40.0
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 30.01.2015 *
Version number 11
Revision: 30.01.2015
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: AQUAFIN-1K · Article number: 204248 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Thickener pulps · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: guido.herfort@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS05 corrosion Eye Dam. 1 H318 Causes serious eye damage. GHS07 Skin Irrit. 2 H315 Causes skin irritation. STOT SE 3 H335 May cause respiratory irritation. · Classification according to Directive 67/548/EEC or Directive 1999/45/EC Xi; Irritant R37/38-41: Irritating to respiratory system and skin. Risk of serious damage to eyes. · Classification system: The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information furnished by supplier companies. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS05, GHS07 · Signal word Danger · Hazard-determining components of labelling: Cement, portland, chemicals · Hazard statements H315 Causes skin irritation. (Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 30.01.2015
Trade name: AQUAFIN-1K (Contd. of page 1)
H318 Causes serious eye damage. H335 May cause respiratory irritation. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Product based on cement and mineral filler. · Dangerous components: CAS: 65997-15-1 Cement, portland, chemicals 25-50% EINECS: 266-043-4 Xi R37/38-41; Xi R43 Eye Dam. 1, H318; Skin Irrit. 2, H315; STOT SE 3, H335 · Additional information The chromate content in cement is less than 2 ppm so that the rating of the relevant phrase no. 43 is not applicable.
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact Instantly wash with water and soap and rinse thoroughly. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents Use fire fighting measures that suit the environment. Product is not inflammable. · For safety reasons unsuitable extinguishing agents Water with a full water jet. · 5.2 Special hazards arising from the substance or mixture No further relevant information available. (Contd. on page 3) GB
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Trade name: AQUAFIN-1K (Contd. of page 2)
· 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. *
SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Avoid eye- and skin contact. Wear protective clothing. · 6.2 Environmental precautions: Prevent material from reaching sewage system, holes and cellars. · 6.3 Methods and material for containment and cleaning up: Pick up the product mechanically, avoid dust formation. · 6.4 Reference to other sections See Section 8 for information on personal protection equipment.
SECTION 7: Handling and storage · 7.1 Precautions for safe handling Keep away from children. Prevent formation of dust. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Protect against wetness and water. Store in cool location. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. · 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 65997-15-1 Cement, portland, chemicals (25-50%) WEL Long-term value: 10* 4** mg/m³ *inhalable dust **respirable dust · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Vacuum clean contaminated clothing. Do not blow or brush off contamination. Avoid contact with the eyes and skin. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: Use respiratory protective equipment at formation of dust. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min (Contd. on page 4) GB
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Trade name: AQUAFIN-1K (Contd. of page 3)
· Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing. *
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Powder Colour: According to product specification · Smell: Weak, characteristic · Change in condition Melting point/Melting range: Not determined Boiling point/Boiling range: Not determined · Flash point:
Not applicable
· Self-inflammability:
Product is not selfigniting.
· Danger of explosion:
Product is not explosive.
· Density
not determine
· Settled apparent density
1,368 kg/dm³
· Solubility in / Miscibility with Water: Fully miscible · 9.2 Other information No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: No dates existing. · Primary irritant effect: · on the skin: Irritant for skin and mucous membranes. · on the eye: Irritant effect. · Sensitisation: Sensitization possible by skin contact. · Additional toxicological information: The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for Preparations as issued in the latest version: (Contd. on page 5) GB
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Trade name: AQUAFIN-1K (Contd. of page 4)
Irritant SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: No further relevant information available. · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. *
SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 10 00 00 WASTES FROM THERMAL PROCESSES 10 12 00 wastes from manufacture of ceramic goods, bricks, tiles and construction products 10 12 03 particulates and dust 17 00 00 CONSTRUCTION AND DEMOLITION WASTES (INCLUDING EXCAVATED SOIL FROM CONTAMINATED SITES) 17 01 00 concrete, bricks, tiles and ceramics 17 01 01 concrete · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleaning agent: Water, if necessary with cleaning agent. SECTION 14: Transport information · 14.1 UN-Number · ADR
Void
· 14.2 UN proper shipping name · ADR
· 14.3 Transport hazard class(es) · ADR · Class
· 14.4 Packing group · ADR
· 14.5 Environmental hazards:
Not applicable.
· 14.6 Special precautions for user
Not applicable. (Contd. on page 6) GB
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Trade name: AQUAFIN-1K (Contd. of page 5)
· 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional information:
Not dangerous according to the above specifications.
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · National regulations · Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. The classification based on german instructions. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H315 Causes skin irritation. H318 Causes serious eye damage. H335 May cause respiratory irritation. R37/38 Irritating to respiratory system and skin. R41 Risk of serious damage to eyes. R43 May cause sensitisation by skin contact. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1 STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
· * Data compared to the previous version altered. GB