ASODUR-K900 comp.B.pdf
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<h1>ASODUR-K900 comp.B.pdf</h1> <p>40.0</p> <p>Page 1/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 03.06.2015 <br />*</p> <p>Version number 12</p> <p>Revision: 03.06.2015</p> <p>SECTION 1: Identification of the substance/mixture and of the company/undertaking <br />· 1.1 Product identifier <br />· Trade name: Asodur-K 900 (B-Komp.) <br />· Article number: 205070B <br />· 1.2 Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture Epoxy coating <br />· 1.3 Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />Fax: ++49 (0)5231/953-123 <br />email: info@schomburg.de <br />web: www.schomburg.de <br />· Informing department: <br />Product Safety Department <br />Tel: ++49 (0)5231/953-193 <br />Fax: ++49 (0)5231/953-106 <br />email: guido.herfort@schomburg.de</p> <p>*</p> <p>SECTION 2: Hazards identification <br />· 2.1 Classification of the substance or mixture <br />· Classification according to Regulation (EC) No 1272/2008 <br />GHS05 corrosion <br />Skin Corr. 1B <br />Eye Dam. 1</p> <p>H314 Causes severe skin burns and eye damage. <br />H318 Causes serious eye damage.</p> <p>GHS07 <br />Acute Tox. 4 <br />Acute Tox. 4 <br />Acute Tox. 4 <br />Skin Sens. 1</p> <p>H302 Harmful if swallowed. <br />H312 Harmful in contact with skin. <br />H332 Harmful if inhaled. <br />H317 May cause an allergic skin reaction.</p> <p>Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. <br />· Classification according to Directive 67/548/EEC or Directive 1999/45/EC <br />C; Corrosive <br />R34:</p> <p>Causes burns. <br />Xn; Harmful</p> <p>R20/21/22: Harmful by inhalation, in contact with skin and if swallowed. <br />Xi; Sensitising <br />(Contd. on page 2) <br />GB</p> <p>40.0</p> <p>Page 2/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 03.06.2015</p> <p>Version number 12</p> <p>Revision: 03.06.2015</p> <p>Trade name: Asodur-K 900 (B-Komp.) <br />(Contd. of page 1)</p> <p>R43: <br />R52/53:</p> <p>May cause sensitisation by skin contact. <br />Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic <br />environment. <br />· Information concerning particular hazards for human and environment: <br />The product is extremely hazardous for water. Don't pollute envrioment, sewerage system or stretch <br />of water. <br />The product has to be labelled due to the calculation procedure of the "General Classification <br />guideline for preparations of the EU" in the latest valid version. <br />· Classification system: <br />The classification is in line with current EC lists. It is expanded, however, by information from <br />technical literature and by information furnished by supplier companies. <br />· 2.2 Label elements <br />· Labelling according to Regulation (EC) No 1272/2008 <br />The product is classified and labelled according to the CLP regulation. <br />· Hazard pictograms GHS05, GHS07 <br />· Signal word Danger <br />· Hazard-determining components of labelling: <br />2-piperazin-1-ylethylamine <br />Benzyl alcohol <br />3-aminomethyl-3,5,5-trimethylcyclohexylamine <br />4,4'-Isopropylidenediphenol, oligomeric reaction products with 1-chloro-2.3-epoxypropane, reaction <br />products with 3-aminomethyl-3,5,5- trimethylcyclohexylamine <br />· Hazard statements <br />H302 Harmful if swallowed. <br />H312 Harmful in contact with skin. <br />H332 Harmful if inhaled. <br />H314 Causes severe skin burns and eye damage. <br />H317 May cause an allergic skin reaction. <br />H412 Harmful to aquatic life with long lasting effects. <br />· Precautionary statements <br />P273 <br />Avoid release to the environment. <br />P260 <br />Do not breathe dust/fume/gas/mist/vapours/spray. <br />P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. <br />Rinse skin with water/shower. <br />P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact <br />lenses, if present and easy to do. Continue rinsing. <br />P405 <br />Store locked up. <br />P501 <br />Dispose of contents/container in accordance with local/regional/national/ <br />international regulations. <br />· 2.3 Other hazards <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />*</p> <p>SECTION 3: Composition/information on ingredients <br />· 3.2 Chemical characterisation: Mixtures <br />· Description: Mixture consisting of the following components. <br />(Contd. on page 3) <br />GB</p> <p>40.0</p> <p>Page 3/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 03.06.2015</p> <p>Version number 12</p> <p>Revision: 03.06.2015</p> <p>Trade name: Asodur-K 900 (B-Komp.) <br />(Contd. of page 2)</p> <p>· Dangerous components: <br />CAS: 100-51-6 <br />Benzyl alcohol <br />EINECS: 202-859-9 <br />Xn R20/22 <br />Acute Tox. 4, H302; Acute Tox. 4, H332; Eye Irrit. 2, H319</p> <p>25-50%</p> <p>CAS: 140-31-8 <br />2-piperazin-1-ylethylamine <br />EINECS: 205-411-0 <br />C R34; <br />Xn R21/22; <br />Xi R43 <br />R52/53 <br />Skin Corr. 1B, H314; <br />Acute Tox. 4, H302; Acute Tox. 4, H312; <br />Skin Sens. 1, H317; Aquatic Chronic 3, H412 <br />CAS: 38294-64-3</p> <p>25-50%</p> <p>4,4'-Isopropylidenediphenol, oligomeric reaction products with 110-25% <br />chloro-2.3-epoxypropane, reaction products with 3-aminomethyl-3,5,5trimethylcyclohexylamine <br />C R34; <br />Xi R41; <br />Xi R43 <br />R52/53 <br />Skin Corr. 1B, H314; Eye Dam. 1, H318; <br />Skin Sens. 1, H317; <br />Aquatic Chronic 3, H412</p> <p>CAS: 2855-13-2 <br />3-aminomethyl-3,5,5-trimethylcyclohexylamine <br />EINECS: 220-666-8 <br />C R34; <br />Xn R21/22; <br />Xi R43 <br />R52/53 <br />Skin Corr. 1B, H314; <br />Acute Tox. 4, H302; Acute Tox. 4, H312; <br />Skin Sens. 1, H317; Aquatic Chronic 3, H412</p> <p>10-25%</p> <p>CAS: 61788-44-1</p> <p>2.5-10%</p> <p>phenol <br />Xi R38; <br />Xi R43; <br />N R51/53 <br />Aquatic Chronic 2, H411; <br />Skin Irrit. 2, H315; Skin Sens. 1, <br />H317 <br />· Additional information For the wording of the listed risk phrases refer to section 16. <br />SECTION 4: First aid measures</p> <p>· 4.1 Description of first aid measures <br />· General information <br />Symptoms of poisoning may even occur after several hours; therefore medical observation for at <br />least 48 hours after the accident. <br />Personal protection for the First Aider. <br />It is possible to choke in case of vomiting in unconsciousness. <br />Bring unconscious persons into a stable position on side. <br />Keep the respiratory tract free (remove dentures and vomiting). <br />Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage <br />of breathing: artificial respiration. <br />Take up a doctor immediately! <br />· After inhalation <br />Supply fresh air or oxygen; call for doctor. <br />In case of unconsciousness bring patient into stable side position for transport. <br />· After skin contact <br />Instantly wash with water and soap and rinse thoroughly. <br />Change immediately contaminated clothes. <br />· After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. <br />· After swallowing <br />Do not induce vomiting; instantly call for medical help. <br />Show the pack or the label to the doctor. <br />· 4.2 Most important symptoms and effects, both acute and delayed <br />No further relevant information available. <br />(Contd. on page 4) <br />GB</p> <p>40.0</p> <p>Page 4/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 03.06.2015</p> <p>Version number 12</p> <p>Revision: 03.06.2015</p> <p>Trade name: Asodur-K 900 (B-Komp.) <br />(Contd. of page 3)</p> <p>· 4.3 Indication of any immediate medical attention and special treatment needed <br />No further relevant information available. <br />SECTION 5: Firefighting measures <br />· 5.1 Extinguishing media <br />· Suitable extinguishing agents <br />CO2, extinguishing powder or water jet. Fight larger fires with water jet. <br />· For safety reasons unsuitable extinguishing agents Water with a full water jet. <br />· 5.2 Special hazards arising from the substance or mixture <br />Formation of poisonous gases during heating or in fires. <br />· 5.3 Advice for firefighters <br />· Protective equipment: Wear self-contained breathing apparatus. <br />· Additional information <br />Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. <br />Follow the emergency-plan. <br />SECTION 6: Accidental release measures <br />· 6.1 Personal precautions, protective equipment and emergency procedures <br />Bring persons out of danger. <br />Wear protective equipment. Keep unprotected persons away. <br />· 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. <br />· 6.3 Methods and material for containment and cleaning up: <br />Ensure adequate ventilation. <br />Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). <br />· 6.4 Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />See Section 13 for information on disposal. <br />SECTION 7: Handling and storage <br />· 7.1 Precautions for safe handling <br />Ensure good ventilation/exhaustion at the workplace. <br />Prevent formation of aerosols. <br />Keep away from children. <br />· Information about protection against explosions and fires: No special measures required. <br />· 7.2 Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: No special requirements. <br />· Information about storage in one common storage facility: <br />Please follow the rules of the VCI-Storage-Concept for chemicals. <br />· Further information about storage conditions: <br />Keep container tightly sealed. <br />Store in a locked cabinet and out of the reach of children. <br />· 7.3 Specific end use(s) No further relevant information available. <br />*</p> <p>SECTION 8: Exposure controls/personal protection <br />· Additional information about design of technical systems: <br />It must be possible to wash the skin in the working area. <br />Eye-wash bottle must be available. <br />(Contd. on page 5) <br />GB</p> <p>40.0</p> <p>Page 5/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 03.06.2015</p> <p>Version number 12</p> <p>Revision: 03.06.2015</p> <p>Trade name: Asodur-K 900 (B-Komp.) <br />(Contd. of page 4)</p> <p>· 8.1 Control parameters <br />· Components with critical values that require monitoring at the workplace: <br />The product does not contain any relevant quantities of materials with critical values that have to be <br />monitored at the workplace. <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· 8.2 Exposure controls <br />· Personal protective equipment <br />· General protective and hygienic measures <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />Instantly remove any soiled and impregnated garments. <br />Avoid contact with the eyes and skin. <br />Be sure to clean skin thoroughly after work and before breaks. <br />· Breathing equipment: Not required. <br />· Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. <br />· Material of gloves <br />Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min <br />· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and <br />has to be observed. <br />· Eye protection: Safety glasses <br />· Body protection: Protective work clothing. <br />*</p> <p>SECTION 9: Physical and chemical properties <br />· 9.1 Information on basic physical and chemical properties <br />· General Information <br />· Appearance: <br />Form: <br />Fluid <br />Colour: <br />According to product specification <br />· Smell: <br />Characteristic <br />· pH-value:</p> <p>Not determined.</p> <p>· Change in condition <br />Melting point/Melting range: Not determined <br />Boiling point/Boiling range: 206 °C <br />· Flash point:</p> <p>88 °C</p> <p>· Self-inflammability:</p> <p>Product is not selfigniting.</p> <p>· Danger of explosion:</p> <p>Product is not explosive.</p> <p>· Critical values for explosion: <br />Lower: <br />Not determined. <br />Upper: <br />Not determined. <br />· Steam pressure:</p> <p>Not determined.</p> <p>· Density at 20 °C</p> <p>1.02 g/cm³</p> <p>· Solubility in / Miscibility with <br />Water: <br />Not miscible or difficult to mix <br />· Viscosity: <br />dynamic at 20 °C: <br />kinematic:</p> <p>112 mPas <br />Not determined. <br />(Contd. on page 6) <br />GB</p> <p>40.0</p> <p>Page 6/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 03.06.2015</p> <p>Version number 12</p> <p>Revision: 03.06.2015</p> <p>Trade name: Asodur-K 900 (B-Komp.) <br />(Contd. of page 5)</p> <p>· 9.2 Other information</p> <p>No further relevant information available.</p> <p>SECTION 10: Stability and reactivity <br />· 10.1 Reactivity <br />· 10.2 Chemical stability <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· 10.3 Possibility of hazardous reactions No dangerous reactions known <br />· 10.4 Conditions to avoid No further relevant information available. <br />· 10.5 Incompatible materials: No further relevant information available. <br />· 10.6 Hazardous decomposition products: No dangerous decomposition products known <br />*</p> <p>SECTION 11: Toxicological information <br />· 11.1 Information on toxicological effects <br />· Acute toxicity: <br />· LD/LC50 values that are relevant for classification: <br />Oral <br />LD50 1.300 mg/kg (rats) <br />100-51-6 Benzyl alcohol <br />Oral <br />LD50 1040 mg/kg (mou) <br />1230 mg/kg (rats) <br />1040 mg/kg (rbt) <br />Dermal LD50 2000 mg/kg (rbt) <br />2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine <br />Oral <br />LD50 1030 mg/kg (rats) <br />Dermal LD50 1840 mg/kg (rabbit) <br />61788-44-1 phenol <br />Oral <br />LD50 > 2000 mg/kg (rats) <br />Dermal LD50 > 2000 mg/kg (rats) <br />· Primary irritant effect: <br />· on the skin: <br />Caustic effect on skin and mucous membranes. <br />Irritant for skin and mucous membranes. <br />· on the eye: Strong caustic effect. <br />· Sensitisation: Sensitization possible by skin contact. <br />· Additional toxicological information: <br />Sensitizing <br />The product shows the following dangers according to the calculation method of the General EC <br />Classification Guidelines for Preparations as issued in the latest version: <br />Harmful <br />Corrosive <br />Irritant <br />Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation <br />of esophagus and stomach. <br />GB</p> <p>(Contd. on page 7)</p> <p>40.0</p> <p>Page 7/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 03.06.2015</p> <p>Version number 12</p> <p>Revision: 03.06.2015</p> <p>Trade name: Asodur-K 900 (B-Komp.) <br />(Contd. of page 6)</p> <p>*</p> <p>SECTION 12: Ecological information <br />· 12.1 Toxicity <br />· Aquatic toxicity: <br />100-51-6 Benzyl alcohol <br />LC/EC50 (96h) 645 mg/l (orfe) <br />10 mg/l (Lepomis macrochius) <br />2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine <br />EC/10/18h <br />1120 mg/l (Pseudomas putida) <br />EC50 <br />>50 mg/l (algae toxicity) <br />EC50 (48h) <br />23 mg/l (Daphnia magna) <br />LC50/96h <br />110 mg/l (Brachydanio rerio) <br />· 12.2 Persistence and degradability No further relevant information available. <br />· 12.3 Bioaccumulative potential No further relevant information available. <br />· 12.4 Mobility in soil No further relevant information available. <br />· Ecotoxical effects: <br />100-51-6 Benzyl alcohol <br />EC 50 400 mg/l (Daphnia (acute) toxicity) <br />· Remark: Toxic for fish <br />· Additional ecological information: <br />· General notes: <br />Water hazard class 2 (Self-assessment): hazardous for water. <br />Do not allow product to reach ground water, water bodies or sewage system, even in small <br />quantities. <br />Danger to drinking water if even extremely small quantities leak into soil. <br />Also poisonous for fish and plankton in water bodies. <br />Toxic for aquatic organisms <br />· 12.5 Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />· 12.6 Other adverse effects No further relevant information available. <br />SECTION 13: Disposal considerations <br />· 13.1 Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />· European waste catalogue <br />08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) <br />OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, <br />SEALANTS AND PRINTING INKS <br />08 01 00 wastes from MFSU and removal of paint and varnish <br />08 01 11 waste paint and varnish containing organic solvents or other dangerous substances <br />· Uncleaned packagings: <br />· Recommendation: Disposal must be made according to official regulations.</p> <p>*</p> <p>SECTION 14: Transport information <br />· 14.1 UN-Number <br />· ADR, IMDG, IATA</p> <p>UN2735 <br />(Contd. on page 8) <br />GB</p> <p>40.0</p> <p>Page 8/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 03.06.2015</p> <p>Version number 12</p> <p>Revision: 03.06.2015</p> <p>Trade name: Asodur-K 900 (B-Komp.) <br />(Contd. of page 7)</p> <p>· 14.2 UN proper shipping name <br />· ADR <br />· IMDG, IATA</p> <p>2735 POLYAMINES, LIQUID, CORROSIVE, N.O.S. <br />(N-AMINOETHYLPIPERAZINE, <br />ISOPHORONEDIAMINE) <br />POLYAMINES, LIQUID, CORROSIVE, N.O.S. (NAMINOETHYLPIPERAZINE, <br />ISOPHORONEDIAMINE)</p> <p>· 14.3 Transport hazard class(es) <br />· ADR, IMDG, IATA</p> <p>· Class <br />· Label</p> <p>8 Corrosive substances. <br />8</p> <p>· 14.4 Packing group <br />· ADR, IMDG, IATA</p> <p>III</p> <p>· 14.5 Environmental hazards: <br />· Marine pollutant:</p> <p>No</p> <p>· 14.6 Special precautions for user <br />· Kemler Number: <br />· EMS Number:</p> <p>Warning: Corrosive substances. <br />80 <br />F-A,S-B</p> <p>· 14.7 Transport in bulk according to Annex II <br />of MARPOL73/78 and the IBC Code <br />Not applicable. <br />· Transport/Additional information: <br />· ADR <br />· Limited quantities (LQ) <br />· Transport category <br />· Tunnel restriction code <br />· UN "Model Regulation":</p> <p>*</p> <p>5L <br />3 <br />E <br />UN2735, POLYAMINES, LIQUID, CORROSIVE, <br />N.O.S. (N-AMINOETHYLPIPERAZINE, <br />ISOPHORONEDIAMINE), 8, III</p> <p>SECTION 15: Regulatory information <br />· 15.1 Safety, health and environmental regulations/legislation specific for the substance or <br />mixture <br />· National regulations <br />· Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water. <br />· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.</p> <p>*</p> <p>SECTION 16: Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for <br />any specific product features and shall not establish a legally valid contractual relationship. <br />· Relevant phrases <br />H302 Harmful if swallowed. <br />H312 Harmful in contact with skin. <br />H314 Causes severe skin burns and eye damage. <br />H315 Causes skin irritation. <br />(Contd. on page 9) <br />GB</p> <p>40.0</p> <p>Page 9/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 03.06.2015</p> <p>Version number 12</p> <p>Revision: 03.06.2015</p> <p>Trade name: Asodur-K 900 (B-Komp.) <br />(Contd. of page 8)</p> <p>H317 <br />H318 <br />H319 <br />H332 <br />H411 <br />H412</p> <p>May cause an allergic skin reaction. <br />Causes serious eye damage. <br />Causes serious eye irritation. <br />Harmful if inhaled. <br />Toxic to aquatic life with long lasting effects. <br />Harmful to aquatic life with long lasting effects.</p> <p>R20/22 Harmful by inhalation and if swallowed. <br />R21/22 Harmful in contact with skin and if swallowed. <br />R34 <br />Causes burns. <br />R38 <br />Irritating to skin. <br />R41 <br />Risk of serious damage to eyes. <br />R43 <br />May cause sensitisation by skin contact. <br />R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic <br />environment. <br />R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic <br />environment. <br />· Department issuing data specification sheet: Environment protection department. <br />· Contact: Mr. Guido Herfort <br />· Abbreviations and acronyms: <br />ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the <br />International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />GHS: Globally Harmonised System of Classification and Labelling of Chemicals <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />Acute Tox. 4: Acute toxicity, Hazard Category 4 <br />Skin Corr. 1B: Skin corrosion/irritation, Hazard Category 1B <br />Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 <br />Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1 <br />Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 <br />Skin Sens. 1: Sensitisation - Skin, Hazard Category 1 <br />Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2 <br />Aquatic Chronic 3: Hazardous to the aquatic environment - Chronic Hazard, Category 3</p> <p>· * Data compared to the previous version altered. <br />GB</p>
