Primer-2000_S comp.A.pdf
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<h1>Primer-2000_S comp.A.pdf</h1> <p>40.0</p> <p>Page 1/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.03.2015 <br />*</p> <p>Version number 8</p> <p>Revision: 16.03.2015</p> <p>SECTION 1: Identification of the substance/mixture and of the company/undertaking <br />· 1.1 Product identifier <br />· Trade name: Primer-2000 S (A-Komp.) <br />· 1.2 Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture Primer <br />· 1.3 Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />Fax: ++49 (0)5231/953-123 <br />email: info@schomburg.de <br />web: www.schomburg.de <br />· Informing department: <br />Product Safety Department <br />Tel: ++49 (0)5231/953-193 <br />Fax: ++49 (0)5231/953-106 <br />email: guido.herfort@schomburg.de</p> <p>*</p> <p>SECTION 2: Hazards identification <br />· 2.1 Classification of the substance or mixture <br />· Classification according to Regulation (EC) No 1272/2008 <br />GHS02 flame <br />Flam. Liq. 2</p> <p>H225 Highly flammable liquid and vapour.</p> <p>GHS08 health hazard <br />Repr. 2</p> <p>H361d Suspected of damaging the unborn child. <br />GHS07</p> <p>Skin Irrit. 2 <br />Eye Irrit. 2 <br />Skin Sens. 1 <br />STOT SE 3</p> <p>H315 <br />H319 <br />H317 <br />H336</p> <p>Causes skin irritation. <br />Causes serious eye irritation. <br />May cause an allergic skin reaction. <br />May cause drowsiness or dizziness.</p> <p>Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. <br />· Classification according to Directive 67/548/EEC or Directive 1999/45/EC <br />Xn; Harmful <br />R63:</p> <p>Possible risk of harm to the unborn child. <br />Xi; Irritant</p> <p>R36/38:</p> <p>Irritating to eyes and skin. <br />(Contd. on page 2) <br />GB</p> <p>40.0</p> <p>Page 2/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.03.2015</p> <p>Version number 8</p> <p>Revision: 16.03.2015</p> <p>Trade name: Primer-2000 S (A-Komp.) <br />(Contd. of page 1)</p> <p>Xi; Sensitising <br />R43:</p> <p>May cause sensitisation by skin contact. <br />F; Highly flammable</p> <p>R11: <br />Highly flammable. <br />R52/53-67: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic <br />environment. Vapours may cause drowsiness and dizziness. <br />· Information concerning particular hazards for human and environment: <br />The product may not leak out in sewerage system, stretch of water or soil. <br />The product has to be labelled due to the calculation procedure of the "General Classification <br />guideline for preparations of the EU" in the latest valid version. <br />Has a narcotising effect. <br />· Classification system: <br />The classification is in line with current EC lists. It is expanded, however, by information from <br />technical literature and by information furnished by supplier companies. <br />· 2.2 Label elements <br />· Labelling according to Regulation (EC) No 1272/2008 <br />The product is classified and labelled according to the CLP regulation. <br />· Hazard pictograms GHS02, GHS07, GHS08 <br />· Signal word Danger <br />· Hazard-determining components of labelling: <br />reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight 700 1100) <br />ethyl acetate <br />toluene <br />reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight = 700) <br />· Hazard statements <br />H225 Highly flammable liquid and vapour. <br />H315 Causes skin irritation. <br />H319 Causes serious eye irritation. <br />H317 May cause an allergic skin reaction. <br />H361d Suspected of damaging the unborn child. <br />H336 May cause drowsiness or dizziness. <br />H412 Harmful to aquatic life with long lasting effects. <br />· Precautionary statements <br />P210 <br />Keep away from heat/sparks/open flames/hot surfaces. - No smoking. <br />P241 <br />Use explosion-proof electrical/ventilating/lighting/equipment. <br />P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. <br />Rinse skin with water/shower. <br />P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact <br />lenses, if present and easy to do. Continue rinsing. <br />P405 <br />Store locked up. <br />P501 <br />Dispose of contents/container in accordance with local/regional/national/ <br />international regulations. <br />· Additional information: <br />Contains epoxy constituents. May produce an allergic reaction. <br />· 2.3 Other hazards <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />*</p> <p>SECTION 3: Composition/information on ingredients <br />· 3.2 Chemical characterisation: Mixtures <br />· Description: Mixture consisting of the following components. <br />(Contd. on page 3) <br />GB</p> <p>40.0</p> <p>Page 3/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.03.2015</p> <p>Version number 8</p> <p>Revision: 16.03.2015</p> <p>Trade name: Primer-2000 S (A-Komp.) <br />(Contd. of page 2)</p> <p>· Dangerous components: <br />CAS: 141-78-6 <br />ethyl acetate <br />EINECS: 205-500-4 <br />Xi R36; <br />F R11 <br />R66-67 <br />Flam. Liq. 2, H225; <br />CAS: 25036-25-3</p> <p>25-50% <br />Eye Irrit. 2, H319; STOT SE 3, H336</p> <p>reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number <br />average molecular weight 700 - 1100) <br />Xi R36/38; <br />Xi R43 <br />Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317</p> <p>10-25%</p> <p>CAS: 108-88-3 <br />toluene <br />EINECS: 203-625-9 <br />Xn R48/20-63-65; <br />Xi R38; <br />F R11 <br />R67 <br />Repr. Cat. 3 <br />Flam. Liq. 2, H225; <br />Repr. 2, H361d; STOT RE 2, H373; Asp. <br />Skin Irrit. 2, H315; STOT SE 3, H336 <br />Tox. 1, H304;</p> <p>2.5-10%</p> <p>CAS: 25068-38-6 <br />NLP: 500-033-5</p> <p>2.5-10%</p> <p>reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number <br />average molecular weight = 700) <br />Xi R36/38; <br />Xi R43; <br />N R51/53 <br />Aquatic Chronic 2, H411; <br />Skin Irrit. 2, H315; Eye Irrit. 2, H319; <br />Skin Sens. 1, H317 <br />· Additional information For the wording of the listed risk phrases refer to section 16. <br />*</p> <p>SECTION 4: First aid measures <br />· 4.1 Description of first aid measures <br />· General information <br />Symptoms of poisoning may even occur after several hours; therefore medical observation for at <br />least 48 hours after the accident. <br />Personal protection for the First Aider. <br />· After inhalation Supply fresh air or oxygen; call for doctor. <br />· After skin contact Instantly wash with water and soap and rinse thoroughly. <br />· After eye contact <br />Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. <br />· After swallowing <br />Drink copious amounts of water and provide fresh air. Instantly call for doctor. <br />Don't cause vomiting <br />Show the pack or the label to the doctor. <br />· 4.2 Most important symptoms and effects, both acute and delayed <br />No further relevant information available. <br />· 4.3 Indication of any immediate medical attention and special treatment needed <br />No further relevant information available. <br />SECTION 5: Firefighting measures <br />· 5.1 Extinguishing media <br />· Suitable extinguishing agents <br />CO2, extinguishing powder or water jet. Fight larger fires with water jet. <br />· For safety reasons unsuitable extinguishing agents Water with a full water jet. <br />· 5.2 Special hazards arising from the substance or mixture <br />Formation of poisonous gases during heating or in fires. <br />· 5.3 Advice for firefighters <br />· Protective equipment: Wear self-contained breathing apparatus. <br />· Additional information <br />Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. <br />(Contd. on page 4) <br />GB</p> <p>40.0</p> <p>Page 4/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.03.2015</p> <p>Version number 8</p> <p>Revision: 16.03.2015</p> <p>Trade name: Primer-2000 S (A-Komp.) <br />(Contd. of page 3)</p> <p>Follow the emergency-plan. <br />Burst- and explosion-danger by increaseing pressure. <br />In case of fire chill the container with water spray. <br />SECTION 6: Accidental release measures <br />· 6.1 Personal precautions, protective equipment and emergency procedures <br />Bring persons out of danger. <br />Wear protective equipment. Keep unprotected persons away. <br />· 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. <br />· 6.3 Methods and material for containment and cleaning up: <br />Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). <br />· 6.4 Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />See Section 13 for information on disposal. <br />SECTION 7: Handling and storage <br />· 7.1 Precautions for safe handling <br />Ensure good ventilation/exhaustion at the workplace. <br />Prevent formation of aerosols. <br />Store in cool, dry place in tightly closed containers. <br />Keep away from children. <br />· Information about protection against explosions and fires: <br />Keep ignition sources away - Do not smoke. <br />Protect against electrostatic charges. <br />· 7.2 Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: Store in cool location. <br />· Information about storage in one common storage facility: <br />Please follow the rules of the VCI-Storage-Concept for chemicals. <br />· Further information about storage conditions: <br />Store in cool, dry conditions in well sealed containers. <br />Store in a locked cabinet and out of the reach of children. <br />· 7.3 Specific end use(s) No further relevant information available. <br />*</p> <p>SECTION 8: Exposure controls/personal protection <br />· Additional information about design of technical systems: <br />It must be possible to wash the skin in the working area. <br />Eye-wash bottle must be available. <br />· 8.1 Control parameters <br />· Components with critical values that require monitoring at the workplace: <br />141-78-6 ethyl acetate (25-50%) <br />WEL Short-term value: 400 ppm <br />Long-term value: 200 ppm <br />108-88-3 toluene (2.5-10%) <br />WEL Short-term value: 384 mg/m³, 100 ppm <br />Long-term value: 191 mg/m³, 50 ppm <br />Sk <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />(Contd. on page 5) <br />GB</p> <p>40.0</p> <p>Page 5/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.03.2015</p> <p>Version number 8</p> <p>Revision: 16.03.2015</p> <p>Trade name: Primer-2000 S (A-Komp.) <br />(Contd. of page 4)</p> <p>· 8.2 Exposure controls <br />· Personal protective equipment <br />· General protective and hygienic measures <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />Instantly remove any soiled and impregnated garments. <br />Do not inhale gases / fumes / aerosols. <br />Avoid contact with the eyes and skin. <br />Be sure to clean skin thoroughly after work and before breaks. <br />· Breathing equipment: <br />In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer <br />exposure use breathing apparatus that is independent of circulating air. <br />· Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. <br />· Material of gloves <br />Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min <br />· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and <br />has to be observed. <br />· Eye protection: Safety glasses <br />· Body protection: Protective work clothing. <br />*</p> <p>SECTION 9: Physical and chemical properties <br />· 9.1 Information on basic physical and chemical properties <br />· General Information <br />· Appearance: <br />Form: <br />Fluid <br />Colour: <br />Light yellow <br />· Smell: <br />Characteristic <br />· Change in condition <br />Melting point/Melting range: Not determined <br />Boiling point/Boiling range: 77 °C <br />· Flash point:</p> <p>-3 °C</p> <p>· Ignition temperature:</p> <p>460 °C <br />460 °C</p> <p>· Self-inflammability:</p> <p>Product is not selfigniting.</p> <p>· Danger of explosion:</p> <p>Product is not explosive. However, formation of explosive air/ <br />steam mixtures is possible.</p> <p>· Critical values for explosion: <br />Lower: <br />2.1 Vol % <br />2,1 % (V) <br />Upper: <br />11.5 Vol % <br />11,5 % (V) <br />· Steam pressure:</p> <p>97 hPa 20 °C</p> <p>· Density at 20 °C</p> <p>0.97 g/cm³</p> <p>· Solubility in / Miscibility with <br />Water: <br />Not miscible or difficult to mix <br />· Viscosity: <br />dynamic at 20 °C:</p> <p>10 mPas <br />(Contd. on page 6) <br />GB</p> <p>40.0</p> <p>Page 6/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.03.2015</p> <p>Version number 8</p> <p>Revision: 16.03.2015</p> <p>Trade name: Primer-2000 S (A-Komp.) <br />(Contd. of page 5)</p> <p>· 9.2 Other information</p> <p>No further relevant information available.</p> <p>SECTION 10: Stability and reactivity <br />· 10.1 Reactivity <br />· 10.2 Chemical stability <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· 10.3 Possibility of hazardous reactions Reacts with strong acids and oxidizing agents <br />· 10.4 Conditions to avoid No further relevant information available. <br />· 10.5 Incompatible materials: No further relevant information available. <br />· 10.6 Hazardous decomposition products: <br />Carbon monoxide and carbon dioxide <br />No dangerous decomposition products known <br />SECTION 11: Toxicological information <br />· 11.1 Information on toxicological effects <br />· Acute toxicity: <br />· LD/LC50 values that are relevant for classification: <br />141-78-6 ethyl acetate <br />Oral <br />LD50 <br />5600 mg/kg (rats) <br />>18000 mg/kg (rbt) <br />Inhalative LC50/4 h 1600 mg/l (rats) <br />108-88-3 toluene <br />Oral <br />LD50 <br />5000 mg/kg (rats) <br />Dermal LD50 <br />12300 mg/kg (rabbit) <br />Inhalative LC50 <br />(8h) 5320 ppm (Maus) <br />LC50/4 h 19 mg/l (rats) <br />25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average <br />molecular weight = 700) <br />Oral <br />LD50 <br />>5000 mg/kg (rats) <br />Dermal LD50 <br />>2000 mg/kg (rats) <br />· Primary irritant effect: <br />· on the skin: Irritant for skin and mucous membranes. <br />· on the eye: Irritant effect. <br />· Sensitisation: Sensitization possible by skin contact. <br />· Additional toxicological information: <br />The product shows the following dangers according to the calculation method of the General EC <br />Classification Guidelines for Preparations as issued in the latest version: <br />Irritant <br />Sensitizing <br />· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) <br />Repr. 2 <br />GB</p> <p>(Contd. on page 7)</p> <p>40.0</p> <p>Page 7/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.03.2015</p> <p>Version number 8</p> <p>Revision: 16.03.2015</p> <p>Trade name: Primer-2000 S (A-Komp.) <br />(Contd. of page 6)</p> <p>*</p> <p>SECTION 12: Ecological information <br />· 12.1 Toxicity <br />· Aquatic toxicity: <br />108-88-3 toluene <br />LC50/96h 1-10 mg/l (fish toxicity) <br />25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average <br />molecular weight = 700) <br />EC50 <br />(24h) 3.6 mg/l (Daphnia magna) <br />LC50 <br />(96h) 1.5 mg/l (rainbow trout) <br />· 12.2 Persistence and degradability <br />25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average <br />molecular weight = 700) <br />301B (Mod. Sturm) 12 % (-) <br />· 12.3 Bioaccumulative potential No further relevant information available. <br />· 12.4 Mobility in soil No further relevant information available. <br />· Ecotoxical effects: <br />108-88-3 toluene <br />EC 50 6mg/l/48h mg/l (Daphnia magna) <br />· Remark: Harmful to fish <br />· Additional ecological information: <br />· General notes: Water hazard class 2 (Self-assessment): hazardous for water. <br />· 12.5 Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />· 12.6 Other adverse effects No further relevant information available. <br />SECTION 13: Disposal considerations <br />· 13.1 Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />· European waste catalogue <br />08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) <br />OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, <br />SEALANTS AND PRINTING INKS <br />08 04 00 wastes from MFSU of adhesives and sealants (including waterproofing products) <br />08 04 09* waste adhesives and sealants containing organic solvents or other dangerous <br />substances <br />· Uncleaned packagings: <br />· Recommendation: Disposal must be made according to official regulations.</p> <p>*</p> <p>SECTION 14: Transport information <br />· 14.1 UN-Number <br />· ADR, IMDG, IATA</p> <p>UN1133</p> <p>· 14.2 UN proper shipping name <br />· ADR <br />· IMDG, IATA</p> <p>1133 ADHESIVES, special provision 640D <br />ADHESIVES <br />(Contd. on page 8) <br />GB</p> <p>40.0</p> <p>Page 8/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.03.2015</p> <p>Version number 8</p> <p>Revision: 16.03.2015</p> <p>Trade name: Primer-2000 S (A-Komp.) <br />(Contd. of page 7)</p> <p>· 14.3 Transport hazard class(es) <br />· ADR, IMDG, IATA</p> <p>· Class <br />· Label</p> <p>3 Flammable liquids. <br />3</p> <p>· 14.4 Packing group <br />· ADR, IMDG, IATA</p> <p>II</p> <p>· 14.5 Environmental hazards: <br />· Marine pollutant:</p> <p>No</p> <p>· 14.6 Special precautions for user <br />· Kemler Number: <br />· EMS Number:</p> <p>Warning: Flammable liquids. <br />33 <br />F-E,S-D</p> <p>· 14.7 Transport in bulk according to Annex II <br />of MARPOL73/78 and the IBC Code <br />Not applicable. <br />· Transport/Additional information:</p> <p>*</p> <p>· ADR <br />· Limited quantities (LQ) <br />· Transport category <br />· Tunnel restriction code</p> <p>5L <br />2 <br />D1E</p> <p>· UN "Model Regulation":</p> <p>UN1133, ADHESIVES, special provision 640D, 3, II</p> <p>SECTION 15: Regulatory information <br />· 15.1 Safety, health and environmental regulations/legislation specific for the substance or <br />mixture <br />· National regulations <br />· Technical instructions (air): <br />· Class Share in % <br />· NK <br />51.4 <br />· Water hazard class: <br />Water hazard class 2 (Self-assessment): hazardous for water. <br />The classification based on german instructions. <br />· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.</p> <p>*</p> <p>SECTION 16: Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for <br />any specific product features and shall not establish a legally valid contractual relationship. <br />· Relevant phrases <br />H225 Highly flammable liquid and vapour. <br />H304 May be fatal if swallowed and enters airways. <br />H315 Causes skin irritation. <br />H317 May cause an allergic skin reaction. <br />H319 Causes serious eye irritation. <br />H336 May cause drowsiness or dizziness. <br />H361d Suspected of damaging the unborn child. <br />H373 May cause damage to organs through prolonged or repeated exposure. <br />(Contd. on page 9) <br />GB</p> <p>40.0</p> <p>Page 9/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.03.2015</p> <p>Version number 8</p> <p>Revision: 16.03.2015</p> <p>Trade name: Primer-2000 S (A-Komp.) <br />(Contd. of page 8)</p> <p>H411</p> <p>Toxic to aquatic life with long lasting effects.</p> <p>R11 <br />Highly flammable. <br />R36 <br />Irritating to eyes. <br />R36/38 Irritating to eyes and skin. <br />R38 <br />Irritating to skin. <br />R43 <br />May cause sensitisation by skin contact. <br />R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. <br />R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic <br />environment. <br />R63 <br />Possible risk of harm to the unborn child. <br />R65 <br />Harmful: may cause lung damage if swallowed. <br />R66 <br />Repeated exposure may cause skin dryness or cracking. <br />R67 <br />Vapours may cause drowsiness and dizziness. <br />· Department issuing data specification sheet: Environment protection department. <br />· Contact: Mr. Guido Herfort <br />· Abbreviations and acronyms: <br />ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the <br />International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />GHS: Globally Harmonised System of Classification and Labelling of Chemicals <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />Flam. Liq. 2: Flammable liquids, Hazard Category 2 <br />Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 <br />Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 <br />Skin Sens. 1: Sensitisation - Skin, Hazard Category 1 <br />Repr. 2: Reproductive toxicity, Hazard Category 2 <br />STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 <br />STOT RE 2: Specific target organ toxicity - Repeated exposure, Hazard Category 2 <br />Asp. Tox. 1: Aspiration hazard, Hazard Category 1 <br />Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2 <br />Aquatic Chronic 3: Hazardous to the aquatic environment - Chronic Hazard, Category 3</p> <p>· * Data compared to the previous version altered. <br />GB</p>
