SDS_BETOCRETE-CL210-WP_-_206444_(24)EN.pdf
8 页数
196.7 KB
Download
<h1>SDS_BETOCRETE-CL210-WP_-_206444_(24)EN.pdf</h1> <p>61.0.30</p> <p>Page 1/8</p> <p>Phiếu an toàn hóa chất <br />theo điều Luật hóa chất số: 06/2007/QH12, Điều 29 <br />Printing date 18.11.2025</p> <p>Version number 24</p> <p>Revision: 18.11.2025</p> <p>SECTION 1: Nhận dạng hóa chất và thông tin về nhà cung cấp <br />· Product identifier <br />· Trade name: BETOCRETE-CL210-WP <br />· Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture Concrete/Mortar admixtures <br />· Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH & Co. KG <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Detmold, Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />Fax: ++49 (0)5231/953-123 <br />Internet: www.schomburg.de <br />· Informing department: <br />Department: Environment and Safety <br />************************************ <br />If you have any questions about the Environment and Safety Department, please contact our <br />department. <br />e-mail: SDB@schomburg.de <br />· Emergency telephone number: <br />Poison centre Berlin (24 hours) <br />German & English <br />Tel: ++49 (0)30/30686700 <br />SECTION 2: Nhận dạng đặc tính nguy hiểm của hóa chất <br />· Classification of the substance or mixture <br />GHS05 corrosion <br />Skin Corr. 1A H314 Causes severe skin burns and eye damage. <br />Eye Dam. 1 H318 Causes serious eye damage. <br />· Label elements <br />· GHS label elements <br />The product is classified and labelled according to the Globally Harmonised System (GHS). <br />· Hazard pictograms GHS05 <br />· Signal word Danger <br />· Hazard-determining components of labelling: <br />potassium hydroxide <br />· Hazard statements <br />Causes severe skin burns and eye damage. <br />· Precautionary statements <br />Do not breathe dusts or mists. <br />Wear protective gloves/protective clothing/eye protection/face protection. <br />IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. <br />(Contd. on page 2) <br />VN</p> <p>61.0.30</p> <p>Page 2/8</p> <p>Phiếu an toàn hóa chất <br />theo điều Luật hóa chất số: 06/2007/QH12, Điều 29 <br />Printing date 18.11.2025</p> <p>Version number 24</p> <p>Revision: 18.11.2025</p> <p>Trade name: BETOCRETE-CL210-WP <br />(Contd. of page 1)</p> <p>IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and <br />easy to do. Continue rinsing. <br />Store locked up. <br />Dispose of contents/container in accordance with local/regional/national/international regulations. <br />· Other hazards not applicable <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />SECTION 3: Thông tin về thành phần các chất <br />· Chemical characterisation: Mixtures <br />· Description: aqueous salt water solution with Metal soaps <br />· Dangerous components: <br />584-08-7 potassium carbonate <br />Skin Irrit. 2, H315; Serious eye damage/irritation – Category 2A, H319; <br />STOT SE 3, H335; Acute Tox. 5, H303; Acute Tox. 5, H313</p> <p>10-25%</p> <p>68153-66-2 Kaliumstearat <br />Acute Tox. 5, H303</p> <p><2,5%</p> <p>1310-58-3 potassium hydroxide <br />Skin Corr. 1A, H314; <br />Acute Tox. 4, H302 <br />Specific concentration limits: Skin Corr. 1A; H314: C ≥ 5 % <br />Skin Corr. 1B; H314: 2 % ≤ C < 5 % <br />Skin Irrit. 2; H315: 0,5 % ≤ C < 2 % <br />Eye Irrit. 2; H319: 0,5 % ≤ C < 2 % <br />· Additional information For the wording of the listed hazard phrases refer to section 16.</p> <p>0-<1%</p> <p>SECTION 4: Biện pháp sơ cứu về y tế <br />· Description of first aid measures <br />· General information <br />Instantly remove any clothing soiled by the product. <br />Symptoms of poisoning may even occur after several hours; therefore medical observation for at <br />least 48 hours after the accident. <br />Personal protection for the First Aider. <br />It is possible to choke in case of vomiting in unconsciousness. <br />Bring unconscious persons into a stable position on side. <br />Keep the respiratory tract free (remove dentures and vomiting). <br />Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage <br />of breathing: artificial respiration. <br />Take up a doctor immediately! <br />· After inhalation Supply fresh air or oxygen; call for doctor. <br />· After skin contact <br />If symptoms appearance, call the doctor. <br />Change immediately contaminated clothes. <br />Instantly wash with water and soap and rinse thoroughly. <br />Don't use solvents to clean the skin. <br />· After eye contact <br />Gently rinse the eyes under running water for at least 10 minutes with the eyelids open. If possible, <br />remove any contact lenses and continue rinsing. Consult a doctor. <br />· After swallowing <br />Show the packaging or the label to the doctor. <br />Drink copious amounts of water. Avert vomiting. Instantly call for doctor. <br />(Contd. on page 3) <br />VN</p> <p>61.0.30</p> <p>Page 3/8</p> <p>Phiếu an toàn hóa chất <br />theo điều Luật hóa chất số: 06/2007/QH12, Điều 29 <br />Printing date 18.11.2025</p> <p>Version number 24</p> <p>Revision: 18.11.2025</p> <p>Trade name: BETOCRETE-CL210-WP <br />(Contd. of page 2)</p> <p>· Information for doctor <br />· Most important symptoms and effects, both acute and delayed <br />No further relevant information available. <br />· Indication of any immediate medical attention and special treatment needed <br />No further relevant information available. <br />SECTION 5: Biện pháp xử lý khi có hỏa hoạn <br />· Extinguishing media <br />· Suitable extinguishing agents <br />Product is not inflammable. <br />CO2, extinguishing powder or water jet. Fight larger fires with water jet. <br />Use fire fighting measures that suit the environment. <br />· Special hazards arising from the substance or mixture <br />Formation of poisonous gases during heating or in fires. <br />· Advice for firefighters <br />· Protective equipment: Wear self-contained breathing apparatus. <br />· Additional information <br />Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. <br />Product is inflammable during water-component is existing. <br />Follow the emergency-plan. <br />Burst- and explosion-danger by increasing pressure. <br />In case of fire chill the container with water spray. <br />SECTION 6: Biện pháp phòng ngừa, ứng phó khi có sự cố <br />· Personal precautions, protective equipment and emergency procedures <br />Bring persons out of danger. <br />Wear protective equipment. Keep unprotected persons away. <br />Wear protective clothing. <br />· Environmental precautions: <br />Do not allow product to reach sewage system or water bodies. <br />Inform respective authorities in case product reaches water or sewage system. <br />· Methods and material for containment and cleaning up: <br />Use neutralising agent. <br />Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). <br />Ensure adequate ventilation. <br />· Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />See Section 13 for information on disposal. <br />SECTION 7: Yêu cầu về sử dụng, bảo quản <br />· Handling <br />· Precautions for safe handling <br />Store in cool, dry place in tightly closed containers. <br />Keep away from heat and direct sunlight. <br />Ensure good ventilation/extraction at the workplace. <br />Prevent formation of aerosols. <br />Keep out of the reach of children <br />For personal protection equipment, see section 8. <br />· Information about protection against explosions and fires: No special measures required. <br />· Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: Store only in the original container. <br />(Contd. on page 4) <br />VN</p> <p>61.0.30</p> <p>Page 4/8</p> <p>Phiếu an toàn hóa chất <br />theo điều Luật hóa chất số: 06/2007/QH12, Điều 29 <br />Printing date 18.11.2025</p> <p>Version number 24</p> <p>Revision: 18.11.2025</p> <p>Trade name: BETOCRETE-CL210-WP <br />(Contd. of page 3)</p> <p>· Information about storage in one common storage facility: Not required. <br />· Further information about storage conditions: <br />Protect from frost. <br />Keep container tightly sealed. <br />Store in cool, dry conditions in well sealed containers. <br />Store in a locked cabinet and out of the reach of children. <br />· Specific end use(s) No further relevant information available. <br />SECTION 8: Kiểm soát phơi nhiễm/yêu cầu về thiết bị bảo vệ cá nhân <br />· Additional information about design of technical systems: <br />It must be possible to wash the skin in the working area. <br />Eye-wash bottle must be available. <br />· Control parameters <br />· Components with critical values that require monitoring at the workplace: <br />1310-58-3 potassium hydroxide (<1%) <br />REL (USA) Ceiling limit: 2 mg/m³ <br />TLV (USA) Ceiling limit: 2 mg/m³ <br />· Regulatory information <br />REL (USA): Guide to Occupational Exposure Values (NIOSH RELs) <br />TLV (USA): Guide to Occupational Exposure Values (TLV) <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· Exposure controls <br />· Personal protective equipment <br />· General protective and hygienic measures <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />Keep away from foodstuffs, beverages and food. <br />Instantly remove any soiled and impregnated garments. <br />Avoid contact with the eyes and skin. <br />Do not eat, drink or smoke while working. <br />Use skin protection cream for preventive skin protection. <br />Be sure to clean skin thoroughly after work and before breaks. <br />· Breathing equipment: Not necessary if room is well-ventilated. <br />· Protection of hands: <br />In case of wearing synthetic protective gloves use cotton-gloves as underwear. <br />The glove material has to be impermeable and resistant to the product/ the substance/ the <br />preparation. <br />Selection of the glove material on consideration of the penetration times, rates of diffusion and the <br />degradation <br />· Material of gloves <br />Gloves made of: Natural latex, polychloroprene, nitrile rubber. <br />(Chemical protection gloves of category 3, recognisable by the CE mark with four-digit test number). <br />The selection of the suitable gloves does not only depend on the material, but also on further marks <br />of quality and varies from manufacturer to manufacturer. As the product is a preparation of several <br />substances, the resistance of the glove material can not be calculated in advance and has therefore <br />to be checked prior to the application. <br />· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and <br />has to be observed. <br />· Not suitable are gloves made of the following materials: <br />Leather gloves. <br />Gloves made of thick fabric. <br />· Eye protection: <br />Suitable safety goggles in accordance with DIN EN 166. <br />In case of splashing use protecting basket-glasses. <br />· Body protection: <br />Contaminated clothing must be changed immediately. <br />(Contd. on page 5) <br />VN</p> <p>61.0.30</p> <p>Page 5/8</p> <p>Phiếu an toàn hóa chất <br />theo điều Luật hóa chất số: 06/2007/QH12, Điều 29 <br />Printing date 18.11.2025</p> <p>Version number 24</p> <p>Revision: 18.11.2025</p> <p>Trade name: BETOCRETE-CL210-WP <br />(Contd. of page 4)</p> <p>long-sleeved clothing <br />Protective work clothing. <br />SECTION 9: Đặc tính lý, hóa của hóa chất <br />· Information on basic physical and chemical properties <br />· General Information <br />· Appearance: <br />Form: <br />Fluid <br />Colour: <br />milky <br />· Smell: <br />Characteristic <br />· Odour threshold: <br />Not determined. <br />· pH-value at 20 °C:</p> <p>>11,5</p> <p>· Change in condition <br />Melting point/freezing point: <br />0 °C <br />Initial boiling point and boiling range: 100 °C <br />· Flash point:</p> <p>Not applicable</p> <p>· Inflammability (solid, gaseous)</p> <p>Not applicable.</p> <p>· Decomposition temperature:</p> <p>Not determined.</p> <p>· Self-inflammability:</p> <p>Product is not selfigniting.</p> <p>· Explosive properties:</p> <p>Product is not explosive.</p> <p>· Critical values for explosion: <br />Lower: <br />Upper:</p> <p>Not determined. <br />Not determined.</p> <p>· Steam pressure:</p> <p>Not determined.</p> <p>· Density at 20 °C <br />· Relative density <br />· Vapour density <br />· Evaporation rate</p> <p>1,025 g/cm³ <br />Not determined. <br />Not determined. <br />Not determined.</p> <p>· Solubility in / Miscibility with <br />Water:</p> <p>miscible</p> <p>· Partition coefficient: n-octanol/water:</p> <p>Not determined.</p> <p>· Viscosity: <br />dynamic: <br />kinematic:</p> <p>Not determined. <br />Not determined.</p> <p>· Other information</p> <p>No further relevant information available.</p> <p>SECTION 10: Mức ổn định và phản ứng của hóa chất <br />· Reactivity No further relevant information available. <br />· Chemical stability <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· Possibility of hazardous reactions No dangerous reactions known <br />· Conditions to avoid No further relevant information available. <br />· Incompatible materials: No further relevant information available. <br />(Contd. on page 6) <br />VN</p> <p>61.0.30</p> <p>Page 6/8</p> <p>Phiếu an toàn hóa chất <br />theo điều Luật hóa chất số: 06/2007/QH12, Điều 29 <br />Printing date 18.11.2025</p> <p>Version number 24</p> <p>Revision: 18.11.2025</p> <p>Trade name: BETOCRETE-CL210-WP <br />(Contd. of page 5)</p> <p>· Hazardous decomposition products: No dangerous decomposition products known <br />SECTION 11: Thông tin về độc tính <br />· Information on toxicological effects <br />· Acute toxicity <br />· LD/LC50 values that are relevant for classification: <br />584-08-7 potassium carbonate <br />Oral <br />LD50 >2.000 mg/kg (rats) (OECD 401) <br />Dermal LD50 >2.000 mg/kg (Kan) <br />68153-66-2 Kaliumstearat <br />Oral <br />LD50 >2.000 mg/kg (rats) <br />1310-58-3 potassium hydroxide <br />Oral <br />LD50 300 mg/kg (rats) <br />· Primary irritant effect: <br />· Skin corrosion/irritation <br />Corrosive <br />Caustic effect on skin and mucous membranes. <br />Irritant for skin and mucous membranes. <br />· Serious eye damage/irritation <br />Corrosive <br />Strong caustic effect. <br />· Respiratory or skin sensitisation No sensitizing effect known. <br />· Additional toxicological information: <br />The product shows the following dangers according to the calculation method of the General EC <br />Classification Guidelines for Preparations as issued in the latest version: <br />Corrosive <br />Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation <br />of esophagus and stomach. <br />SECTION 12: Thông tin về sinh thái <br />· Toxicity <br />· Aquatic toxicity: <br />68153-66-2 Kaliumstearat <br />LC50 <br />>100 mg/l (fish toxicity) <br />1310-58-3 potassium hydroxide <br />LC50/96h 80 mg/l (Gambusia affinis) <br />45,4 mg/l (rainbow trout) <br />EC50 (48h) 40,4 mg/l (water flea (Ceriodaphnia spec) <br />40 mg/l (acute toxicity (invertebrates)) <br />· Persistence and degradability No further relevant information available. <br />· Behaviour in environmental systems: <br />· Bioaccumulative potential No further relevant information available. <br />· Mobility in soil No further relevant information available. <br />· Additional ecological information: <br />· General notes: <br />Water hazard class 2 (Self-assessment): hazardous for water. <br />Do not allow product to reach ground water, water bodies or sewage system. <br />Must not reach sewage water or drainage ditch undiluted or unneutralised. <br />Danger to drinking water if even small quantities leak into soil. <br />(Contd. on page 7) <br />VN</p> <p>61.0.30</p> <p>Page 7/8</p> <p>Phiếu an toàn hóa chất <br />theo điều Luật hóa chất số: 06/2007/QH12, Điều 29 <br />Printing date 18.11.2025</p> <p>Version number 24</p> <p>Revision: 18.11.2025</p> <p>Trade name: BETOCRETE-CL210-WP <br />(Contd. of page 6)</p> <p>· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />· Other adverse effects No further relevant information available. <br />SECTION 13: Thông tin về thải bỏ <br />· Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />· Uncleaned packagings: <br />· Recommendation: Disposal must be made according to official regulations. <br />· Recommended cleaning agent: Water, if necessary with cleaning agent. <br />SECTION 14: Thông tin khi vận chuyển <br />· UN-Number <br />· ADR, ADN, IMDG, IATA</p> <p>Void</p> <p>· UN proper shipping name <br />· ADR, ADN, IMDG, IATA</p> <p>Void</p> <p>· Transport hazard class(es) <br />· ADR, ADN, IMDG, IATA <br />· Class</p> <p>Void</p> <p>· Packing group <br />· ADR, IMDG, IATA</p> <p>Void</p> <p>· Environmental hazards: <br />· Marine pollutant:</p> <p>No</p> <p>· Special precautions for user</p> <p>Not applicable.</p> <p>· Transport in bulk according to Annex II of <br />Marpol and the IBC Code <br />Not applicable. <br />· UN "Model Regulation":</p> <p>Void</p> <p>SECTION 15: Thông tin về pháp luật <br />· Safety, health and environmental regulations/legislation specific for the substance or mixture <br />· Chemicals subject to conditional production or trading in industrial sector <br />1310-58-3 potassium hydroxide <br />· Restricted chemicals in production and business in industry <br />None of the ingredients is listed. <br />· Hazardous chemicals that require elaboration of chemical prevention and response plans <br />and maintenance of safety distances - Maximum volume storage limit (kg) <br />None of the ingredients is listed. <br />· List of chemicals subject to compulsory declaration <br />1310-58-3 potassium hydroxide <br />· GHS label elements <br />The product is classified and labelled according to the Globally Harmonised System (GHS). <br />· Hazard pictograms GHS05 <br />· Signal word Danger <br />(Contd. on page 8) <br />VN</p> <p>61.0.30</p> <p>Page 8/8</p> <p>Phiếu an toàn hóa chất <br />theo điều Luật hóa chất số: 06/2007/QH12, Điều 29 <br />Printing date 18.11.2025</p> <p>Version number 24</p> <p>Revision: 18.11.2025</p> <p>Trade name: BETOCRETE-CL210-WP <br />(Contd. of page 7)</p> <p>· Hazard-determining components of labelling: <br />potassium hydroxide <br />· Hazard statements <br />Causes severe skin burns and eye damage. <br />· Precautionary statements <br />Do not breathe dusts or mists. <br />Wear protective gloves/protective clothing/eye protection/face protection. <br />IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. <br />IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and <br />easy to do. Continue rinsing. <br />Store locked up. <br />Dispose of contents/container in accordance with local/regional/national/international regulations. <br />· Directive 2012/18/EU <br />· Named dangerous substances - ANNEX I None of the ingredients is listed. <br />· Chemical safety assessment: A Chemical Safety Assessment has not been carried out. <br />SECTION 16: Các thông tin cần thiết khác <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for <br />any specific product features and shall not establish a legally valid contractual relationship. <br />· Department issuing data specification sheet: Department EHS (Environment-Health-Safety) <br />· Abbreviations and acronyms: <br />ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning <br />the International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />PBT: Persistent, Bioaccumulative and Toxic <br />vPvB: very Persistent and very Bioaccumulative <br />Acute Tox. 4: Acute toxicity – Category 4 <br />Acute Tox. 5: Acute toxicity – Category 5 <br />Skin Corr. 1A: Skin corrosion/irritation – Category 1A <br />Skin Irrit. 2: Skin corrosion/irritation – Category 2 <br />Eye Dam. 1: Serious eye damage/eye irritation – Category 1 <br />Serious eye damage/irritation – Category 2A: Serious eye damage/eye irritation – Category 2A <br />STOT SE 3: Specific target organ toxicity (single exposure) – Category 3 <br />VN</p>
