40.0
Page 1/10
Safety data sheet according to 1907/2006/EC, Article 31 Printing date 16.03.2015
Version number 11
Revision: 16.03.2015
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: INDUFLOOR-IB 1275 (A-Komp.) · Article number: 550063 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Priming · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: guido.herfort@schomburg.de SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS09 environment Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. GHS07 Skin Irrit. 2 Eye Irrit. 2 Skin Sens. 1
H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC Xi; Irritant R36/38: Irritating to eyes and skin. Xi; Sensitising R43:
May cause sensitisation by skin contact. N; Dangerous for the environment
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. · Information concerning particular hazards for human and environment: The product may not leak out in sewerage system, stretch of water or soil. The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. (Contd. on page 2) GB
Page 2/10
Trade name: INDUFLOOR-IB 1275 (A-Komp.) (Contd. of page 1)
· Classification system: The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information furnished by supplier companies. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS07, GHS09 · Signal word Warning · Hazard-determining components of labelling: reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight = 700) bisphenol-F-epoxy resin oxirane, mono[(C12-14-alkyloxy)methyl] derivs · Hazard statements H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P363 Wash contaminated clothing before reuse. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · Additional information: Contains epoxy constituents. May produce an allergic reaction. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Mixture consisting of the following components. · Dangerous components: CAS: 25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number NLP: 500-033-5 average molecular weight = 700) Xi R36/38; Xi R43; N R51/53 Aquatic Chronic 2, H411; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317
25-50%
2.5-10%
CAS: 38640-62-9
Diisopropylnaphtalene Xn R65; N R51/53 Asp. Tox. 1, H304; Aquatic Chronic 4, H413
CAS: 9003-36-5 NLP: 500-006-8
bisphenol-F-epoxy resin 2.5-10% Xi R36/38; Xi R43; N R51/53 Aquatic Chronic 2, H411; Eye Irrit. 2, H319; Skin Sens. 1, H317
CAS: 68609-97-2 oxirane, mono[(C12-14-alkyloxy)methyl] derivs EINECS: 271-846-8 Xi R38; Xi R43 Skin Irrit. 2, H315; Skin Sens. 1, H317
2.5-10% (Contd. on page 3) GB
Page 3/10
Trade name: INDUFLOOR-IB 1275 (A-Komp.) (Contd. of page 2)
CAS: 100-51-6 Benzyl alcohol Xn R20/22 EINECS: 202-859-9 Acute Tox. 4, H302; Acute Tox. 4, H332; Eye Irrit. 2, H319
< 2.5%
CAS: 64742-95-6 Solvent naphtha (petroleum), light arom. EINECS: 265-199-0 Xn R65; Xi R37; N R51/53 R10-66-67 Flam. Liq. 3, H226; Asp. Tox. 1, H304; Aquatic Chronic 2, H411; STOT SE 3, H335-H336 · Additional information For the wording of the listed risk phrases refer to section 16.
< 0.5%
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. In case of unconsciousness bring patient into stable side position for transport. · After skin contact Instantly wash with water and soap and rinse thoroughly. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Show the pack or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. In case of strong heat burst- and explosion hazard, the pressure in the container will increase. In case of fire chill the container with water-spray. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. GB
(Contd. on page 4)
Page 4/10
Trade name: INDUFLOOR-IB 1275 (A-Komp.) (Contd. of page 3)
SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Ensure adequate ventilation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Keep away from children. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Clean skin only with cleaning agent especially for epoxy resin. Don't use solvent for skin cleaning! Clean clothes which are contaminate with epoxi resin before unsing again. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: Not required. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. (Contd. on page 5) GB
Page 5/10
Trade name: INDUFLOOR-IB 1275 (A-Komp.) (Contd. of page 4)
· Eye protection: Safety glasses · Body protection: Protective work clothing. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Liquid Colour: According to product specification · Smell: Characteristic · Odour threshold: Not determined. · pH-value:
Not determined.
· Change in condition Melting point/Melting range: Boiling point/Boiling range:
Not determined 201 °C
· Flash point:
Not applicable
· Inflammability (solid, gaseous)
Not applicable.
· Ignition temperature: Decomposition temperature:
· Self-inflammability:
Product is not selfigniting.
· Danger of explosion:
Product is not explosive.
· Critical values for explosion: Lower: Upper:
Not determined. Not determined.
· Steam pressure:
· Density at 20 °C · Relative density · Vapour density · Evaporation rate
1.6647 g/cm³ Not determined. Not determined. Not determined.
· Solubility in / Miscibility with Water:
Not miscible or difficult to mix
· Partition coefficient (n-octanol/water): Not determined. · Viscosity: dynamic: kinematic: · 9.2 Other information
Not determined. Not determined. No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions Reacts with strong acids and oxidizing agents · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. (Contd. on page 6) GB
Page 6/10
Trade name: INDUFLOOR-IB 1275 (A-Komp.) (Contd. of page 5)
· 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: 25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight = 700) Oral LD50 >5000 mg/kg (rats) Dermal LD50 >2000 mg/kg (rats) 38640-62-9 Diisopropylnaphtalene Oral LD50 >3900 mg/kg (rats) Dermal LD50 >4500 mg/kg (rats) Inhalative LC 50 5.64 mg/l (rats) 9003-36-5 bisphenol-F-epoxy resin Oral LD50 >5000 mg/kg (rats) 68609-97-2 oxirane, mono[(C12-14-alkyloxy)methyl] derivs Oral LD50 >5000 mg/kg (rats) Dermal LD50 >4500 mg/kg (rabbit) 100-51-6 Benzyl alcohol Oral LD50 1040 mg/kg (mou) 1230 mg/kg (rats) 1040 mg/kg (rbt) Dermal LD50 2000 mg/kg (rbt) 64742-95-6 Solvent naphtha (petroleum), light arom. Oral LD50 >2000 mg/kg (rats) Dermal LD50 >2000 mg/kg (rabbit) Inhalative LC50/4 h >5 mg/l (rats) · Primary irritant effect: · on the skin: Irritant for skin and mucous membranes. The produkt has an irritate-effect. · on the eye: Irritant effect. · Sensitisation: Sensitization possible by skin contact. · Additional toxicological information: The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for Preparations as issued in the latest version: Irritant Sensitizing SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight = 700) EC50 (24h) 3.6 mg/l (Daphnia magna) LC50 (96h) 1.5 mg/l (rainbow trout) (Contd. on page 7) GB
Page 7/10
Trade name: INDUFLOOR-IB 1275 (A-Komp.) (Contd. of page 6)
38640-62-9 Diisopropylnaphtalene EC0 (72h) 0.15 mg/l (algae toxicity) (48h) 0.16 mg/l (Daphnia (acute) toxicity) LC 0 (96h) 0.5 mg/l (fish toxicity) 9003-36-5 bisphenol-F-epoxy resin EC50 2 mg/l (Daphnia (acute) toxicity) LC50/96h 2 mg/l (fish toxicity) 68609-97-2 oxirane, mono[(C12-14-alkyloxy)methyl] derivs EC50 (48h) 1-10 mg/l (Daphnia magna) EC50 (96h) 1-10 mg/l (fish toxicity) 100-51-6 Benzyl alcohol LC/EC50 (96h) 645 mg/l (orfe) 10 mg/l (Lepomis macrochius) 64742-95-6 Solvent naphtha (petroleum), light arom. LC/EC/IC 50 1-10 mg/l (algae toxicity) 1-10 mg/l (Daphnia (acute) toxicity) · 12.2 Persistence and degradability 25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight = 700) 301B (Mod. Sturm) 12 % (-) · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Ecotoxical effects: 100-51-6 Benzyl alcohol EC 50 400 mg/l (Daphnia (acute) toxicity) · Remark: Toxic for fish · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. Toxic for aquatic organisms · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. GB
(Contd. on page 8)
Page 8/10
Trade name: INDUFLOOR-IB 1275 (A-Komp.) (Contd. of page 7)
SECTION 14: Transport information · 14.1 UN-Number · ADR, IMDG, IATA · 14.2 UN proper shipping name · ADR
· IMDG
· IATA
UN3082 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A(epichlorhydrin); epoxy resin(number average molecular weight<700), Diisopropylnaphtalene) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A-(epichlorhydrin); epoxy resin(number average molecular weight<700), Diisopropylnaphthalin-Isomere), MARINE POLLUTANT ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A-(epichlorhydrin); epoxy resin(number average molecular weight<700), Diisopropylnaphthalin-Isomere)
· 14.3 Transport hazard class(es) · ADR, IMDG, IATA
· Class · Label
9 Miscellaneous dangerous substances and articles. 9
· 14.4 Packing group · ADR, IMDG, IATA
III
· 14.5 Environmental hazards: · Marine pollutant: · Special marking (ADR): · Special marking (IATA): · 14.6 Special precautions for user · Kemler Number: · EMS Number:
Product contains environmentally hazardous substances: bisphenol A-(epichlorhydrin); epoxy resin(number average molecular weight<700) Yes Symbol (fish and tree) Symbol (fish and tree) Symbol (fish and tree) Warning: Miscellaneous dangerous substances and articles. 90 F-A,S-F
· 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional information: · ADR · Limited quantities (LQ) · Transport category · Tunnel restriction code
5L 3 E (Contd. on page 9) GB
Page 9/10
Trade name: INDUFLOOR-IB 1275 (A-Komp.) (Contd. of page 8)
· UN "Model Regulation":
UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A(epichlorhydrin); epoxy resin(number average molecular weight<700), Diisopropylnaphtalene), 9, III
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · National regulations · Technical instructions (air): · Class Share in % · NK 0.3 · Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water. The classification based on german instructions. · Other regulations, limitations and prohibitive regulations · Substances of very high concern (SVHC) according to REACH, Article 57 872-50-4 1-methyl-2-pyrrolidone · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H411 Toxic to aquatic life with long lasting effects. H413 May cause long lasting harmful effects to aquatic life. R10 Flammable. R20/22 Harmful by inhalation and if swallowed. R36/38 Irritating to eyes and skin. R37 Irritating to respiratory system. R38 Irritating to skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort (Contd. on page 10) GB
Page 10/10
Trade name: INDUFLOOR-IB 1275 (A-Komp.) (Contd. of page 9)
· Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Flam. Liq. 3: Flammable liquids, Hazard Category 3 Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 Skin Sens. 1: Sensitisation - Skin, Hazard Category 1 STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 Asp. Tox. 1: Aspiration hazard, Hazard Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2 Aquatic Chronic 4: Hazardous to the aquatic environment - Chronic Hazard, Category 4
· * Data compared to the previous version altered. GB