41.1.2
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 21.07.2015 *
Version number 14
Revision: 21.07.2015
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASODUR-SG3-Superfast (A-Comp.) · Article number: 203543 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture primer based on epoxy resin · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: guido.herfort@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS09 environment Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. GHS07 Skin Irrit. 2 Eye Irrit. 2 Skin Sens. 1
H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction.
· 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS07, GHS09 · Signal word Warning · Hazard-determining components of labelling: reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight = 700) 1,6-bis(2,3-ethoxypropoxy)hexane aliphatisches trimethyol-propantriglydylether bisphenol-F-epoxy resin · Hazard statements H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction.
(Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 21.07.2015
Trade name: ASODUR-SG3-Superfast (A-Comp.) (Contd. of page 1)
H411 Toxic to aquatic life with long lasting effects. · Precautionary statements P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P363 Wash contaminated clothing before reuse. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · Additional information: Contains epoxy constituents. May produce an allergic reaction. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Solvent- free preparation based on Bisphenol-A-Epichlorhydrin resin molecular weight ≤ 700. · Dangerous components: 50-100% CAS: 25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number NLP: 500-033-5 average molecular weight = 700) Aquatic Chronic 2, H411; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317
CAS: 16096-31-4 1,6-bis(2,3-ethoxypropoxy)hexane Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; Aquatic Chronic 3, H412
10-25%
CAS: 30499-70-8 aliphatisches trimethyol-propantriglydylether Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; Aquatic Chronic 3, H412
CAS: 9003-36-5 bisphenol-F-epoxy resin NLP: 500-006-8 Aquatic Chronic 2, H411; Eye Irrit. 2, H319; Skin Sens. 1, H317 · Additional information Contains epoxide-compounds. Note the index of the manufacturer. For the wording of the listed risk phrases refer to section 16.
2.5-10%
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor.
(Contd. on page 3) GB
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Trade name: ASODUR-SG3-Superfast (A-Comp.) (Contd. of page 2)
Supply fresh air and call for doctor for safety reasons. In case of unconsciousness bring patient into stable side position for transport. · After skin contact Don't use solvents to clean the skin. Instantly wash with water and soap and rinse thoroughly. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Do not give household remedys (milk, alcohol etc.) Show the pack or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures
· 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · For safety reasons unsuitable extinguishing agents Water with a full water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. In case of strong heat burst- and explosion hazard, the pressure in the container will increase. In case of fire chill the container with water-spray. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. Burst- and explosion-danger by increaseing pressure. In case of fire chill the container with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Avoid eye- and skin contact. Do not breath in vapour. Keep away from ignition sources Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding, inflammable material (sand, diatomite, acid binders, universal binder). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Keep containers tightly sealed. Work with fresh air supply, keep doors and windows open.
(Contd. on page 4) GB
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Trade name: ASODUR-SG3-Superfast (A-Comp.) (Contd. of page 3)
Keep away from heat and direct sunlight. Keep away from children. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Do not leave open containers. Do not store in common rooms. · Information about storage in one common storage facility: Store away from foodstuffs. Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Protect from frost. Keep container tightly sealed. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures Clean skin only with cleaning agent especially for epoxy resin. Don't use solvent for skin cleaning! Clean clothes which are contaminate with epoxi resin before unsing again. The usual precautionary measures should be adhered to in handling the chemicals. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: Not required. · Protection of hands: Nitril-rubber-latex-cotton gloves. · Material of gloves Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing. Contaminated protection clothes must be cleaned carfully before reuse.
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Liquid (Contd. on page 5) GB
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Trade name: ASODUR-SG3-Superfast (A-Comp.) (Contd. of page 4)
Colour: · Smell:
Colourless Weak, characteristic
· Change in condition Melting point/Melting range: Not determined Boiling point/Boiling range: Not determined · Flash point:
> 100 °C
· Self-inflammability:
Product is not selfigniting.
· Danger of explosion:
Product is not explosive.
· Steam pressure:
Not determined.
· Density at 20 °C
1.14 g/cm³
· Solubility in / Miscibility with Water: Not miscible or difficult to mix · Viscosity: dynamic at 20 °C: kinematic: · 9.2 Other information
730 mPas Not determined. No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions Reacts violently with oxidizing agents Reacts with strong acids and oxidizing agents · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: Can react with acid and oxidizing agends. · 10.6 Hazardous decomposition products: În case of heating dangerous decomposition products can be arise. *
SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity · LD/LC50 values that are relevant for classification: 25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight = 700) Oral LD50 >5000 mg/kg (rats) Dermal LD50 >2000 mg/kg (rats) 16096-31-4 1,6-bis(2,3-ethoxypropoxy)hexane Oral LD50 1400 mg/kg (rabbit) 2900 mg/kg (rats) Inhalative LC50/4 h >100 mg/l (Maus) 9003-36-5 bisphenol-F-epoxy resin Oral LD50 >5000 mg/kg (rats) · Primary irritant effect: · Skin corrosion/irritation Causes skin irritation.
(Contd. on page 6) GB
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Trade name: ASODUR-SG3-Superfast (A-Comp.) (Contd. of page 5)
· Serious eye damage/irritation Causes serious eye irritation. · Respiratory or skin sensitisation May cause an allergic skin reaction. · Additional toxicological information: Sensitizing · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. *
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight = 700) EC50 (24h) 3.6 mg/l (Daphnia magna) LC50 (96h) 1.5 mg/l (rainbow trout) 9003-36-5 bisphenol-F-epoxy resin EC50 2 mg/l (Daphnia (acute) toxicity) LC50/96h 2 mg/l (fish toxicity) · 12.2 Persistence and degradability 25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight = 700) 301B (Mod. Sturm) 12 % (-) · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Ecotoxical effects: · Remark: Toxic for fish · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. Danger to drinking water if even small quantities leak into soil. Also poisonous for fish and plankton in water bodies. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Cured materials which mixed with epoxy resin can put to the houshold-rubbish, after consulting the waste diposal. Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
(Contd. on page 7) GB
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Trade name: ASODUR-SG3-Superfast (A-Comp.) (Contd. of page 6)
· Uncleaned packagings: · Recommendation: Empty Containers with solid product rests can be supplied for recycling. Empty Containers including fluid product rests are hazardous waste. *
SECTION 14: Transport information · 14.1 UN-Number · ADR, IMDG, IATA · 14.2 UN proper shipping name · ADR
· IMDG
· IATA
UN3082 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A(epichlorhydrin); epoxy resin(number average molecular weight<700), 1,6Hexandioldiglycidylether) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A-(epichlorhydrin); epoxy resin(number average molecular weight<700), 1,6-Hexandioldiglycidylether), MARINE POLLUTANT ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A-(epichlorhydrin); epoxy resin(number average molecular weight<700), 1,6-Hexandioldiglycidylether)
· 14.3 Transport hazard class(es) · ADR, IMDG, IATA
· Class · Label
9 Miscellaneous dangerous substances and articles. 9
· 14.4 Packing group · ADR, IMDG, IATA
III
· 14.5 Environmental hazards: · Marine pollutant: · Special marking (ADR): · Special marking (IATA): · 14.6 Special precautions for user · Kemler Number: · EMS Number:
Yes Symbol (fish and tree) Symbol (fish and tree) Symbol (fish and tree) Warning: Miscellaneous dangerous substances and articles. 90 F-A,S-F
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · Transport/Additional information: · ADR · Limited quantities (LQ) · Transport category
5L 3 (Contd. on page 8) GB
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Trade name: ASODUR-SG3-Superfast (A-Comp.) (Contd. of page 7)
· Tunnel restriction code
E
· UN "Model Regulation":
UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A(epichlorhydrin); epoxy resin(number average molecular weight<700), 1,6-bis(2,3-ethoxypropoxy) hexane), 9, III
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · National regulations · Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water. The classification based on german instructions. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 Skin Sens. 1: Sensitisation - Skin, Hazard Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2 Aquatic Chronic 3: Hazardous to the aquatic environment - Chronic Hazard, Category 3
· * Data compared to the previous version altered.
GB