ASODUR-K-900 comp.A.pdf
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<h1>ASODUR-K-900 comp.A.pdf</h1> <p>40.0</p> <p>Page 1/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 04.02.2015 <br />*</p> <p>Version number 11</p> <p>Revision: 04.02.2015</p> <p>SECTION 1: Identification of the substance/mixture and of the company/undertaking <br />· 1.1 Product identifier <br />· Trade name: Asodur-K 900 (A-Komp.) <br />· Article number: 205070 <br />· 1.2 Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture Epoxy coating <br />· 1.3 Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />Fax: ++49 (0)5231/953-123 <br />email: info@schomburg.de <br />web: www.schomburg.de <br />· Informing department: <br />Product Safety Department <br />Tel: ++49 (0)5231/953-193 <br />Fax: ++49 (0)5231/953-106 <br />email: guido.herfort@schomburg.de</p> <p>*</p> <p>SECTION 2: Hazards identification <br />· 2.1 Classification of the substance or mixture <br />· Classification according to Regulation (EC) No 1272/2008 <br />GHS09 environment <br />Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. <br />GHS07 <br />Skin Irrit. 2 <br />Eye Irrit. 2 <br />Skin Sens. 1</p> <p>H315 Causes skin irritation. <br />H319 Causes serious eye irritation. <br />H317 May cause an allergic skin reaction.</p> <p>· Classification according to Directive 67/548/EEC or Directive 1999/45/EC <br />Xi; Irritant <br />R36/38: Irritating to eyes and skin. <br />Xi; Sensitising <br />R43:</p> <p>May cause sensitisation by skin contact. <br />N; Dangerous for the environment</p> <p>R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic <br />environment. <br />· Information concerning particular hazards for human and environment: <br />The product may not leak out in sewerage system, stretch of water or soil. <br />The product has to be labelled due to the calculation procedure of the "General Classification <br />guideline for preparations of the EU" in the latest valid version.</p> <p>(Contd. on page 2) <br />GB</p> <p>40.0</p> <p>Page 2/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 04.02.2015</p> <p>Version number 11</p> <p>Revision: 04.02.2015</p> <p>Trade name: Asodur-K 900 (A-Komp.) <br />(Contd. of page 1)</p> <p>· Classification system: <br />The classification is in line with current EC lists. It is expanded, however, by information from <br />technical literature and by information furnished by supplier companies. <br />· 2.2 Label elements <br />· Labelling according to Regulation (EC) No 1272/2008 <br />The product is classified and labelled according to the CLP regulation. <br />· Hazard pictograms GHS07, GHS09 <br />· Signal word Warning</p> <p>· Hazard-determining components of labelling: <br />reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight = 700) <br />bisphenol-F-epoxy resin <br />1,6-bis(2,3-ethoxypropoxy)hexane <br />· Hazard statements <br />H315 Causes skin irritation. <br />H319 Causes serious eye irritation. <br />H317 May cause an allergic skin reaction. <br />H411 Toxic to aquatic life with long lasting effects. <br />· Precautionary statements <br />P261 <br />Avoid breathing dust/fume/gas/mist/vapours/spray. <br />P280 <br />Wear protective gloves/protective clothing/eye protection/face protection. <br />P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact <br />lenses, if present and easy to do. Continue rinsing. <br />P363 <br />Wash contaminated clothing before reuse. <br />P333+P313 <br />If skin irritation or rash occurs: Get medical advice/attention. <br />P501 <br />Dispose of contents/container in accordance with local/regional/national/ <br />international regulations. <br />· Additional information: <br />Contains epoxy constituents. May produce an allergic reaction. <br />· 2.3 Other hazards <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />*</p> <p>SECTION 3: Composition/information on ingredients <br />· 3.2 Chemical characterisation: Mixtures <br />· Description: <br />Solvent- free preparation based on Bisphenol-A-Epichlorhydrin resin molecular weight ≤ 700. <br />· Dangerous components: <br />CAS: 25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number <br />NLP: 500-033-5 average molecular weight = 700) <br />Xi R36/38; <br />Xi R43; <br />N R51/53 <br />Aquatic Chronic 2, H411; <br />Skin Irrit. 2, H315; Eye Irrit. 2, H319; <br />Skin Sens. 1, H317</p> <p>50-100%</p> <p>CAS: 38640-62-9 Diisopropylnaphtalene <br />Xn R65; <br />N R51/53 <br />Asp. Tox. 1, H304; Aquatic Chronic 4, H413</p> <p>10-25%</p> <p>CAS: 9003-36-5 bisphenol-F-epoxy resin <br />NLP: 500-006-8 <br />Xi R36/38; <br />Xi R43; <br />N R51/53 <br />Aquatic Chronic 2, H411; <br />Eye Irrit. 2, H319; Skin Sens. 1, H317</p> <p>2.5-10%</p> <p>(Contd. on page 3) <br />GB</p> <p>40.0</p> <p>Page 3/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 04.02.2015</p> <p>Version number 11</p> <p>Revision: 04.02.2015</p> <p>Trade name: Asodur-K 900 (A-Komp.) <br />(Contd. of page 2)</p> <p>CAS: 16096-31-4 1,6-bis(2,3-ethoxypropoxy)hexane <br />Xi R36/38; <br />Xi R43 <br />R52/53 <br />Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; Aquatic <br />Chronic 3, H412 <br />· Additional information For the wording of the listed risk phrases refer to section 16.</p> <p>2.5-10%</p> <p>SECTION 4: First aid measures <br />· 4.1 Description of first aid measures <br />· General information <br />Personal protection for the First Aider. <br />Symptoms of poisoning may even occur after several hours; therefore medical observation for at <br />least 48 hours after the accident. <br />Personal protection for the First Aider. <br />It is possible to choke in case of vomiting in unconsciousness. <br />Bring unconscious persons into a stable position on side. <br />Keep the respiratory tract free (remove dentures and vomiting). <br />Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage <br />of breathing: artificial respiration. <br />Take up a doctor immediately! <br />· After inhalation Supply fresh air or oxygen; call for doctor. <br />· After skin contact <br />Don't use solvents to clean the skin. <br />Instantly wash with water and soap and rinse thoroughly. <br />· After eye contact <br />Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. <br />· After swallowing <br />Do not induce vomiting; instantly call for medical help. <br />Show the pack or the label to the doctor. <br />· 4.2 Most important symptoms and effects, both acute and delayed <br />No further relevant information available. <br />· 4.3 Indication of any immediate medical attention and special treatment needed <br />No further relevant information available. <br />SECTION 5: Firefighting measures <br />· 5.1 Extinguishing media <br />· Suitable extinguishing agents <br />CO2, extinguishing powder or water jet. Fight larger fires with water jet. <br />· For safety reasons unsuitable extinguishing agents Water with a full water jet. <br />· 5.2 Special hazards arising from the substance or mixture <br />Formation of poisonous gases during heating or in fires. <br />· 5.3 Advice for firefighters <br />· Protective equipment: Wear self-contained breathing apparatus. <br />· Additional information <br />Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. <br />Follow the emergency-plan. <br />SECTION 6: Accidental release measures <br />· 6.1 Personal precautions, protective equipment and emergency procedures <br />Ensure adequate ventilation <br />Avoid eye- and skin contact. <br />Do not breath in vapour. <br />Keep away from ignition sources</p> <p>(Contd. on page 4) <br />GB</p> <p>40.0</p> <p>Page 4/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 04.02.2015</p> <p>Version number 11</p> <p>Revision: 04.02.2015</p> <p>Trade name: Asodur-K 900 (A-Komp.) <br />(Contd. of page 3)</p> <p>Bring persons out of danger. <br />Wear protective equipment. Keep unprotected persons away. <br />· 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. <br />· 6.3 Methods and material for containment and cleaning up: <br />Absorb with liquid-binding, inflammable material (sand, diatomite, acid binders, universal binder). <br />· 6.4 Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />See Section 13 for information on disposal. <br />*</p> <p>SECTION 7: Handling and storage <br />· 7.1 Precautions for safe handling <br />Keep containers tightly sealed. <br />Work with fresh air supply, keep doors and windows open. <br />Keep away from heat and direct sunlight. <br />Keep away from children. <br />· Information about protection against explosions and fires: No special measures required. <br />· 7.2 Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: Do not leave open containers. <br />· Information about storage in one common storage facility: <br />Store away from foodstuffs. <br />Please follow the rules of the VCI-Storage-Concept for chemicals. <br />· Further information about storage conditions: <br />Protect from frost. <br />Keep container tightly sealed. <br />· 7.3 Specific end use(s) No further relevant information available.</p> <p>*</p> <p>SECTION 8: Exposure controls/personal protection <br />· Additional information about design of technical systems: <br />It must be possible to wash the skin in the working area. <br />Eye-wash bottle must be available. <br />· 8.1 Control parameters <br />· Components with critical values that require monitoring at the workplace: <br />The product does not contain any relevant quantities of materials with critical values that have to be <br />monitored at the workplace. <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· 8.2 Exposure controls <br />· Personal protective equipment <br />· General protective and hygienic measures <br />Clean skin only with cleaning agent especially for epoxy resin. <br />Don't use solvent for skin cleaning! <br />Clean clothes which are contaminate with epoxi resin before unsing again. <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />Instantly remove any soiled and impregnated garments. <br />Avoid contact with the eyes and skin. <br />Be sure to clean skin thoroughly after work and before breaks. <br />· Breathing equipment: <br />In not so good ventilated space the filter combination A2B2E2K1HgP3RD is to be used. <br />· Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. <br />· Material of gloves <br />Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min <br />(Contd. on page 5) <br />GB</p> <p>40.0</p> <p>Page 5/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 04.02.2015</p> <p>Version number 11</p> <p>Revision: 04.02.2015</p> <p>Trade name: Asodur-K 900 (A-Komp.) <br />(Contd. of page 4)</p> <p>· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and <br />has to be observed. <br />· Eye protection: Safety glasses <br />· Body protection: <br />Protective work clothing. <br />Contaminated protection clothes must be cleaned carfully before reuse. <br />SECTION 9: Physical and chemical properties <br />· 9.1 Information on basic physical and chemical properties <br />· General Information <br />· Appearance: <br />Form: <br />Liquid <br />Colour: <br />Colourless <br />· Smell: <br />Type specific <br />· Change in condition <br />Melting point/Melting range: Not determined <br />Boiling point/Boiling range: Not determined <br />· Flash point:</p> <p>Not applicable</p> <p>· Self-inflammability:</p> <p>Product is not selfigniting.</p> <p>· Danger of explosion:</p> <p>Product is not explosive.</p> <p>· Density at 20 °C</p> <p>1.13 g/cm³</p> <p>· Solubility in / Miscibility with <br />Water: <br />Not miscible or difficult to mix <br />· Viscosity: <br />dynamic at 20 °C: <br />· 9.2 Other information</p> <p>*</p> <p>1500 mPas <br />No further relevant information available.</p> <p>SECTION 10: Stability and reactivity <br />· 10.1 Reactivity <br />· 10.2 Chemical stability <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· 10.3 Possibility of hazardous reactions <br />Reacts violently with oxidizing agents <br />Reacts with strong acids and oxidizing agents <br />· 10.4 Conditions to avoid No further relevant information available. <br />· 10.5 Incompatible materials: Can react with acid and oxidizing agends. <br />· 10.6 Hazardous decomposition products: <br />În case of heating dangerous decomposition products can be arise.</p> <p>*</p> <p>SECTION 11: Toxicological information <br />· 11.1 Information on toxicological effects <br />· Acute toxicity: <br />· LD/LC50 values that are relevant for classification: <br />25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average <br />molecular weight = 700) <br />Oral <br />LD50 <br />>5000 mg/kg (rats)</p> <p>(Contd. on page 6) <br />GB</p> <p>40.0</p> <p>Page 6/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 04.02.2015</p> <p>Version number 11</p> <p>Revision: 04.02.2015</p> <p>Trade name: Asodur-K 900 (A-Komp.) <br />(Contd. of page 5)</p> <p>Dermal</p> <p>LD50</p> <p>>2000 mg/kg (rats)</p> <p>38640-62-9 Diisopropylnaphtalene <br />Oral <br />LD50 <br />>3900 mg/kg (rats) <br />Dermal LD50 <br />>4500 mg/kg (rats) <br />Inhalative LC 50 <br />5.64 mg/l (rats) <br />9003-36-5 bisphenol-F-epoxy resin <br />Oral <br />LD50 <br />>5000 mg/kg (rats) <br />16096-31-4 1,6-bis(2,3-ethoxypropoxy)hexane <br />Oral <br />LD50 <br />1400 mg/kg (rabbit) <br />2900 mg/kg (rats) <br />Inhalative LC50/4 h >100 mg/l (Maus) <br />· Primary irritant effect: <br />· on the skin: Irritant for skin and mucous membranes. <br />· on the eye: Irritant effect. <br />· Sensitisation: Sensitization possible by skin contact. <br />· Additional toxicological information: <br />The product shows the following dangers according to the calculation method of the General EC <br />Classification Guidelines for Preparations as issued in the latest version: <br />Irritant <br />Sensitizing <br />*</p> <p>SECTION 12: Ecological information <br />· 12.1 Toxicity <br />· Aquatic toxicity: <br />25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average <br />molecular weight = 700) <br />EC50 <br />(24h) 3.6 mg/l (Daphnia magna) <br />LC50 <br />(96h) 1.5 mg/l (rainbow trout) <br />38640-62-9 Diisopropylnaphtalene <br />EC0 <br />(72h) 0.15 mg/l (algae toxicity) <br />(48h) 0.16 mg/l (Daphnia (acute) toxicity) <br />LC 0 <br />(96h) 0.5 mg/l (fish toxicity) <br />9003-36-5 bisphenol-F-epoxy resin <br />EC50 <br />2 mg/l (Daphnia (acute) toxicity) <br />LC50/96h 2 mg/l (fish toxicity) <br />· 12.2 Persistence and degradability <br />25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average <br />molecular weight = 700) <br />301B (Mod. Sturm) 12 % (-) <br />· 12.3 Bioaccumulative potential No further relevant information available. <br />· 12.4 Mobility in soil No further relevant information available. <br />· Ecotoxical effects: <br />· Remark: Harmful to fish <br />· Additional ecological information: <br />· General notes: <br />Water hazard class 2 (Self-assessment): hazardous for water. <br />Do not allow product to reach ground water, water bodies or sewage system. <br />Danger to drinking water if even small quantities leak into soil. <br />Harmful to aquatic organisms</p> <p>(Contd. on page 7) <br />GB</p> <p>40.0</p> <p>Page 7/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 04.02.2015</p> <p>Version number 11</p> <p>Revision: 04.02.2015</p> <p>Trade name: Asodur-K 900 (A-Komp.)</p> <p>· 12.5 Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />· 12.6 Other adverse effects No further relevant information available. <br />*</p> <p>(Contd. of page 6)</p> <p>SECTION 13: Disposal considerations <br />· 13.1 Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />· European waste catalogue <br />17 00 00 CONSTRUCTION AND DEMOLITION WASTES (INCLUDING EXCAVATED SOIL FROM <br />CONTAMINATED SITES) <br />17 02 00 wood, glass and plastic <br />17 02 03 plastic <br />· Uncleaned packagings: <br />· Recommendation: Disposal must be made according to official regulations.</p> <p>*</p> <p>SECTION 14: Transport information <br />· 14.1 UN-Number <br />· ADR, IMDG, IATA <br />· 14.2 UN proper shipping name <br />· ADR</p> <p>· IMDG</p> <p>· IATA</p> <p>UN3082 <br />3082 ENVIRONMENTALLY HAZARDOUS <br />SUBSTANCE, LIQUID, N.O.S. (bisphenol A(epichlorhydrin); epoxy resin(number average <br />molecular weight<700), DiisopropylnaphthalinIsomere) <br />ENVIRONMENTALLY HAZARDOUS SUBSTANCE, <br />LIQUID, N.O.S. (bisphenol A-(epichlorhydrin); <br />epoxy resin(number average molecular <br />weight<700), Diisopropylnaphthalin-Isomere), <br />MARINE POLLUTANT <br />ENVIRONMENTALLY HAZARDOUS SUBSTANCE, <br />LIQUID, N.O.S. (bisphenol A-(epichlorhydrin); <br />epoxy resin(number average molecular <br />weight<700), Diisopropylnaphthalin-Isomere)</p> <p>· 14.3 Transport hazard class(es) <br />· ADR, IMDG, IATA</p> <p>· Class <br />· Label</p> <p>9 Miscellaneous dangerous substances and <br />articles. <br />9</p> <p>· 14.4 Packing group <br />· ADR, IMDG, IATA</p> <p>III</p> <p>· 14.5 Environmental hazards: <br />· Marine pollutant:</p> <p>Yes <br />Symbol (fish and tree) <br />(Contd. on page 8) <br />GB</p> <p>40.0</p> <p>Page 8/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 04.02.2015</p> <p>Version number 11</p> <p>Revision: 04.02.2015</p> <p>Trade name: Asodur-K 900 (A-Komp.) <br />(Contd. of page 7)</p> <p>· Special marking (ADR): <br />· Special marking (IATA):</p> <p>Symbol (fish and tree) <br />Symbol (fish and tree)</p> <p>· 14.6 Special precautions for user</p> <p>Warning: Miscellaneous dangerous substances and <br />articles. <br />90 <br />F-A,S-F</p> <p>· Kemler Number: <br />· EMS Number:</p> <p>· 14.7 Transport in bulk according to Annex II <br />of MARPOL73/78 and the IBC Code <br />Not applicable. <br />· Transport/Additional information: <br />· ADR <br />· Limited quantities (LQ) <br />· Transport category <br />· Tunnel restriction code <br />· UN "Model Regulation":</p> <p>*</p> <p>5L <br />3 <br />E <br />UN3082, ENVIRONMENTALLY HAZARDOUS <br />SUBSTANCE, LIQUID, N.O.S. (bisphenol A(epichlorhydrin); epoxy resin(number average <br />molecular weight<700), Diisopropylnaphtalene), 9, <br />III</p> <p>SECTION 15: Regulatory information <br />· 15.1 Safety, health and environmental regulations/legislation specific for the substance or <br />mixture <br />· National regulations <br />· Water hazard class: <br />Water hazard class 2 (Self-assessment): hazardous for water. <br />The classification based on german instructions. <br />· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.</p> <p>*</p> <p>SECTION 16: Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for <br />any specific product features and shall not establish a legally valid contractual relationship. <br />· Relevant phrases <br />H304 May be fatal if swallowed and enters airways. <br />H315 Causes skin irritation. <br />H317 May cause an allergic skin reaction. <br />H319 Causes serious eye irritation. <br />H411 Toxic to aquatic life with long lasting effects. <br />H412 Harmful to aquatic life with long lasting effects. <br />H413 May cause long lasting harmful effects to aquatic life. <br />R36/38 Irritating to eyes and skin. <br />R43 <br />May cause sensitisation by skin contact. <br />R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic <br />environment. <br />R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic <br />environment. <br />R65 <br />Harmful: may cause lung damage if swallowed. <br />· Department issuing data specification sheet: Environment protection department. <br />· Contact: Mr. Guido Herfort</p> <p>(Contd. on page 9) <br />GB</p> <p>40.0</p> <p>Page 9/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 04.02.2015</p> <p>Version number 11</p> <p>Revision: 04.02.2015</p> <p>Trade name: Asodur-K 900 (A-Komp.)</p> <p>· Abbreviations and acronyms:</p> <p>(Contd. of page 8)</p> <p>ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the <br />International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />GHS: Globally Harmonised System of Classification and Labelling of Chemicals <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 <br />Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 <br />Skin Sens. 1: Sensitisation - Skin, Hazard Category 1 <br />Asp. Tox. 1: Aspiration hazard, Hazard Category 1 <br />Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2 <br />Aquatic Chronic 3: Hazardous to the aquatic environment - Chronic Hazard, Category 3 <br />Aquatic Chronic 4: Hazardous to the aquatic environment - Chronic Hazard, Category 4</p> <p>· * Data compared to the previous version altered.</p> <p>GB</p>
