2735 POLYAMINES, LIQUID, CORROSIVE, N.O.S. (N-AMINOETHYLPIPERAZINE, ISOPHORONEDIAMINE) POLYAMINES, LIQUID, CORROSIVE, N.O.S. (NAMINOETHYLPIPERAZINE, ISOPHORONEDIAMINE)
· 14.3 Transport hazard class(es) · ADR
· Class · Label
8 Corrosive substances. 8
· IMDG, IATA
· 14.4 Packing group · ADR, IMDG, IATA
III
· 14.5 Environmental hazards: · Marine pollutant: · Special marking (ADR):
No Symbol (fish and tree)
· 14.6 Special precautions for user · Kemler Number:
Warning: Corrosive substances. 80 (Contd. on page 8) GB
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Trade name: ASODUR-K-900 (B-Komp.) (Contd. of page 7)
· EMS Number: · Stowage Category · Segregation Code
F-A,S-B A SG35 Stow "separated from" acids.
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · Transport/Additional information: · ADR · Limited quantities (LQ) · Excepted quantities (EQ) · Transport category · Tunnel restriction code · IMDG · Limited quantities (LQ) · Excepted quantities (EQ)
· UN "Model Regulation":
5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml 3 E 5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN2735, POLYAMINES, LIQUID, CORROSIVE, N.O.S. (N-AMINOETHYLPIPERAZINE, ISOPHORONEDIAMINE), 8, III
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3 · National regulations · Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water. The classification based on german instructions. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) (Contd. on page 9) GB
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Trade name: ASODUR-K-900 (B-Komp.) (Contd. of page 8) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity – Category 4 Skin Corr. 1B: Skin corrosion/irritation – Category 1B Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Skin Sens. 1: Skin sensitisation – Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered. GB