AQUAFIN-P4 comp.B.pdf
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<h1>AQUAFIN-P4 comp.B.pdf</h1> <p>40.0</p> <p>Page 1/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 06.03.2015 <br />*</p> <p>Version number 10</p> <p>Revision: 06.03.2015</p> <p>SECTION 1: Identification of the substance/mixture and of the company/undertaking <br />· 1.1 Product identifier <br />· Trade name: AQUAFIN-P4 (B-Komp.) <br />· Article number: 205091BNEU <br />· 1.2 Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture Reaction resin <br />· 1.3 Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />Fax: ++49 (0)5231/953-123 <br />email: info@schomburg.de <br />web: www.schomburg.de <br />· Informing department: <br />Product Safety Department <br />Tel: ++49 (0)5231/953-193 <br />Fax: ++49 (0)5231/953-106 <br />email: guido.herfort@schomburg.de <br />SECTION 2: Hazards identification <br />· 2.1 Classification of the substance or mixture <br />· Classification according to Regulation (EC) No 1272/2008 <br />GHS08 health hazard <br />Resp. Sens. 1 <br />Carc. 2 <br />STOT RE 2 <br />Asp. Tox. 1</p> <p>H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />H351 Suspected of causing cancer. <br />H373 May cause damage to organs through prolonged or repeated exposure. <br />H304 May be fatal if swallowed and enters airways.</p> <p>GHS07 <br />Skin Irrit. 2 <br />Eye Irrit. 2 <br />Skin Sens. 1 <br />STOT SE 3</p> <p>H315 Causes skin irritation. <br />H319 Causes serious eye irritation. <br />H317 May cause an allergic skin reaction. <br />H335 May cause respiratory irritation.</p> <p>Aquatic Chronic 4 H413 May cause long lasting harmful effects to aquatic life. <br />· Classification according to Directive 67/548/EEC or Directive 1999/45/EC <br />Xn; Harmful <br />R20-40-48/20: Harmful by inhalation. Limited evidence of a carcinogenic effect. Harmful: danger of <br />serious damage to health by prolonged exposure through inhalation. <br />Xn; Sensitising <br />R42/43:</p> <p>May cause sensitisation by inhalation and skin contact. <br />(Contd. on page 2) <br />GB</p> <p>40.0</p> <p>Page 2/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 06.03.2015</p> <p>Version number 10</p> <p>Revision: 06.03.2015</p> <p>Trade name: AQUAFIN-P4 (B-Komp.) <br />(Contd. of page 1)</p> <p>Xi; Irritant <br />R36/37/38: <br />Irritating to eyes, respiratory system and skin. <br />R53: <br />May cause long-term adverse effects in the aquatic environment. <br />· Information concerning particular hazards for human and environment: <br />This product is irritant and sensitive by inhalation: <br />repeated inhalation of concentrates of steam or aerosols about the stated limit may cause <br />sensitization at the respiratory tract. <br />Symptoms could be appear several hours after exposition. <br />Sensitize persons can react heavy on minimal MDI-concentrationes. <br />The product may not leak out in sewerage system, stretch of water or soil. <br />The product has to be labelled due to the calculation procedure of the "General Classification <br />guideline for preparations of the EU" in the latest valid version. <br />· Classification system: <br />The classification is in line with current EC lists. It is expanded, however, by information from <br />technical literature and by information furnished by supplier companies. <br />· 2.2 Label elements <br />· Labelling according to Regulation (EC) No 1272/2008 <br />The product is classified and labelled according to the CLP regulation. <br />· Hazard pictograms GHS07, GHS08 <br />· Signal word Danger <br />· Hazard-determining components of labelling: <br />diphenylmethanediisocyanate,isomeres and homologues <br />Diisopropylnaphtalene <br />· Hazard statements <br />H315 Causes skin irritation. <br />H319 Causes serious eye irritation. <br />H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />H317 May cause an allergic skin reaction. <br />H351 Suspected of causing cancer. <br />H335 May cause respiratory irritation. <br />H373 May cause damage to organs through prolonged or repeated exposure. <br />H304 May be fatal if swallowed and enters airways. <br />H413 May cause long lasting harmful effects to aquatic life. <br />· Precautionary statements <br />P260 <br />Do not breathe dust/fume/gas/mist/vapours/spray. <br />P285 <br />In case of inadequate ventilation wear respiratory protection. <br />P301+P310 <br />IF SWALLOWED: Immediately call a POISON CENTER/ doctor. <br />P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact <br />lenses, if present and easy to do. Continue rinsing. <br />P405 <br />Store locked up. <br />P501 <br />Dispose of contents/container in accordance with local/regional/national/ <br />international regulations. <br />· Additional information: <br />Contains isocyanates. May produce an allergic reaction. <br />· 2.3 Other hazards <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />*</p> <p>SECTION 3: Composition/information on ingredients <br />· 3.2 Chemical characterisation: Mixtures <br />· Description: Preparation based on Diphenylmethan-Diisocyanat-Prepolymers. (MDI) <br />(Contd. on page 3) <br />GB</p> <p>40.0</p> <p>Page 3/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 06.03.2015</p> <p>Version number 10</p> <p>Revision: 06.03.2015</p> <p>Trade name: AQUAFIN-P4 (B-Komp.) <br />(Contd. of page 2)</p> <p>· Dangerous components: <br />9016-87-9 diphenylmethanediisocyanate,isomeres and homologues <br />Xn R20-40-48/20; <br />Xn R42/43; <br />Xi R36/37/38 <br />Carc. Cat. 3 <br />Resp. Sens. 1, H334; <br />Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. <br />2, H319; Skin Sens. 1, H317; STOT SE 3, H335 <br />38640-62-9 Diisopropylnaphtalene <br />Xn R65; <br />N R51/53 <br />Asp. Tox. 1, H304; Aquatic Chronic 4, H413 <br />· Additional information For the wording of the listed risk phrases refer to section 16. <br />*</p> <p>50-100%</p> <p>10-25%</p> <p>SECTION 4: First aid measures <br />· 4.1 Description of first aid measures <br />· General information <br />Symptoms of poisoning may even occur after several hours; therefore medical observation for at <br />least 48 hours after the accident. <br />Personal protection for the First Aider. <br />It is possible to choke in case of vomiting in unconsciousness. <br />Bring unconscious persons into a stable position on side. <br />Keep the respiratory tract free (remove dentures and vomiting). <br />Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage <br />of breathing: artificial respiration. <br />Take up a doctor immediately! <br />· After inhalation <br />Supply fresh air or oxygen; call for doctor. <br />Supply fresh air and call for doctor for safety reasons. <br />· After skin contact <br />Instantly wash with water and soap and rinse thoroughly. <br />Change immediately contaminated clothes. <br />· After eye contact <br />Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. <br />· After swallowing <br />Drink copious amounts of water and provide fresh air. Instantly call for doctor. <br />Show the pack or the label to the doctor. <br />· 4.2 Most important symptoms and effects, both acute and delayed <br />No further relevant information available. <br />· 4.3 Indication of any immediate medical attention and special treatment needed <br />No further relevant information available. <br />SECTION 5: Firefighting measures <br />· 5.1 Extinguishing media <br />· Suitable extinguishing agents <br />CO2, extinguishing powder or water jet. Fight larger fires with water jet. <br />· For safety reasons unsuitable extinguishing agents Water with a full water jet. <br />· 5.2 Special hazards arising from the substance or mixture <br />In case of fire unhealthy gas/vapour is formed. <br />Formation of poisonous gases during heating or in fires. <br />· 5.3 Advice for firefighters <br />· Protective equipment: Wear self-contained breathing apparatus. <br />· Additional information <br />Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. <br />Follow the emergency-plan. <br />(Contd. on page 4) <br />GB</p> <p>40.0</p> <p>Page 4/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 06.03.2015</p> <p>Version number 10</p> <p>Revision: 06.03.2015</p> <p>Trade name: AQUAFIN-P4 (B-Komp.) <br />(Contd. of page 3)</p> <p>Burst- and explosion-danger by increaseing pressure. <br />In case of fire chill the container with water spray. <br />SECTION 6: Accidental release measures <br />· 6.1 Personal precautions, protective equipment and emergency procedures <br />Ensure adequate ventilation <br />Bring persons out of danger. <br />Wear protective equipment. Keep unprotected persons away. <br />· 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. <br />· 6.3 Methods and material for containment and cleaning up: <br />Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). <br />Ensure adequate ventilation. <br />· 6.4 Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />See Section 13 for information on disposal. <br />SECTION 7: Handling and storage <br />· 7.1 Precautions for safe handling <br />Ensure good ventilation/exhaustion at the workplace. <br />Prevent formation of aerosols. <br />Keep away from children. <br />· Information about protection against explosions and fires: No special measures required. <br />· 7.2 Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: <br />The Product reacts with water and CO2-Gas will be given off. <br />In tight closed containers pressure may arise and the cover can burst. <br />· Information about storage in one common storage facility: <br />Please follow the rules of the VCI-Storage-Concept for chemicals. <br />· Further information about storage conditions: <br />Keep container tightly sealed. <br />Store in a locked cabinet and out of the reach of children. <br />· 7.3 Specific end use(s) No further relevant information available. <br />*</p> <p>SECTION 8: Exposure controls/personal protection <br />· Additional information about design of technical systems: <br />It must be possible to wash the skin in the working area. <br />Eye-wash bottle must be available. <br />· 8.1 Control parameters <br />· Components with critical values that require monitoring at the workplace: <br />9016-87-9 diphenylmethanediisocyanate,isomeres and homologues (50-100%) <br />WEL Short-term value: 0.07 mg/m³ <br />Long-term value: 0.02 mg/m³ <br />Sen; as -NCO <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· 8.2 Exposure controls <br />· Personal protective equipment <br />· General protective and hygienic measures <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />Instantly remove any soiled and impregnated garments. <br />Do not inhale gases / fumes / aerosols. <br />(Contd. on page 5) <br />GB</p> <p>40.0</p> <p>Page 5/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 06.03.2015</p> <p>Version number 10</p> <p>Revision: 06.03.2015</p> <p>Trade name: AQUAFIN-P4 (B-Komp.) <br />(Contd. of page 4)</p> <p>Avoid contact with the eyes and skin. <br />Be sure to clean skin thoroughly after work and before breaks. <br />When the material is hardened on the skin, remove it carfully mechanically. <br />· Breathing equipment: <br />In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer <br />exposure use breathing apparatus that is independent of circulating air. <br />· Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. <br />· Material of gloves <br />Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min <br />· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and <br />has to be observed. <br />· Eye protection: Safety glasses <br />· Body protection: <br />Protective work clothing. <br />Contaminated protection clothes must be cleaned carfully before reuse. <br />SECTION 9: Physical and chemical properties <br />· 9.1 Information on basic physical and chemical properties <br />· General Information <br />· Appearance: <br />Form: <br />Liquid <br />Colour: <br />Brown <br />· Smell: <br />Characteristic <br />· Odour threshold: <br />Not determined. <br />· pH-value:</p> <p>Not determined.</p> <p>· Change in condition <br />Melting point/Melting range: <br />Boiling point/Boiling range:</p> <p>Not determined <br />190 °C</p> <p>· Flash point:</p> <p>> 100 °C</p> <p>· Inflammability (solid, gaseous)</p> <p>Not applicable.</p> <p>· Ignition temperature:</p> <p>450 °C</p> <p>· Decomposition temperature:</p> <p>Not determined.</p> <p>· Self-inflammability:</p> <p>Product is not selfigniting.</p> <p>· Danger of explosion:</p> <p>Product is not explosive.</p> <p>· Critical values for explosion: <br />Lower: <br />Upper:</p> <p>Not determined. <br />Not determined.</p> <p>· Steam pressure:</p> <p>Not determined.</p> <p>· Density at 20 °C <br />· Relative density <br />· Vapour density <br />· Evaporation rate</p> <p>1.09 g/cm³ <br />Not determined. <br />Not determined. <br />Not determined.</p> <p>· Solubility in / Miscibility with <br />Water:</p> <p>Not miscible or difficult to mix</p> <p>· Partition coefficient (n-octanol/water): Not determined. <br />· Viscosity: <br />dynamic at 20 °C:</p> <p>15 mPas <br />(Contd. on page 6) <br />GB</p> <p>40.0</p> <p>Page 6/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 06.03.2015</p> <p>Version number 10</p> <p>Revision: 06.03.2015</p> <p>Trade name: AQUAFIN-P4 (B-Komp.) <br />(Contd. of page 5)</p> <p>kinematic: <br />· 9.2 Other information</p> <p>Not determined. <br />No further relevant information available.</p> <p>SECTION 10: Stability and reactivity <br />· 10.1 Reactivity <br />· 10.2 Chemical stability <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· 10.3 Possibility of hazardous reactions No dangerous reactions known <br />· 10.4 Conditions to avoid No further relevant information available. <br />· 10.5 Incompatible materials: No further relevant information available. <br />· 10.6 Hazardous decomposition products: No dangerous decomposition products known <br />SECTION 11: Toxicological information <br />· 11.1 Information on toxicological effects <br />· Acute toxicity: <br />· LD/LC50 values that are relevant for classification: <br />9016-87-9 diphenylmethanediisocyanate,isomeres and homologues <br />Oral <br />LD50 <br />>5000 mg/kg (rats) <br />Dermal LD50 <br />>5000 mg/kg (rabbit) <br />Inhalative LC50/4 h 490 mg/l (rats) <br />38640-62-9 Diisopropylnaphtalene <br />Oral <br />LD50 <br />>3900 mg/kg (rats) <br />Dermal LD50 <br />>4500 mg/kg (rats) <br />Inhalative LC 50 <br />5.64 mg/l (rats) <br />· Primary irritant effect: <br />· on the skin: <br />Irritant for skin and mucous membranes. <br />The produkt has an irritate-effect. <br />· on the eye: Irritant effect. <br />· Sensitisation: <br />Sensitization possible by inhalation. <br />Sensitization possible by skin contact. <br />· Additional toxicological information: <br />The product shows the following dangers according to the calculation method of the General EC <br />Classification Guidelines for Preparations as issued in the latest version: <br />Harmful <br />Irritant <br />Sensitizing <br />· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) <br />Carc. 2 <br />SECTION 12: Ecological information <br />· 12.1 Toxicity <br />· Aquatic toxicity: <br />9016-87-9 diphenylmethanediisocyanate,isomeres and homologues <br />EC50 (3h) = > 1000 mg/l (activated sludge bacteria) <br />LC 0 <br />(96h) >1000 mg/l (zebra danio) <br />(Contd. on page 7) <br />GB</p> <p>40.0</p> <p>Page 7/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 06.03.2015</p> <p>Version number 10</p> <p>Revision: 06.03.2015</p> <p>Trade name: AQUAFIN-P4 (B-Komp.) <br />(Contd. of page 6)</p> <p>>1000 mg/l (acute fishtoxicity zebrafish) <br />38640-62-9 Diisopropylnaphtalene <br />EC0 <br />(72h) 0.15 mg/l (algae toxicity) <br />(48h) 0.16 mg/l (Daphnia (acute) toxicity) <br />LC 0 <br />(96h) 0.5 mg/l (fish toxicity) <br />· 12.2 Persistence and degradability No further relevant information available. <br />· 12.3 Bioaccumulative potential No further relevant information available. <br />· 12.4 Mobility in soil No further relevant information available. <br />· Ecotoxical effects: <br />9016-87-9 diphenylmethanediisocyanate,isomeres and homologues <br />EC 50 (24h) >1000 mg/l (Daphnia magna) <br />>100 mg/l (E. Coli) <br />· Additional ecological information: <br />· General notes: <br />Water hazard class 1 (Self-assessment): slightly hazardous for water. <br />Do not allow undiluted product or large quantities of it to reach ground water, water bodies or <br />sewage system. <br />· 12.5 Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />· 12.6 Other adverse effects No further relevant information available. <br />SECTION 13: Disposal considerations <br />· 13.1 Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />· European waste catalogue <br />08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) <br />OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, <br />SEALANTS AND PRINTING INKS <br />08 05 00 wastes not otherwise specified in 08 <br />08 05 01* waste isocyanates <br />· Uncleaned packagings: <br />· Recommendation: Disposal must be made according to official regulations. <br />*</p> <p>SECTION 14: Transport information <br />· 14.1 UN-Number <br />· ADR, ADN, IMDG, IATA</p> <p>Void</p> <p>· 14.2 UN proper shipping name <br />· ADR, ADN, IMDG, IATA</p> <p>Void</p> <p>· 14.3 Transport hazard class(es) <br />· ADR, ADN, IMDG, IATA <br />· Class</p> <p>Void</p> <p>· 14.4 Packing group <br />· ADR, IMDG, IATA</p> <p>Void</p> <p>· 14.5 Environmental hazards:</p> <p>Not applicable. <br />(Contd. on page 8) <br />GB</p> <p>40.0</p> <p>Page 8/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 06.03.2015</p> <p>Version number 10</p> <p>Revision: 06.03.2015</p> <p>Trade name: AQUAFIN-P4 (B-Komp.) <br />(Contd. of page 7)</p> <p>· 14.6 Special precautions for user</p> <p>Not applicable.</p> <p>· 14.7 Transport in bulk according to Annex II <br />of MARPOL73/78 and the IBC Code <br />Not applicable. <br />· UN "Model Regulation":</p> <p>*</p> <p>-</p> <p>SECTION 15: Regulatory information <br />· 15.1 Safety, health and environmental regulations/legislation specific for the substance or <br />mixture <br />· National regulations <br />· Technical instructions (air): <br />· Class Share in % <br />· I <br />65.0 <br />· Water hazard class: <br />Water hazard class 1 (Self-assessment): slightly hazardous for water. <br />The classification based on german instructions. <br />· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.</p> <p>*</p> <p>SECTION 16: Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for <br />any specific product features and shall not establish a legally valid contractual relationship. <br />· Relevant phrases <br />H304 <br />May be fatal if swallowed and enters airways. <br />H315 <br />Causes skin irritation. <br />H317 <br />May cause an allergic skin reaction. <br />H319 <br />Causes serious eye irritation. <br />H332 <br />Harmful if inhaled. <br />H334 <br />May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />H335 <br />May cause respiratory irritation. <br />H413 <br />May cause long lasting harmful effects to aquatic life. <br />R20 <br />Harmful by inhalation. <br />R36/37/38 Irritating to eyes, respiratory system and skin. <br />R40 <br />Limited evidence of a carcinogenic effect. <br />R42/43 <br />May cause sensitisation by inhalation and skin contact. <br />R48/20 <br />Harmful: danger of serious damage to health by prolonged exposure through inhalation. <br />R51/53 <br />Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic <br />environment. <br />R65 <br />Harmful: may cause lung damage if swallowed. <br />· Department issuing data specification sheet: Environment protection department. <br />· Contact: Mr. Guido Herfort <br />· Abbreviations and acronyms: <br />ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the <br />International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />GHS: Globally Harmonised System of Classification and Labelling of Chemicals <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />Acute Tox. 4: Acute toxicity, Hazard Category 4 <br />Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 <br />Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 <br />(Contd. on page 9) <br />GB</p> <p>40.0</p> <p>Page 9/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 06.03.2015</p> <p>Version number 10</p> <p>Revision: 06.03.2015</p> <p>Trade name: AQUAFIN-P4 (B-Komp.) <br />(Contd. of page 8) <br />Resp. Sens. 1: Sensitisation - Respirat., Hazard Category 1 <br />Skin Sens. 1: Sensitisation - Skin, Hazard Category 1 <br />Carc. 2: Carcinogenicity, Hazard Category 2 <br />STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 <br />STOT RE 2: Specific target organ toxicity - Repeated exposure, Hazard Category 2 <br />Asp. Tox. 1: Aspiration hazard, Hazard Category 1 <br />Aquatic Chronic 4: Hazardous to the aquatic environment - Chronic Hazard, Category 4</p> <p>· * Data compared to the previous version altered. <br />GB</p>
