40.0
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 16.03.2015 *
Version number 8
Revision: 16.03.2015
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: Primer-2000 S (B-Komp.) · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Primer · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: guido.herfort@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS02 flame Flam. Liq. 2 H225 Highly flammable liquid and vapour. GHS05 corrosion Skin Corr. 1B H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage. GHS07 Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H336 May cause drowsiness or dizziness. · Classification according to Directive 67/548/EEC or Directive 1999/45/EC C; Corrosive R34:
Causes burns. Xn; Harmful
R21/22: Harmful in contact with skin and if swallowed. Xi; Sensitising R43:
May cause sensitisation by skin contact. (Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 16.03.2015
Trade name: Primer-2000 S (B-Komp.) (Contd. of page 1)
F; Highly flammable R11: Highly flammable. R67: Vapours may cause drowsiness and dizziness. · Information concerning particular hazards for human and environment: The product may not leak out in sewerage system, stretch of water or soil. The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Has a narcotising effect. · Classification system: The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information furnished by supplier companies. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS02, GHS05, GHS07 · Signal word Danger · Hazard-determining components of labelling: Ethylenediamine ethyl acetate · Hazard statements H225 Highly flammable liquid and vapour. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H336 May cause drowsiness or dizziness. · Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P241 Use explosion-proof electrical/ventilating/lighting/equipment. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Mixture consisting of the following components. · Dangerous components: CAS: 141-78-6 ethyl acetate EINECS: 205-500-4 Xi R36; F R11 R66-67 Flam. Liq. 2, H225;
50-100% Eye Irrit. 2, H319; STOT SE 3, H336
CAS: 25707-70-4 Ethylenediamine EINECS: 247-196-6 C R34; Xn R21; Xi R43 Skin Corr. 1B, H314; Acute Tox. 4, H312; Skin Sens. 1, H317
10-25%
(Contd. on page 3) GB
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Trade name: Primer-2000 S (B-Komp.) (Contd. of page 2)
CAS: 90-72-2 2,4,6-tris(dimethylaminomethyl)phenol Xn R22; Xi R36/38 EINECS: 202-013-9 Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2, H319 · Additional information For the wording of the listed risk phrases refer to section 16.
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact Instantly wash with water and soap and rinse thoroughly. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Don't cause vomiting Show the pack or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. · For safety reasons unsuitable extinguishing agents Water with a full water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. Burst- and explosion-danger by increaseing pressure. In case of fire chill the container with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. (Contd. on page 4) GB
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Trade name: Primer-2000 S (B-Komp.) (Contd. of page 3)
See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Store in cool, dry place in tightly closed containers. Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Keep away from children. · Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Store in cool location. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Store in cool, dry conditions in well sealed containers. Store in a locked cabinet and out of the reach of children. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 141-78-6 ethyl acetate (50-100%) WEL Short-term value: 400 ppm Long-term value: 200 ppm · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Instantly remove any soiled and impregnated garments. Do not inhale gases / fumes / aerosols. Avoid contact with the eyes and skin. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: Not required. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing. GB
(Contd. on page 5)
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Trade name: Primer-2000 S (B-Komp.) (Contd. of page 4)
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Fluid Colour: Light yellow · Smell: Amine-like · Change in condition Melting point/Melting range: Not determined Boiling point/Boiling range: 77 °C · Flash point:
-4 °C
· Ignition temperature:
460 °C 460 °C
· Self-inflammability:
Product is not selfigniting.
· Danger of explosion:
Product is not explosive. However, formation of explosive air/ steam mixtures is possible.
· Critical values for explosion: Lower: 2.1 Vol % 2,1 % (V) Upper: 11.5 Vol % 11,5 % (V) · Steam pressure:
Not determined. 97 hPa 20 °C
· Density at 20 °C
0.91 g/cm³
· Solubility in / Miscibility with Water: Not miscible or difficult to mix · Viscosity: dynamic at 20 °C:
10 mPas
· Solvent content: Organic solvents: Water:
71.3 % 0.0 %
Solids content: · 9.2 Other information
26.3 % No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions Decomposes with water, acids and alkalis · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: Carbon monoxide and carbon dioxide No dangerous decomposition products known GB
(Contd. on page 6)
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Trade name: Primer-2000 S (B-Komp.) (Contd. of page 5)
SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: 141-78-6 ethyl acetate Oral LD50 5600 mg/kg (rats) >18000 mg/kg (rbt) Inhalative LC50/4 h 1600 mg/l (rats) · Primary irritant effect: · on the skin: Irritant for skin and mucous membranes. · on the eye: Irritant effect. · Sensitisation: No sensitizing effect known. · Additional toxicological information: The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for Preparations as issued in the latest version: Harmful Irritant Sensitizing · Sensitisation May cause sensitisation by skin contact. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: No further relevant information available. · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS 08 04 00 wastes from MFSU of adhesives and sealants (including waterproofing products) 08 04 09* waste adhesives and sealants containing organic solvents or other dangerous substances · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. GB
(Contd. on page 7)
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Trade name: Primer-2000 S (B-Komp.) (Contd. of page 6)
SECTION 14: Transport information · 14.1 UN-Number · ADR, IMDG, IATA · 14.2 UN proper shipping name · ADR · IMDG, IATA
UN2924 2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. (ETHYL ACETATE) FLAMMABLE LIQUID, CORROSIVE, N.O.S. (ETHYL ACETATE)
· 14.3 Transport hazard class(es) · ADR, IMDG, IATA
· Class · Label
3 Flammable liquids. 3+8
· 14.4 Packing group · ADR, IMDG, IATA
II
· 14.5 Environmental hazards: · Marine pollutant:
No
· 14.6 Special precautions for user · Kemler Number: · EMS Number:
Warning: Flammable liquids. 33 F-E,S-C
· 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional information: · ADR · Limited quantities (LQ) · Transport category · Tunnel restriction code · UN "Model Regulation":
1L 2 D/E UN2924, FLAMMABLE LIQUID, CORROSIVE, N.O.S. (ETHYL ACETATE), 3 (8), II
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · National regulations · Technical instructions (air): · Class Share in % · NK 71.3 · Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. The classification based on german instructions. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. GB
(Contd. on page 8)
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Trade name: Primer-2000 S (B-Komp.) (Contd. of page 7)
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H225 Highly flammable liquid and vapour. H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. R11 Highly flammable. R21 Harmful in contact with skin. R22 Harmful if swallowed. R34 Causes burns. R36 Irritating to eyes. R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Flam. Liq. 2: Flammable liquids, Hazard Category 2 Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Corr. 1B: Skin corrosion/irritation, Hazard Category 1B Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1 Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 Skin Sens. 1: Sensitisation - Skin, Hazard Category 1 STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
· * Data compared to the previous version altered. GB