ESCO-FLUAT.pdf
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<h1>ESCO-FLUAT.pdf</h1> <p>40.0</p> <p>Page 1/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 12.03.2015</p> <p>Version number 14</p> <p>Revision: 11.03.2015</p> <p>SECTION 1: Identification of the substance/mixture and of the company/undertaking <br />· 1.1 Product identifier <br />· Trade name: ESCO-FLUAT <br />· Article number: 204146 <br />· 1.2 Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture salt treatment (neutralization agent) <br />· 1.3 Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />Fax: ++49 (0)5231/953-123 <br />email: info@schomburg.de <br />web: www.schomburg.de <br />· Informing department: <br />Product Safety Department <br />Tel: ++49 (0)5231/953-193 <br />Fax: ++49 (0)5231/953-106 <br />email: guido.herfort@schomburg.de <br />SECTION 2: Hazards identification <br />· 2.1 Classification of the substance or mixture <br />· Classification according to Regulation (EC) No 1272/2008 <br />GHS05 corrosion <br />Skin Corr. 1C H314 Causes severe skin burns and eye damage. <br />GHS07 <br />Acute Tox. 4 H302 Harmful if swallowed. <br />· Classification according to Directive 67/548/EEC or Directive 1999/45/EC <br />Xn; Harmful <br />R22: Harmful if swallowed. <br />· Classification system: <br />The classification is in line with current EC lists. It is expanded, however, by information from <br />technical literature and by information furnished by supplier companies. <br />· 2.2 Label elements <br />· Labelling according to Regulation (EC) No 1272/2008 <br />The product is classified and labelled according to the CLP regulation. <br />· Hazard pictograms GHS05, GHS07 <br />· Signal word Danger <br />· Hazard-determining components of labelling: <br />zinc hexafluorosilicate <br />· Hazard statements <br />H302 Harmful if swallowed. <br />H314 Causes severe skin burns and eye damage. <br />(Contd. on page 2) <br />GB</p> <p>40.0</p> <p>Page 2/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 12.03.2015</p> <p>Version number 14</p> <p>Revision: 11.03.2015</p> <p>Trade name: ESCO-FLUAT <br />(Contd. of page 1)</p> <p>· Precautionary statements <br />P260 <br />Do not breathe dust/fume/gas/mist/vapours/spray. <br />P280 <br />Wear protective gloves/protective clothing/eye protection/face protection. <br />P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. <br />Rinse skin with water/shower. <br />P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact <br />lenses, if present and easy to do. Continue rinsing. <br />P405 <br />Store locked up. <br />P501 <br />Dispose of contents/container in accordance with local/regional/national/ <br />international regulations. <br />· 2.3 Other hazards <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />SECTION 3: Composition/information on ingredients <br />· 3.2 Chemical characterisation: Mixtures <br />· Description: aqueous hexafluorosilicate solution <br />· Dangerous components: <br />CAS: 16871-71-9 zinc hexafluorosilicate <br />EINECS: 240-894-1 <br />Xn R22 <br />Acute Tox. 4, H302</p> <p>50-100%</p> <p>SECTION 4: First aid measures <br />· 4.1 Description of first aid measures <br />· General information <br />Personal protection for the First Aider. <br />Symptoms of poisoning may even occur after several hours; therefore medical observation for at <br />least 48 hours after the accident. <br />Instantly remove any clothing soiled by the product. <br />It is possible to choke in case of vomiting in unconsciousness. <br />Bring unconscious persons into a stable position on side. <br />Keep the respiratory tract free (remove dentures and vomiting). <br />Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage <br />of breathing: artificial respiration. <br />Take up a doctor immediately! <br />· After inhalation Supply fresh air or oxygen; call for doctor. <br />· After skin contact <br />Change immediately contaminated clothes. <br />Instantly wash with water and soap and rinse thoroughly. <br />· After eye contact Rinse opened eye for several minutes under running water. <br />· After swallowing Do not induce vomiting; instantly call for medical help. <br />· 4.2 Most important symptoms and effects, both acute and delayed <br />No further relevant information available. <br />· 4.3 Indication of any immediate medical attention and special treatment needed <br />No further relevant information available. <br />SECTION 5: Firefighting measures <br />· 5.1 Extinguishing media <br />· Suitable extinguishing agents <br />Product is not inflammable. <br />Use fire fighting measures that suit the environment. <br />(Contd. on page 3) <br />GB</p> <p>40.0</p> <p>Page 3/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 12.03.2015</p> <p>Version number 14</p> <p>Revision: 11.03.2015</p> <p>Trade name: ESCO-FLUAT <br />(Contd. of page 2)</p> <p>· 5.2 Special hazards arising from the substance or mixture <br />No further relevant information available. <br />· 5.3 Advice for firefighters <br />· Protective equipment: <br />Wear self-contained breathing apparatus. <br />Wear full protective suit. <br />· Additional information <br />Cool endangered containers with water spray jet. <br />Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. <br />SECTION 6: Accidental release measures <br />· 6.1 Personal precautions, protective equipment and emergency procedures <br />Wear protective equipment. Keep unprotected persons away. <br />Ensure adequate ventilation <br />· 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. <br />· 6.3 Methods and material for containment and cleaning up: <br />Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). <br />· 6.4 Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />SECTION 7: Handling and storage <br />· 7.1 Precautions for safe handling <br />Ensure good ventilation/exhaustion at the workplace. <br />Open and handle container with care. <br />· Information about protection against explosions and fires: Protect from heat. <br />· 7.2 Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: Provide floor trough without outlet. <br />· Information about storage in one common storage facility: <br />Store away from foodstuffs. <br />Please follow the rules of the VCI-Storage-Concept for chemicals. <br />· Further information about storage conditions: Protect from frost. <br />· 7.3 Specific end use(s) No further relevant information available. <br />SECTION 8: Exposure controls/personal protection <br />· Additional information about design of technical systems: No further data; see item 7 MSDS. <br />· 8.1 Control parameters <br />· Components with critical values that require monitoring at the workplace: <br />The product does not contain any relevant quantities of materials with critical values that have to be <br />monitored at the workplace. <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· 8.2 Exposure controls <br />· Personal protective equipment <br />· General protective and hygienic measures <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />Wash hands during breaks and at the end of the work. <br />Avoid contact with the eyes and skin. <br />Ensure that washing facilities are available in the work place. <br />· Breathing equipment: Not required. <br />· Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. <br />(Contd. on page 4) <br />GB</p> <p>40.0</p> <p>Page 4/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 12.03.2015</p> <p>Version number 14</p> <p>Revision: 11.03.2015</p> <p>Trade name: ESCO-FLUAT <br />(Contd. of page 3)</p> <p>· Material of gloves <br />Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min <br />· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and <br />has to be observed. <br />· Eye protection: Safety glasses <br />· Body protection: Acid resistant protective clothing <br />SECTION 9: Physical and chemical properties <br />· 9.1 Information on basic physical and chemical properties <br />· General Information <br />· Appearance: <br />Form: <br />Fluid <br />Colour: <br />Clear <br />· Smell: <br />Odourless <br />· pH-value at 20 °C:</p> <p>2</p> <p>· Change in condition <br />Melting point/Melting range: Not determined <br />Boiling point/Boiling range: Not determined <br />· Flash point:</p> <p>Not applicable</p> <p>· Self-inflammability:</p> <p>Product is not selfigniting.</p> <p>· Danger of explosion:</p> <p>Product is not explosive.</p> <p>· Density at 20 °C</p> <p>1.34 g/cm³</p> <p>· Solubility in / Miscibility with <br />Water: <br />Fully miscible <br />· 9.2 Other information <br />No further relevant information available.</p> <p>SECTION 10: Stability and reactivity <br />· 10.1 Reactivity <br />· 10.2 Chemical stability <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· 10.3 Possibility of hazardous reactions No dangerous reactions known <br />· 10.4 Conditions to avoid No further relevant information available. <br />· 10.5 Incompatible materials: No further relevant information available. <br />· 10.6 Hazardous decomposition products: No dangerous decomposition products known <br />SECTION 11: Toxicological information <br />· 11.1 Information on toxicological effects <br />· Acute toxicity: <br />· LD/LC50 values that are relevant for classification: No dates existing. <br />· Primary irritant effect: <br />· on the skin: Irritant for skin and mucous membranes. <br />· on the eye: Irritant effect. <br />· Sensitisation: No sensitizing effect known. <br />(Contd. on page 5) <br />GB</p> <p>40.0</p> <p>Page 5/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 12.03.2015</p> <p>Version number 14</p> <p>Revision: 11.03.2015</p> <p>Trade name: ESCO-FLUAT <br />(Contd. of page 4)</p> <p>· Additional toxicological information: <br />The product shows the following dangers according to the calculation method of the General EC <br />Classification Guidelines for Preparations as issued in the latest version: <br />Harmful <br />SECTION 12: Ecological information <br />· 12.1 Toxicity <br />· Aquatic toxicity: No further relevant information available. <br />· 12.2 Persistence and degradability No further relevant information available. <br />· 12.3 Bioaccumulative potential No further relevant information available. <br />· 12.4 Mobility in soil No further relevant information available. <br />· Additional ecological information: <br />· General notes: <br />Water hazard class 2 (Self-assessment): hazardous for water. <br />Do not allow product to reach ground water, water bodies or sewage system. <br />· 12.5 Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />· 12.6 Other adverse effects No further relevant information available. <br />SECTION 13: Disposal considerations <br />· 13.1 Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />· European waste catalogue <br />06 00 00 WASTES FROM INORGANIC CHEMICAL PROCESSES <br />06 03 00 wastes from the MFSU of salts and their solutions and metallic oxides <br />06 03 13* solid salts and solutions containing heavy metals <br />· Uncleaned packagings: <br />· Recommendation: Disposal must be made according to official regulations. <br />· Recommended cleaning agent: Water, if necessary with cleaning agent. <br />SECTION 14: Transport information <br />· 14.1 UN-Number <br />· ADR, IMDG, IATA <br />· 14.2 UN proper shipping name <br />· ADR <br />· IMDG <br />· IATA</p> <p>UN3082 <br />3082 ENVIRONMENTALLY HAZARDOUS <br />SUBSTANCE, LIQUID, N.O.S. (ZINC <br />FLUOROSILICATE) <br />ENVIRONMENTALLY HAZARDOUS SUBSTANCE, <br />LIQUID, N.O.S. (ZINC FLUOROSILICATE), <br />MARINE POLLUTANT <br />ENVIRONMENTALLY HAZARDOUS SUBSTANCE, <br />LIQUID, N.O.S. (ZINC FLUOROSILICATE) <br />(Contd. on page 6) <br />GB</p> <p>40.0</p> <p>Page 6/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 12.03.2015</p> <p>Version number 14</p> <p>Revision: 11.03.2015</p> <p>Trade name: ESCO-FLUAT <br />(Contd. of page 5)</p> <p>· 14.3 Transport hazard class(es) <br />· ADR, IMDG, IATA</p> <p>· Class <br />· Label</p> <p>9 Miscellaneous dangerous substances and <br />articles. <br />9</p> <p>· 14.4 Packing group <br />· ADR, IMDG, IATA</p> <p>III</p> <p>· 14.5 Environmental hazards: <br />· Marine pollutant: <br />· Special marking (ADR): <br />· Special marking (IATA):</p> <p>Symbol (fish and tree) <br />Symbol (fish and tree) <br />Symbol (fish and tree)</p> <p>· 14.6 Special precautions for user <br />· Kemler Number: <br />· EMS Number: <br />· Segregation groups</p> <p>Warning: Miscellaneous dangerous substances and <br />articles. <br />90 <br />F-A,S-F <br />Heavy metals and their salts (including their <br />organometallic compounds)</p> <p>· 14.7 Transport in bulk according to Annex II <br />of MARPOL73/78 and the IBC Code <br />Not applicable. <br />· Transport/Additional information: <br />· ADR <br />· Limited quantities (LQ) <br />· Excepted quantities (EQ) <br />· Transport category <br />· Tunnel restriction code <br />· IMDG <br />· Limited quantities (LQ) <br />· Excepted quantities (EQ)</p> <p>· UN "Model Regulation":</p> <p>5L <br />Code: E1 <br />Maximum net quantity per inner packaging: 30 ml <br />Maximum net quantity per outer packaging: 1000 ml <br />3 <br />E <br />5 kg <br />Code: E1 <br />Maximum net quantity per inner packaging: 30 ml <br />Maximum net quantity per outer packaging: 1000 ml <br />UN3082, ENVIRONMENTALLY HAZARDOUS <br />SUBSTANCE, LIQUID, N.O.S. (ZINC <br />FLUOROSILICATE), 9, III</p> <p>SECTION 15: Regulatory information <br />· 15.1 Safety, health and environmental regulations/legislation specific for the substance or <br />mixture <br />· National regulations <br />· Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water. <br />· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. <br />GB</p> <p>(Contd. on page 7)</p> <p>40.0</p> <p>Page 7/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 12.03.2015</p> <p>Version number 14</p> <p>Revision: 11.03.2015</p> <p>Trade name: ESCO-FLUAT <br />(Contd. of page 6)</p> <p>SECTION 16: Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for <br />any specific product features and shall not establish a legally valid contractual relationship. <br />· Relevant phrases <br />H302 Harmful if swallowed. <br />R22 Harmful if swallowed. <br />· Department issuing data specification sheet: Environment protection department. <br />· Contact: Mr. Guido Herfort <br />· Abbreviations and acronyms: <br />ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the <br />International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />GHS: Globally Harmonised System of Classification and Labelling of Chemicals <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />Acute Tox. 4: Acute toxicity, Hazard Category 4 <br />Skin Corr. 1C: Skin corrosion/irritation, Hazard Category 1C <br />GB</p>
