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<h1>Blankol_Super.pdf</h1> <p>40.0</p> <p>Page 1/6</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.04.2015 <br />*</p> <p>Version number 5</p> <p>Revision: 16.04.2015</p> <p>SECTION 1: Identification of the substance/mixture and of the company/undertaking <br />· 1.1 Product identifier <br />· Trade name: Blankol Super <br />· 1.2 Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture release agent <br />· 1.3 Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />Fax: ++49 (0)5231/953-123 <br />email: info@schomburg.de <br />web: www.schomburg.de <br />· Informing department: <br />Product Safety Department <br />Tel: ++49 (0)5231/953-193 <br />Fax: ++49 (0)5231/953-106 <br />email: guido.herfort@schomburg.de</p> <p>*</p> <p>SECTION 2: Hazards identification <br />· 2.1 Classification of the substance or mixture <br />· Classification according to Regulation (EC) No 1272/2008 <br />GHS08 health hazard <br />Asp. Tox. 1 H304 May be fatal if swallowed and enters airways. <br />· Classification according to Directive 67/548/EEC or Directive 1999/45/EC <br />Xn; Harmful <br />R65: Harmful: may cause lung damage if swallowed. <br />R66: Repeated exposure may cause skin dryness or cracking. <br />· Information concerning particular hazards for human and environment: <br />Swallow up and vomiting may cause aspiration into the lungs, which could lead to chemical <br />pneumonia or suffocation. <br />· Classification system: <br />The classification is in line with current EC lists. It is expanded, however, by information from <br />technical literature and by information furnished by supplier companies. <br />· 2.2 Label elements <br />· Labelling according to Regulation (EC) No 1272/2008 <br />The product is classified and labelled according to the CLP regulation. <br />· Hazard pictograms GHS08 <br />· Signal word Danger <br />· Hazard-determining components of labelling: <br />Naphtha (petroleum), hydrotreated heavy <br />· Hazard statements <br />H304 May be fatal if swallowed and enters airways. <br />· Precautionary statements <br />P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. <br />P363 <br />Wash contaminated clothing before reuse. <br />(Contd. on page 2) <br />GB</p> <p>40.0</p> <p>Page 2/6</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.04.2015</p> <p>Version number 5</p> <p>Revision: 16.04.2015</p> <p>Trade name: Blankol Super <br />(Contd. of page 1)</p> <p>P405 <br />P501</p> <p>Store locked up. <br />Dispose of contents/container in accordance with local/regional/national/international <br />regulations. <br />· 2.3 Other hazards <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />*</p> <p>SECTION 3: Composition/information on ingredients <br />· 3.2 Chemical characterisation: Mixtures <br />· Description: Preparation, contains paraffinic and naphtenic hydrocarbons. <br />· Dangerous components: <br />CAS: 64742-48-9 Naphtha (petroleum), hydrotreated heavy <br />Xn R65 <br />EINECS: 265-150-3 <br />R66 <br />Asp. Tox. 1, H304</p> <p>10-25%</p> <p>SECTION 4: First aid measures <br />· 4.1 Description of first aid measures <br />· General information <br />Personal protection for the First Aider. <br />It is possible to choke in case of vomiting in unconsciousness. <br />Bring unconscious persons into a stable position on side. <br />Keep the respiratory tract free (remove dentures and vomiting). <br />Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage <br />of breathing: artificial respiration. <br />Take up a doctor immediately! <br />· After inhalation Supply fresh air; consult doctor in case of symptoms. <br />· After skin contact <br />Instantly wash with water and soap and rinse thoroughly. <br />Change immediately heavy contaminated clothes. <br />· After eye contact Rinse opened eye for several minutes under running water. <br />· After swallowing <br />Do not induce vomiting; instantly call for medical help. <br />Do not give household remedys (milk, alcohol etc.) <br />Show the pack or the label to the doctor. <br />· 4.2 Most important symptoms and effects, both acute and delayed <br />No further relevant information available. <br />· 4.3 Indication of any immediate medical attention and special treatment needed <br />No further relevant information available. <br />SECTION 5: Firefighting measures <br />· 5.1 Extinguishing media <br />· Suitable extinguishing agents <br />CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. <br />· For safety reasons unsuitable extinguishing agents Water with a full water jet. <br />· 5.2 Special hazards arising from the substance or mixture <br />Formation of poisonous gases during heating or in fires. <br />In case of strong heat burst- and explosion hazard, the pressure in the container will increase. In <br />case of fire chill the container with water-spray. <br />· 5.3 Advice for firefighters <br />· Protective equipment: Wear self-contained breathing apparatus. <br />(Contd. on page 3) <br />GB</p> <p>40.0</p> <p>Page 3/6</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.04.2015</p> <p>Version number 5</p> <p>Revision: 16.04.2015</p> <p>Trade name: Blankol Super <br />(Contd. of page 2)</p> <p>· Additional information <br />Cool endangered containers with water spray jet. <br />Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. <br />*</p> <p>SECTION 6: Accidental release measures <br />· 6.1 Personal precautions, protective equipment and emergency procedures <br />Wear protective equipment. Keep unprotected persons away. <br />· 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. <br />· 6.3 Methods and material for containment and cleaning up: <br />Ensure adequate ventilation. <br />Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). <br />· 6.4 Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />See Section 13 for information on disposal.</p> <p>*</p> <p>SECTION 7: Handling and storage <br />· 7.1 Precautions for safe handling <br />Ensure good ventilation/exhaustion at the workplace. <br />Keep away from children. <br />· Information about protection against explosions and fires: <br />Keep ignition sources away - Do not smoke. <br />Do not spray on flames or red-hot objects. <br />Traces of flammable substances may collect in the voids of enclosed systems. Keep ignition <br />sources clear. <br />Protect against electrostatic charges. <br />· 7.2 Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: No special requirements. <br />· Information about storage in one common storage facility: <br />Dispose from explosive or flammable stuff. <br />· Further information about storage conditions: <br />Store in a locked cabinet and out of the reach of children. <br />· 7.3 Specific end use(s) No further relevant information available.</p> <p>*</p> <p>SECTION 8: Exposure controls/personal protection <br />· Additional information about design of technical systems: <br />It must be possible to wash the skin in the working area. <br />Eye-wash bottle must be available. <br />· 8.1 Control parameters <br />· Components with critical values that require monitoring at the workplace: <br />The product does not contain any relevant quantities of materials with critical values that have to be <br />monitored at the workplace. <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· 8.2 Exposure controls <br />· Personal protective equipment <br />· General protective and hygienic measures <br />Avoid contact with the eyes and skin. <br />Be sure to clean skin thoroughly after work and before breaks. <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />(Contd. on page 4) <br />GB</p> <p>40.0</p> <p>Page 4/6</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.04.2015</p> <p>Version number 5</p> <p>Revision: 16.04.2015</p> <p>Trade name: Blankol Super <br />(Contd. of page 3)</p> <p>· Breathing equipment: <br />In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer <br />exposure use breathing apparatus that is independent of circulating air. <br />· Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. <br />· Material of gloves <br />Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min <br />· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and <br />has to be observed. <br />· Eye protection: Safety glasses <br />· Body protection: Protective work clothing. <br />SECTION 9: Physical and chemical properties <br />· 9.1 Information on basic physical and chemical properties <br />· General Information <br />· Appearance: <br />Form: <br />Fluid <br />Colour: <br />Light yellow <br />· Smell: <br />Weak, characteristic <br />· pH-value at 20 °C:</p> <p>7.2</p> <p>· Change in condition <br />Melting point/Melting range: Not determined <br />Boiling point/Boiling range: 193 °C <br />· Flash point:</p> <p>95 °C</p> <p>· Ignition temperature:</p> <p>240 °C</p> <p>· Self-inflammability:</p> <p>Product is not selfigniting.</p> <p>· Danger of explosion:</p> <p>Heating may cause an explosion.</p> <p>· Critical values for explosion: <br />Lower: <br />0.6 Vol % <br />Upper: <br />7.0 Vol % <br />· Steam pressure:</p> <p>Not determined.</p> <p>· Density at 20 °C</p> <p>0.81 g/cm³</p> <p>· Solubility in / Miscibility with <br />Water: <br />Not miscible or difficult to mix <br />· Viscosity: <br />dynamic: <br />kinematic at 20 °C: <br />· 9.2 Other information</p> <p>Not determined. <br />14 s (ISO 4 mm) <br />No further relevant information available.</p> <p>SECTION 10: Stability and reactivity <br />· 10.1 Reactivity <br />· 10.2 Chemical stability <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· 10.3 Possibility of hazardous reactions No dangerous reactions known <br />· 10.4 Conditions to avoid No further relevant information available. <br />· 10.5 Incompatible materials: No further relevant information available. <br />(Contd. on page 5) <br />GB</p> <p>40.0</p> <p>Page 5/6</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.04.2015</p> <p>Version number 5</p> <p>Revision: 16.04.2015</p> <p>Trade name: Blankol Super <br />(Contd. of page 4)</p> <p>· 10.6 Hazardous decomposition products: No dangerous decomposition products known <br />*</p> <p>SECTION 11: Toxicological information <br />· 11.1 Information on toxicological effects <br />· Acute toxicity: <br />· LD/LC50 values that are relevant for classification: <br />64742-53-6 Distillates (petroleum), hydrotreated light naphthenic <br />Oral <br />LD50 > 5000 mg/kg (rats) <br />Dermal LD50 > 5000 mg/kg (rabbit) <br />64742-48-9 Naphtha (petroleum), hydrotreated heavy <br />Oral <br />LD50 >2000 mg/kg (rats) <br />Dermal LD50 >2000 mg/kg (rabbit) <br />Inhalative LC 50 >5 mg/l (rats) <br />· Primary irritant effect: <br />· on the skin: Effect of degreasing. <br />· Sensitisation: Sensitization possible by skin contact. <br />· Additional toxicological information: <br />The product shows the following dangers according to the calculation method of the General EC <br />Classification Guidelines for Preparations as issued in the latest version: <br />Harmful <br />SECTION 12: Ecological information <br />· 12.1 Toxicity <br />· Aquatic toxicity: No further relevant information available. <br />· 12.2 Persistence and degradability No further relevant information available. <br />· 12.3 Bioaccumulative potential No further relevant information available. <br />· 12.4 Mobility in soil No further relevant information available. <br />· Additional ecological information: <br />· General notes: <br />Water hazard class 1 (Self-assessment): slightly hazardous for water. <br />Do not allow undiluted product or large quantities of it to reach ground water, water bodies or <br />sewage system. <br />· 12.5 Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />· 12.6 Other adverse effects No further relevant information available. <br />SECTION 13: Disposal considerations <br />· 13.1 Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />· European waste catalogue <br />07 00 00 Wastes from organic chemical processes <br />07 01 00 waste from the manufacture, formulation, supply and use (MFSU) of basic organic <br />chemicals <br />07 01 04 other organic solvents, washing liquids and mother liquors <br />07 00 00 Wastes from organic chemical processes <br />07 03 00 waste from the MFSU of organic dyes and pigments (excluding 06 11 00) <br />(Contd. on page 6) <br />GB</p> <p>40.0</p> <p>Page 6/6</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.04.2015</p> <p>Version number 5</p> <p>Revision: 16.04.2015</p> <p>Trade name: Blankol Super <br />(Contd. of page 5)</p> <p>07 03 04 other organic solvents, washing liquids and mother liquors <br />· Uncleaned packagings: <br />· Recommendation: Disposal must be made according to official regulations. <br />SECTION 14: Transport information <br />· 14.1 UN-Number <br />· ADR</p> <p>Void</p> <p>· 14.2 UN proper shipping name <br />· ADR</p> <p>Void</p> <p>· 14.3 Transport hazard class(es) <br />· ADR <br />· Class</p> <p>Void</p> <p>· 14.4 Packing group <br />· ADR</p> <p>Void</p> <p>· 14.5 Environmental hazards: <br />· Marine pollutant:</p> <p>No</p> <p>· 14.6 Special precautions for user</p> <p>Not applicable.</p> <p>· 14.7 Transport in bulk according to Annex II <br />of MARPOL73/78 and the IBC Code <br />Not applicable.</p> <p>*</p> <p>SECTION 15: Regulatory information <br />· 15.1 Safety, health and environmental regulations/legislation specific for the substance or <br />mixture <br />· National regulations <br />· Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. <br />· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.</p> <p>*</p> <p>SECTION 16: Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for <br />any specific product features and shall not establish a legally valid contractual relationship. <br />· Relevant phrases <br />H304 May be fatal if swallowed and enters airways. <br />R65 Harmful: may cause lung damage if swallowed. <br />R66 Repeated exposure may cause skin dryness or cracking. <br />· Department issuing data specification sheet: Environment protection department. <br />· Contact: Mr. Guido Herfort <br />· Abbreviations and acronyms: <br />ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the <br />International Carriage of Dangerous Goods by Road) <br />GHS: Globally Harmonised System of Classification and Labelling of Chemicals <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />Asp. Tox. 1: Aspiration hazard, Hazard Category 1</p> <p>· * Data compared to the previous version altered. <br />GB</p>
