40.0
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 30.01.2015 *
Version number 25
Revision: 30.01.2015
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: AK7P · Article number: 201000 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Tile adhesive · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: guido.herfort@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS05 corrosion Eye Dam. 1 H318 Causes serious eye damage. GHS07 Skin Irrit. 2 H315 Causes skin irritation. STOT SE 3 H335 May cause respiratory irritation. · Classification according to Directive 67/548/EEC or Directive 1999/45/EC Xi; Irritant R37/38-41: Irritating to respiratory system and skin. Risk of serious damage to eyes. · Information concerning particular hazards for human and environment: The product may not leak out in sewerage system, stretch of water or soil. Continual breath in of product-dust may damage your health. Breath-in of the material dust can damage health. The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. · Classification system: The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information furnished by supplier companies. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS05, GHS07 (Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 30.01.2015
Trade name: AK7P (Contd. of page 1)
· Signal word Danger · Hazard-determining components of labelling: Cement, portland, chemicals · Hazard statements H315 Causes skin irritation. H318 Causes serious eye damage. H335 May cause respiratory irritation. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Product based on cement and mineral filler. · Dangerous components: CAS: 65997-15-1 Cement, portland, chemicals 25-50% EINECS: 266-043-4 Xi R37/38-41; Xi R43 Eye Dam. 1, H318; Skin Irrit. 2, H315; STOT SE 3, H335 · Additional information The chromate content in cement is less than 2 ppm so that the rating of the relevant phrase no. 43 is not applicable. For the wording of the listed risk phrases refer to section 16.
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact After contact, clean the skin mechanical and rinse with water and soap. · After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. · After swallowing Avert vomiting. Drink copious amounts of water and provide fresh air. Instantly call for doctor. Show the pack or the label to the doctor. (Contd. on page 3) GB
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Trade name: AK7P (Contd. of page 2)
· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. *
SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents Product is not inflammable. · 5.2 Special hazards arising from the substance or mixture The product formed corrosive water for fire-fighting. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan.
SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Avoid causing dust. Avoid eye- and skin contact. Wear protective clothing. Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Ensure adequate ventilation. Pick up the product mechanically, avoid dust formation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal.
SECTION 7: Handling and storage · 7.1 Precautions for safe handling Keep away from children. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Store in cool location. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. · 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. (Contd. on page 4) GB
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Trade name: AK7P (Contd. of page 3)
· 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 65997-15-1 Cement, portland, chemicals (25-50%) OES Long-term value: 10* 4** mg/m³ *total inhalable dust **respirable dust 1305-62-0 calcium dihydroxide (< 1%) OES Long-term value: 5 mg/m³ ILV · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Vacuum clean contaminated clothing. Do not blow or brush off contamination. Avoid contact with the eyes and skin. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: Use respiratory protective equipment at formation of dust. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Contaminated protection clothes must be cleaned carfully before reuse. Protective work clothing. *
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Powder Colour: Grey · Smell: Weak, characteristic · Odour threshold: Not determined. · pH-value:
Not applicable.
· Change in condition Melting point/Melting range: Boiling point/Boiling range:
Not determined not apply
· Flash point:
Not applicable
· Inflammability (solid, gaseous)
Not determined.
· Ignition temperature: Decomposition temperature:
· Self-inflammability:
Product is not selfigniting.
· Danger of explosion:
Product is not explosive.
· Critical values for explosion: Lower:
Not determined. (Contd. on page 5) GB
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Trade name: AK7P (Contd. of page 4)
Upper: · Steam pressure:
Not determined. Not applicable.
· Density Settled apparent density Relative density Vapour density Evaporation rate · Solubility in / Miscibility with Water:
1,370 kg/dm³ Not determined. Not applicable. Not applicable. miscible
· Partition coefficient (n-octanol/water): Not determined. · Viscosity: dynamic: kinematic: · 9.2 Other information
Not applicable. Not applicable. No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known
SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: 544-17-2 Calciumformiat Oral LD50 3050 mg/kg (rats) Dermal LD50 >2000 mg/kg (rats) Inhalative LC50/4 h >0.67 mg/l (rats) · Primary irritant effect: · on the skin: Irritant for skin and mucous membranes. The produkt has an irritate-effect. · on the eye: Strong irritant with the danger of severe eye injury. Irritant effect. · Sensitisation: No sensitizing effect known. · Additional toxicological information: The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for Preparations as issued in the latest version: Irritant Sensitizing GB
(Contd. on page 6)
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Trade name: AK7P (Contd. of page 5)
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 544-17-2 Calciumformiat EC50 >1000 mg/l (bacterial toxicity) EC50 (48h) >1000 mg/l (Daphnia magna) LC 0 (96h) 1000 mg/l (Brachydanio rerio) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleaning agent: Water, if necessary with cleaning agent.
SECTION 14: Transport information · 14.1 UN-Number · ADR, ADN, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, ADN, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards: · Marine pollutant:
No
· 14.6 Special precautions for user
· 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · UN "Model Regulation":
GB
(Contd. on page 7)
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Trade name: AK7P (Contd. of page 6)
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · National regulations · Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. The classification based on german instructions. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H315 Causes skin irritation. H318 Causes serious eye damage. H335 May cause respiratory irritation. R37/38 Irritating to respiratory system and skin. R41 Risk of serious damage to eyes. R43 May cause sensitisation by skin contact. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1 STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
· * Data compared to the previous version altered. GB