40.0
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 13.03.2015 *
Version number 4
Revision: 13.03.2015
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: INDUFLEX-VK-TKF-2000 mv (B-Komp.) · Article number: 555133B · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture hardener component · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: guido.herfort@schomburg.de SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS09 environment Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. GHS07 Acute Tox. 4 Skin Irrit. 2 Eye Irrit. 2 Skin Sens. 1
H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC Xn; Harmful R22:
Harmful if swallowed. Xi; Irritant
R36/38: Irritating to eyes and skin. Xi; Sensitising R43:
May cause sensitisation by skin contact. N; Dangerous for the environment (Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 13.03.2015
Trade name: INDUFLEX-VK-TKF-2000 mv (B-Komp.) (Contd. of page 1)
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. · Information concerning particular hazards for human and environment: The product may not leak out in sewerage system, stretch of water or soil. The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. · Classification system: The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information furnished by supplier companies. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS07, GHS09 · Signal word Warning · Hazard-determining components of labelling: manganese dioxide zinc bis(diethyldithiocarbamate) · Hazard statements H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312 Call a POISON CENTER/doctor if you feel unwell. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Mixture consisting of the following components. · Dangerous components: CAS: 27138-31-4 Oxydipropyldibenzoat N R51/53 Aquatic Chronic 2, H411 CAS: 1313-13-9 manganese dioxide EINECS: 215-202-6 Xn R20/22 Acute Tox. 4, H302; Acute Tox. 4, H332
25-50%
25-50% (Contd. on page 3) GB
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Trade name: INDUFLEX-VK-TKF-2000 mv (B-Komp.) (Contd. of page 2)
CAS: 14324-55-1 zinc bis(diethyldithiocarbamate) < 2.5% Xn R22; Xi R36/37/38; Xi R43; N R50/53 EINECS: 238-270-9 Aquatic Acute 1, H400; Aquatic Chronic 1, H410; Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335 CAS: 1310-73-2 sodium hydroxide EINECS: 215-185-5 C R35 Skin Corr. 1A, H314 · Additional information For the wording of the listed risk phrases refer to section 16. *
< 1%
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact Instantly wash with water and soap and rinse thoroughly. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. · After swallowing Do not induce vomiting; instantly call for medical help. Show the pack or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · For safety reasons unsuitable extinguishing agents Water with a full water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. (Contd. on page 4) GB
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Trade name: INDUFLEX-VK-TKF-2000 mv (B-Komp.) (Contd. of page 3)
See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Keep away from children. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Store in cool location. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. Store in a locked cabinet and out of the reach of children. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: Not required. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Viscous Colour: Dark brown (Contd. on page 5) GB
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Trade name: INDUFLEX-VK-TKF-2000 mv (B-Komp.) (Contd. of page 4)
· Smell:
Characteristic
· Change in condition Melting point/Melting range: Not determined Boiling point/Boiling range: Not determined · Flash point:
> 150 °C
· Ignition temperature:
400 °C
· Self-inflammability:
Product is not selfigniting.
· Danger of explosion:
Product is not explosive.
· Density at 20 °C
1.81 g/cm³
· Solubility in / Miscibility with Water: Not miscible or difficult to mix · Viscosity: dynamic at 20 °C: · 9.2 Other information
25000 mPas No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known *
SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: 27138-31-4 Oxydipropyldibenzoat Oral LD50 5313 mg/kg (rats) Dermal LD50 > 2000 mg/kg (rats) 1313-13-9 manganese dioxide Oral LD50 14900 mg/kg (rats) 14324-55-1 zinc bis(diethyldithiocarbamate) Oral LD50 1400 mg/kg (Maus) 400 - 570 mg/kg (rabbit) 700 - 3530 mg/kg (rats) Dermal LD50 > 3160 mg/kg (rabbit) > 2000 mg/kg (rats) Inhalative LC50/4 h 0.026 - 0.081 mg/l (rats) 1310-73-2 sodium hydroxide Oral LD50 2000 mg/kg (rats) · Primary irritant effect: · on the skin: Irritant for skin and mucous membranes. (Contd. on page 6) GB
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Trade name: INDUFLEX-VK-TKF-2000 mv (B-Komp.) (Contd. of page 5)
· on the eye: Irritant effect. · Sensitisation: Sensitization possible by skin contact. · Additional toxicological information: The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for Preparations as issued in the latest version: Harmful Irritant Sensitizing *
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 27138-31-4 Oxydipropyldibenzoat EC 50 19.3 mg/kg (Daphnia (acute) toxicity) 14324-55-1 zinc bis(diethyldithiocarbamate) EC 50 0.24 - 0.44 mg/kg (Daphnia (acute) toxicity) 1310-73-2 sodium hydroxide LC50 (48h) 133 mg/l (orfe) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Ecotoxical effects: · Remark: Toxic for fish · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS 08 04 00 wastes from MFSU of adhesives and sealants (including waterproofing products) 08 04 09* waste adhesives and sealants containing organic solvents or other dangerous substances · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations.
*
SECTION 14: Transport information · 14.1 UN-Number · ADR, IMDG, IATA
UN3082 (Contd. on page 7) GB
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Trade name: INDUFLEX-VK-TKF-2000 mv (B-Komp.) (Contd. of page 6)
· 14.2 UN proper shipping name · ADR · IMDG · IATA
3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (zinc bis(diethyldithiocarbamate)) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM HYDROXIDE, manganese dioxide), MARINE POLLUTANT ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM HYDROXIDE, manganese dioxide)
· 14.3 Transport hazard class(es) · ADR
· Class · Label
9 Miscellaneous dangerous substances and articles. 9
· IMDG, IATA
8 Corrosive substances. 9
· 14.4 Packing group · ADR, IMDG, IATA
III
· 14.5 Environmental hazards: · Marine pollutant: · Special marking (ADR): · Special marking (IATA): · 14.6 Special precautions for user · Kemler Number: · EMS Number: · Segregation groups
Product contains environmentally hazardous substances: Oxydipropyldibenzoat, zinc bis(diethyldithiocarbamate) Yes Symbol (fish and tree) Symbol (fish and tree) Symbol (fish and tree) Warning: Miscellaneous dangerous substances and articles. 90 F-A,S-F Alkalis
· 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional information: · ADR · Limited quantities (LQ) · Transport category · Tunnel restriction code
5L 3 E (Contd. on page 8) GB
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Trade name: INDUFLEX-VK-TKF-2000 mv (B-Komp.) (Contd. of page 7)
· UN "Model Regulation":
UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (zinc bis(diethyldithiocarbamate)), 9, III
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · National regulations · Technical instructions (air): · Class Share in % · III 40.3 · Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water. The classification based on german instructions. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. *
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. R20/22 Harmful by inhalation and if swallowed. R22 Harmful if swallowed. R35 Causes severe burns. R36/37/38 Irritating to eyes, respiratory system and skin. R43 May cause sensitisation by skin contact. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Corr. 1A: Skin corrosion/irritation, Hazard Category 1A (Contd. on page 9) GB
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Trade name: INDUFLEX-VK-TKF-2000 mv (B-Komp.) (Contd. of page 8) Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 Skin Sens. 1: Sensitisation - Skin, Hazard Category 1 STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 Aquatic Acute 1: Hazardous to the aquatic environment - AcuteHazard, Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - Chronic Hazard, Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2
· * Data compared to the previous version altered. GB