40.0
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 09.03.2015 *
Version number 7
Revision: 09.03.2015
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASO-EZ4-Plus · Article number: 205528 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Ready-mixed mortar · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: guido.herfort@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS05 corrosion Eye Dam. 1 H318 Causes serious eye damage. · Classification according to Directive 67/548/EEC or Directive 1999/45/EC Xi; Irritant R41: Risk of serious damage to eyes. · Classification system: The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information furnished by supplier companies. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS05 · Signal word Danger · Hazard-determining components of labelling: Cement, portland, chemicals · Hazard statements H318 Causes serious eye damage. · Precautionary statements P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P363 Wash contaminated clothing before reuse. (Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 09.03.2015
Trade name: ASO-EZ4-Plus (Contd. of page 1)
· 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Product based on cement and mineral filler. · Dangerous components: 10-25% CAS: 65997-15-1 Cement, portland, chemicals Xi R37/38-41; Xi R43 EINECS: 266-043-4 Eye Dam. 1, H318; Skin Irrit. 2, H315; STOT SE 3, H335 · Additional information The chromate content in cement is less than 2 ppm so that the rating of the relevant phrase no. 43 is not applicable.
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. · After inhalation Supply fresh air; consult doctor in case of symptoms. · After skin contact Instantly wash with water and soap and rinse thoroughly. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available.
SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents Use fire fighting measures that suit the environment. Product is not inflammable. · 5.2 Special hazards arising from the substance or mixture No further relevant information available. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Follow the emergency-plan. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Wear protective clothing. Avoid causing dust. · 6.2 Environmental precautions: Do not allow to enter drainage system, surface or ground water. · 6.3 Methods and material for containment and cleaning up: Ensure adequate ventilation. Do not flush with water or aqueous cleansing agents Pick up the product mechanically, avoid dust formation. (Contd. on page 3) GB
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Trade name: ASO-EZ4-Plus (Contd. of page 2)
· 6.4 Reference to other sections See Section 8 for information on personal protection equipment. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of dust. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Keep dry. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. No further data; see item 7 MSDS. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 65997-15-1 Cement, portland, chemicals (10-25%) WEL Long-term value: 10* 4** mg/m³ *inhalable dust **respirable dust · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Be sure to clean skin thoroughly after work and before breaks. Avoid contact with the eyes and skin. Vacuum clean contaminated clothing. Do not blow or brush off contamination. · Breathing equipment: Use respiratory protective equipment at formation of dust. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing.
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Powder (Contd. on page 4) GB
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Trade name: ASO-EZ4-Plus (Contd. of page 3)
Colour: · Smell:
Grey Characteristic
· Change in condition Melting point/Melting range: Not determined Boiling point/Boiling range: Not determined · Flash point:
Not applicable
· Self-inflammability:
Product is not selfigniting.
· Danger of explosion:
Product is not explosive.
· Density Settled apparent density
1,850 kg/dm³
· Solubility in / Miscibility with Water: miscible · 9.2 Other information No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: No dates existing. · Primary irritant effect: · on the skin: Irritant for skin and mucous membranes. · on the eye: Irritant effect. · Sensitisation: No sensitizing effect known. · Additional toxicological information: The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for Preparations as issued in the latest version: Irritant SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: No further relevant information available. · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. (Contd. on page 5) GB
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Trade name: ASO-EZ4-Plus (Contd. of page 4)
· 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. *
SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 10 00 00 WASTES FROM THERMAL PROCESSES 10 12 00 wastes from manufacture of ceramic goods, bricks, tiles and construction products 10 12 03 particulates and dust 17 00 00 CONSTRUCTION AND DEMOLITION WASTES (INCLUDING EXCAVATED SOIL FROM CONTAMINATED SITES) 17 01 00 concrete, bricks, tiles and ceramics 17 01 01 concrete · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleaning agent: Water, if necessary with cleaning agent.
SECTION 14: Transport information · 14.1 UN-Number · ADR, ADN, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, ADN, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards:
Not applicable.
· 14.6 Special precautions for user
· 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional information:
Not dangerous according to the above specifications.
· Number/Letter: · UN "Model Regulation":
GB
(Contd. on page 6)
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Trade name: ASO-EZ4-Plus (Contd. of page 5)
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · National regulations · Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H315 Causes skin irritation. H318 Causes serious eye damage. H335 May cause respiratory irritation. R37/38 Irritating to respiratory system and skin. R41 Risk of serious damage to eyes. R43 May cause sensitisation by skin contact. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1 STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
· * Data compared to the previous version altered. GB