40.0
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 06.03.2015 *
Version number 9
Revision: 06.03.2015
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: AQUAFIN-P4 (A-Komp.) · Article number: 205091NEU · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Polyurethane resin · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: guido.herfort@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS07 Acute Tox. 4 H302 Harmful if swallowed. · Classification according to Directive 67/548/EEC or Directive 1999/45/EC Xn; Harmful R22: Harmful if swallowed. · Information concerning particular hazards for human and environment: The product may not leak out in sewerage system, stretch of water or soil. · Classification system: The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information furnished by supplier companies. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS07 · Signal word Warning · Hazard-determining components of labelling: polypropylene glykol ethane-1,2-diol · Hazard statements H302 Harmful if swallowed. · Precautionary statements P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. (Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 06.03.2015
Trade name: AQUAFIN-P4 (A-Komp.) (Contd. of page 1)
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P363 Wash contaminated clothing before reuse. P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: mixture of polyols · Dangerous components: polypropylene glykol Xn R22 Acute Tox. 4, H302 CAS: 107-21-1 ethane-1,2-diol EINECS: 203-473-3 Xn R22 STOT RE 2, H373;
50-100%
2.5-10% Acute Tox. 4, H302
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact Wash with water and soap. · After eye contact Rinse opened eye for several minutes under running water. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Show the pack or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. Use fire fighting measures that suit the environment. · 5.2 Special hazards arising from the substance or mixture No further relevant information available. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Follow the emergency-plan. GB
(Contd. on page 3)
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Trade name: AQUAFIN-P4 (A-Komp.) (Contd. of page 2)
SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Keep away from children. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Store in cool location. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: None. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 107-21-1 ethane-1,2-diol (2.5-10%) WEL Short-term value: 104** mg/m³, 40** ppm Long-term value: 10* 52** mg/m³, 20** ppm Sk *particulate **vapour · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. · Breathing equipment: Not required. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses (Contd. on page 4) GB
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Trade name: AQUAFIN-P4 (A-Komp.) (Contd. of page 3)
· Body protection: Protective work clothing. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Liquid Colour: Light yellow · Smell: Characteristic · Change in condition Melting point/Melting range: Not determined Boiling point/Boiling range: 351 °C · Flash point:
255 °C
· Ignition temperature:
450 °C
· Self-inflammability:
Product is not selfigniting.
· Danger of explosion:
Product is not explosive.
· Density at 20 °C
0.99 g/cm³
· Solubility in / Miscibility with Water: Not miscible or difficult to mix · Viscosity: dynamic at 20 °C: · 9.2 Other information
285 mPas No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: 107-21-1 ethane-1,2-diol Oral LD50 4000 mg/kg (rats) Dermal LD50 10600 mg/kg (rabbit) · Primary irritant effect: No irritant action known. · on the skin: No irritant effect. · on the eye: No irritant effect · Sensitisation: No sensitizing effect known. (Contd. on page 5) GB
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Trade name: AQUAFIN-P4 (A-Komp.) (Contd. of page 4)
· Additional toxicological information: The product is not subject to classification according to the calculation method of the General EC Classification Guidelines for Preparations as issued in the latest version: SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 107-21-1 ethane-1,2-diol EC50 6500 mg/l (Grünalge (Scenedesmus subspicatus)) LC50 >10000 mg/l (Daphnia magna) >18000 mg/l (rainbow trout) >10000 mg/l (orfe) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Smaller quantities can be disposed with household garbage. · European waste catalogue 08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS 08 04 00 wastes from MFSU of adhesives and sealants (including waterproofing products) 08 04 10 waste adhesives and sealants other than those mentioned in 08 04 09 · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. *
SECTION 14: Transport information · 14.1 UN-Number · ADR, ADN, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, ADN, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
Void (Contd. on page 6) GB
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Trade name: AQUAFIN-P4 (A-Komp.) (Contd. of page 5)
· 14.5 Environmental hazards: · Marine pollutant:
No
· 14.6 Special precautions for user
Not applicable.
· 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
Not dangerous according to the above specifications.
· UN "Model Regulation":
-
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · National regulations · Technical instructions (air): · Class Share in % · NK 5.0 · Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H373 May cause damage to organs through prolonged or repeated exposure. R22 Harmful if swallowed. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Acute Tox. 4: Acute toxicity, Hazard Category 4 STOT RE 2: Specific target organ toxicity - Repeated exposure, Hazard Category 2
· * Data compared to the previous version altered. GB