44.0
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 09.02.2017 *
Version number 39
Revision: 09.02.2017
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASODUR-B 3356 EFC (A-Komponente) · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Epoxy coating · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: guido.herfort@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS09 environment Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. GHS07 Skin Irrit. 2 Eye Irrit. 2 Skin Sens. 1
H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction.
· 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS07, GHS09 · Signal word Warning · Hazard-determining components of labelling: reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700) oxirane, mono[(C12-14-alkyloxy)methyl] derivs bisphenol-F-epoxy resin Fatty acids, C14-18 and C16-18-unsatd., 2-phenoxyethyl esters, maleated · Hazard statements H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects.
(Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 09.02.2017
Trade name: ASODUR-B 3356 EFC (A-Komponente) (Contd. of page 1)
· Precautionary statements P273 Avoid release to the environment. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves / eye protection / face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P363 Wash contaminated clothing before reuse. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · Additional information: Contains isocyanates. May produce an allergic reaction. Contains epoxy constituents. May produce an allergic reaction. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Solvent- free preparation based on Bisphenol-A-Epichlorhydrin resin molecular weight ≤ 700. · Dangerous components: CAS: 25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number NLP: 500-033-5 average molecular weight ≤ 700) Aquatic Chronic 2, H411; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317
25-50%
CAS: 68609-97-2 oxirane, mono[(C12-14-alkyloxy)methyl] derivs EINECS: 271-846-8 Skin Irrit. 2, H315; Skin Sens. 1, H317
10-25%
CAS: 9003-36-5 NLP: 500-006-8
bisphenol-F-epoxy resin Aquatic Chronic 2, H411; Skin Sens. 1, H317
2.5-10%
CAS: 91001-64-8
Fatty acids, C14-18 and C16-18-unsatd., 2-phenoxyethyl esters, maleated Eye Irrit. 2, H319; Skin Sens. 1A, H317
Skin Irrit. 2, H315; Eye Irrit. 2, H319; < 0.5%
CAS: 25154-52-3 nonylphenol < 0.5% EINECS: 246-672-0 Repr. 2, H361fd; Skin Corr. 1B, H314; Aquatic Acute 1, H400; Aquatic Chronic 1, H410; Acute Tox. 4, H302 · SVHC 25154-52-3 nonylphenol SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air; consult doctor in case of symptoms.
(Contd. on page 3) GB
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Trade name: ASODUR-B 3356 EFC (A-Komponente) (Contd. of page 2)
· After skin contact Change immediately contaminated clothes. Instantly wash with water and soap and rinse thoroughly. Don't use solvents to clean the skin. · After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. · After swallowing Do not induce vomiting; instantly call for medical help. Show the pack or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. *
SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Avoid eye- and skin contact. Wear protective equipment. Keep unprotected persons away. Do not breath in vapour. Keep away from ignition sources · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding, inflammable material (sand, diatomite, acid binders, universal binder). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Keep containers tightly sealed. Work with fresh air supply, keep doors and windows open. Keep away from children. Keep away from heat and direct sunlight. · Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Store in cool location. Do not leave open containers. Do not store in common rooms.
(Contd. on page 4) GB
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Trade name: ASODUR-B 3356 EFC (A-Komponente)
· Information about storage in one common storage facility: Store away from foodstuffs. Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Protect from frost. · 7.3 Specific end use(s) No further relevant information available. *
(Contd. of page 3)
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures Do not take thinner to clean the skin. The usual precautionary measures should be adhered to in handling the chemicals. Instantly remove any soiled and impregnated garments. Wash hands during breaks and at the end of the work. Avoid contact with the eyes and skin. · Breathing equipment: Not required. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing.
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Liquid Colour: Colourless · Smell: Weak, characteristic · Change in condition Melting point/freezing point: Not determined Initial boiling point and boiling range: Not determined · Flash point:
Not applicable
· Self-inflammability:
Product is not selfigniting.
· Explosive properties:
Product is not explosive. (Contd. on page 5) GB
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Trade name: ASODUR-B 3356 EFC (A-Komponente) (Contd. of page 4)
· Critical values for explosion: Lower: Upper:
Not determined. Not determined.
· Steam pressure:
Not determined.
· Density at 20 °C
1.350 g/cm³
· Solubility in / Miscibility with Water:
Unsoluble
· Viscosity: dynamic at 20 °C: kinematic: · 9.2 Other information
6500 mPas Not determined. No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions Reacts violently with oxidizing agents · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: Can react with acid and oxidizing agends. · 10.6 Hazardous decomposition products: În case of heating dangerous decomposition products can be arise. *
SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700) Oral LD50 >5000 mg/kg (rats) Dermal LD50 >2000 mg/kg (rats) 68609-97-2 oxirane, mono[(C12-14-alkyloxy)methyl] derivs Oral LD50 34600 mg/kg (rats) Dermal LD50 >23800 mg/kg (rabbit) 9003-36-5 bisphenol-F-epoxy resin Oral LD50 >10000 mg/kg (rats) Dermal LD50 >2000 mg/kg (rats) · Primary irritant effect: · Skin corrosion/irritation Causes skin irritation. · Serious eye damage/irritation Causes serious eye irritation. · Respiratory or skin sensitisation May cause an allergic skin reaction. · Additional toxicological information: Sensitizing · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met.
(Contd. on page 6) GB
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Trade name: ASODUR-B 3356 EFC (A-Komponente) (Contd. of page 5)
· Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. *
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700) LC50 (96h) 2 mg/l (rainbow trout) EC50 (48h) 1.7 mg/l (Daphnia sp.) EC50 (48h) 1.7 mg/l (Daphnia magna) NOEC 0.3 mg/l (Daphnia magna) 68609-97-2 oxirane, mono[(C12-14-alkyloxy)methyl] derivs EC50 (48h) 1-10 mg/l (Daphnia magna) EC50 1-10 mg/l (Daphnia magna) 9003-36-5 bisphenol-F-epoxy resin LC50/96h 2.54 mg/l (Leuciscus idus) EC50 2.55 mg/l (Daphnia magna) ERC50 1.8 mg/l (algae toxicity) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. Danger to drinking water if even small quantities leak into soil. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Transfer to a permitted waste diposal institution. Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 07 00 00 WASTES FROM ORGANIC CHEMICAL PROCESSES 07 02 00 wastes from the MFSU of plastics, synthetic rubber and man-made fibres 07 02 99 wastes not otherwise specified 08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS 08 01 00 wastes from MFSU and removal of paint and varnish 08 01 99 wastes not otherwise specified
(Contd. on page 7) GB
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Trade name: ASODUR-B 3356 EFC (A-Komponente) (Contd. of page 6)
· Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. *
SECTION 14: Transport information · 14.1 UN-Number · ADR, IMDG, IATA · 14.2 UN proper shipping name · ADR
· IMDG
· IATA
UN3082 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A(epichlorhydrin); epoxy resin(number average molecular weight<700), oxirane, mono[(C12-14alkyloxy)methyl] derivs) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A-(epichlorhydrin); epoxy resin(number average molecular weight<700), oxirane, mono[(C12-14-alkyloxy) methyl] derivs), MARINE POLLUTANT ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A-(epichlorhydrin); epoxy resin(number average molecular weight<700), oxirane, mono[(C12-14-alkyloxy) methyl] derivs)
· 14.3 Transport hazard class(es) · ADR, IMDG, IATA
· Class · Label
9 Miscellaneous dangerous substances and articles. 9
· 14.4 Packing group · ADR, IMDG, IATA
III
· 14.5 Environmental hazards: · Marine pollutant: · Special marking (ADR): · Special marking (IATA): · 14.6 Special precautions for user · Kemler Number: · EMS Number:
Yes Symbol (fish and tree) Symbol (fish and tree) Symbol (fish and tree) Warning: Miscellaneous dangerous substances and articles. 90 F-A,S-F
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · Transport/Additional information: · ADR · Limited quantities (LQ) · Transport category · Tunnel restriction code · UN "Model Regulation":
5L 3 E UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A(Contd. on page 8) GB
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Trade name: ASODUR-B 3356 EFC (A-Komponente) (Contd. of page 7)
·
(epichlorhydrin); epoxy resin(number average molecular weight<700), oxirane, mono[(C12-14alkyloxy)methyl] derivs), 9, III
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3, 46a · National regulations · Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H361fd Suspected of damaging fertility. Suspected of damaging the unborn child. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. · Contact: Mr. Guido Herfort · Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic SVHC: Substances of Very High Concern vPvB: very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity – Category 4 Skin Corr. 1B: Skin corrosion/irritation – Category 1B Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Skin Sens. 1: Skin sensitisation – Category 1 Skin Sens. 1A: Skin sensitisation – Category 1A Repr. 2: Reproductive toxicity – Category 2 Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
· * Data compared to the previous version altered.
GB