SDS_ASOLIN-WS_-_201246_(28)EN_GB.pdf
9 页数
437.4 KB
Download
<h1>SDS_ASOLIN-WS_-_201246_(28)EN_GB.pdf</h1> <p>63.3.7</p> <p>Page 1/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 07.10.2026 <br />*</p> <p>Version number 28</p> <p>Revision: 07.10.2026</p> <p>SECTION 1: Identification of the substance/mixture and of the company/undertaking <br />· 1.1 Product identifier <br />· Trade name: ASOLIN-WS <br />· UFI: 8VAY-2JT2-N00C-Q44Q <br />· 1.2 Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture Impregnation <br />· 1.3 Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH & Co. KG <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Germany <br />Phone: +49 5231 953 00 <br />E-mail: info@schomburg.de <br />Website: www.schomburg.de <br />· Informing department: <br />Environment and Safety Department <br />SCHOMBURG GmbH & Co. KG <br />E-mail: SDB@schomburg.de <br />· 1.4 Emergency telephone number: <br />Members of the public seeking specific information on poisons should contact: <br />In England and Wales: NHS 111 - dial 111 (24h) <br />In Scotland: NHS 24 - dial 111</p> <p>*</p> <p>SECTION 2: Hazards identification <br />· 2.1 Classification of the substance or mixture <br />· Classification according to Regulation (EC) No 1272/2008 <br />GHS02 flame <br />Flam. Liq. 3 H226 Flammable liquid and vapour. <br />GHS08 health hazard <br />Asp. Tox. 1 H304 May be fatal if swallowed and enters airways. <br />GHS07 <br />STOT SE 3 H336 May cause drowsiness or dizziness. <br />· Additional information: <br />The full text of the classification and labelling elements mentioned is given in Section 16. <br />· 2.2 Label elements <br />· Labelling according to Regulation (EC) No 1272/2008 <br />The product is classified and labelled according to the GB CLP regulation. <br />· Hazard pictograms GHS02, GHS07, GHS08 <br />· Signal word Danger <br />(Contd. on page 2) <br />GB</p> <p>63.3.7</p> <p>Page 2/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 07.10.2026</p> <p>Version number 28</p> <p>Revision: 07.10.2026</p> <p>Trade name: ASOLIN-WS <br />(Contd. of page 1)</p> <p>· Hazard-determining components of labelling: <br />Hydrocarbons, C9–C11, n-alkanes, isoalkanes, cyclenes, <2% aromatics <br />· Hazard statements <br />H226 Flammable liquid and vapour. <br />H336 May cause drowsiness or dizziness. <br />H304 May be fatal if swallowed and enters airways. <br />· Precautionary statements <br />P210 <br />Keep away from heat, hot surfaces, sparks, open flames and other ignition <br />sources. No smoking. <br />P301+P310 <br />IF SWALLOWED: Immediately call a POISON CENTER/ doctor. <br />P331 <br />Do NOT induce vomiting. <br />P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin <br />with water [or shower]. <br />P405 <br />Store locked up. <br />P501 <br />Dispose of contents/container in accordance with local/regional/national/ <br />international regulations. <br />· Additional information: <br />EUH208 Contains trimethoxy(2,4,4-trimethylpentyl)silane. May produce an allergic reaction. <br />· 2.3 Other hazards not applicable <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable <br />· vPvB: Not applicable <br />· Determination of endocrine-disrupting properties Not applicable <br />*</p> <p>SECTION 3: Composition/information on ingredients <br />· 3.2 Mixtures <br />· Description: Alkylpolysiloxan/-silan-mixture in organic solvents. <br />· Dangerous components: <br />EC number: 919-857-5 Hydrocarbons, C9–C11, n-alkanes, isoalkanes, cyclenes, <2% <br />50-100% <br />aromatics <br />Flam. Liq. 3, H226; <br />Asp. Tox. 1, H304; <br />STOT SE 3, H336 <br />CAS: 34396-03-7</p> <p>trimethoxy(2,4,4-trimethylpentyl)silane <br />Flam. Liq. 3, H226; <br />Skin Sens. 1B, H317 <br />· Additional information For the wording of the listed hazard phrases refer to section 16. <br />*</p> <p>0-<1%</p> <p>SECTION 4: First aid measures <br />· 4.1 Description of first aid measures <br />· General information <br />Personal protection for the First Aider. <br />It is possible to choke in case of vomiting in unconsciousness. <br />Bring unconscious persons into a stable position on side. <br />Keep the respiratory tract free (remove dentures and vomiting). <br />Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage <br />of breathing: artificial respiration. <br />Take up a doctor immediately! <br />· After inhalation Supply fresh air or oxygen; call for doctor. <br />· After skin contact <br />Change immediately contaminated clothes. <br />Rinse with large amount of water and soap. <br />Don't use solvents to clean the skin. <br />· After eye contact <br />Gently rinse the eyes under running water for at least 10 minutes with the eyelids open. If possible, <br />remove any contact lenses and continue rinsing. Consult a doctor. <br />· After swallowing <br />Drink copious amounts of water and provide fresh air. Instantly call for doctor. <br />Prevent vomiting if possible. <br />(Contd. on page 3) <br />GB</p> <p>63.3.7</p> <p>Page 3/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 07.10.2026</p> <p>Version number 28</p> <p>Revision: 07.10.2026</p> <p>Trade name: ASOLIN-WS <br />(Contd. of page 2)</p> <p>Show the packaging or the label to the doctor. <br />· 4.2 Most important symptoms and effects, both acute and delayed <br />No further relevant information available. <br />· 4.3 Indication of any immediate medical attention and special treatment needed <br />No further relevant information available. <br />*</p> <p>SECTION 5: Firefighting measures <br />· 5.1 Extinguishing media <br />· Suitable extinguishing agents <br />CO2, sand, extinguishing powder. Do not use water. <br />Use fire fighting measures that suit the environment. <br />· For safety reasons unsuitable extinguishing agents <br />Water. <br />Water with a full water jet. <br />· 5.2 Special hazards arising from the substance or mixture <br />Formation of poisonous gases during heating or in fires. <br />· 5.3 Advice for firefighters <br />· Protective equipment: Wear self-contained breathing apparatus. <br />· Additional information <br />Follow the emergency-plan. <br />Burst- and explosion-danger by increasing pressure. <br />In case of fire chill the container with water spray.</p> <p>*</p> <p>SECTION 6: Accidental release measures <br />· 6.1 Personal precautions, protective equipment and emergency procedures <br />Wear protective equipment. Keep unprotected persons away. <br />Bring persons out of danger. <br />Wear protective clothing. <br />· 6.2 Environmental precautions: <br />Do not allow product to reach sewage system or water bodies. <br />Inform respective authorities in case product reaches water or sewage system. <br />· 6.3 Methods and material for containment and cleaning up: <br />Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). <br />Ensure adequate ventilation. <br />Do not flush with water or aqueous cleansing agents <br />· 6.4 Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />See Section 13 for information on disposal.</p> <p>*</p> <p>SECTION 7: Handling and storage <br />· 7.1 Precautions for safe handling <br />Keep away from heat and direct sunlight. <br />Ensure good ventilation/extraction at the workplace. <br />Prevent formation of aerosols. <br />Keep out of the reach of children <br />For personal protection equipment, see section 8. <br />· Information about protection against explosions and fires: <br />Keep ignition sources away - Do not smoke. <br />Protect from heat. <br />Protect against electrostatic charges. <br />· 7.2 Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: Store only in the original container. <br />· Information about storage in one common storage facility: <br />Please follow the rules of the VCI-Storage-Concept for chemicals. <br />(Contd. on page 4) <br />GB</p> <p>63.3.7</p> <p>Page 4/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 07.10.2026</p> <p>Version number 28</p> <p>Revision: 07.10.2026</p> <p>Trade name: ASOLIN-WS <br />(Contd. of page 3)</p> <p>· Further information about storage conditions: <br />Protect from frost. <br />Keep container tightly sealed. <br />Store in cool, dry conditions in well sealed containers. <br />Protect from heat and direct sunlight. <br />Store in a locked cabinet and out of the reach of children. <br />· 7.3 Specific end use(s) No further relevant information available. <br />*</p> <p>SECTION 8: Exposure controls/personal protection <br />· 8.1 Control parameters <br />· Components with critical values that require monitoring at the workplace: <br />The product does not contain any relevant quantities of materials with critical values that have to be <br />monitored at the workplace. <br />· DNELs <br />34396-03-7 trimethoxy(2,4,4-trimethylpentyl)silane <br />Inhalative DNEL 130 mg/mg³ (human) <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· 8.2 Exposure controls <br />· Appropriate engineering controls <br />It must be possible to wash the skin in the working area. <br />Eye-wash bottle must be available. <br />· Individual protection measures, such as personal protective equipment <br />· General protective and hygienic measures <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />Keep away from foodstuffs, beverages and food. <br />Avoid contact with the eyes and skin. <br />Do not eat, drink or smoke while working. <br />Use skin protection cream for preventive skin protection. <br />Be sure to clean skin thoroughly after work and before breaks. <br />When the material is hardened on the skin, remove it carfully mechanically. <br />· Breathing equipment: <br />In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer <br />exposure use breathing apparatus that is independent of circulating air. <br />Recommended filter type: A <br />· Hand protection <br />Hand Protection: Nitril-rubber-latex-gloves. <br />In case of wearing synthetic protective gloves use cotton-gloves as underwear. <br />The glove material has to be impermeable and resistant to the product/ the substance/ the <br />preparation. <br />Selection of the glove material on consideration of the penetration times, rates of diffusion and the <br />degradation <br />· Material of gloves <br />The selection of the suitable gloves does not only depend on the material, but also on further marks <br />of quality and varies from manufacturer to manufacturer. As the product is a preparation of several <br />substances, the resistance of the glove material can not be calculated in advance and has therefore <br />to be checked prior to the application. <br />· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and <br />has to be observed. <br />· Not suitable are gloves made of the following materials: <br />Leather gloves. <br />Gloves made of thick fabric. <br />· Eye/face protection Suitable eye protection: Basket goggles. (DIN EN 166) <br />· Body protection: <br />Protective work clothing. <br />Solvent resistant protective clothing <br />GB</p> <p>(Contd. on page 5)</p> <p>63.3.7</p> <p>Page 5/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 07.10.2026</p> <p>Version number 28</p> <p>Revision: 07.10.2026</p> <p>Trade name: ASOLIN-WS <br />(Contd. of page 4)</p> <p>*</p> <p>SECTION 9: Physical and chemical properties <br />· 9.1 Information on basic physical and chemical properties <br />· General Information <br />· Physical state <br />Liquid <br />· Colour: <br />Clear <br />· Smell: <br />Aromatic <br />· Odour threshold: <br />Not determined <br />· Melting point/freezing point: <br />Not determined <br />· Boiling point or initial boiling point and <br />boiling range <br />153 °C <br />· Flammability <br />Flammable. <br />· Lower and upper explosion limit <br />· Lower: <br />Not determined <br />· Upper: <br />Not determined <br />· Flash point: <br />40 °C <br />· Decomposition temperature: <br />Not determined <br />· pH <br />Mixture is non-soluble (in water). <br />· Viscosity: <br />· Kinematic viscosity at 20 °C <br />1.45 mm²/s <br />· dynamic: <br />Not determined <br />· Solubility <br />· Water: <br />Emulsifiable <br />· Partition coefficient n-octanol/water (log <br />value) <br />Not determined <br />· Steam pressure: <br />Not determined <br />· Density and/or relative density <br />· Density at 20 °C <br />0.785 g/cm³ <br />· Relative density <br />Not determined <br />· Vapour density <br />Not determined <br />· Particle characteristics <br />68909-20-6 silanamine, 1,1,1-trimethyl-N(trimethylsilyl)-, hydrolysis products with silica: <br />set including amorphous nanoforms <br />Number-based particle size distribution: d50: 6-50 <br />nm <br />surface-treated nanoforms <br />Shape: fractal aggregates <br />Crystallinity: amorphous nanoform <br />Aspect ratio: 1 - 3 <br />Surface-to-mass ratio: 40 - 350 m²/g <br />Methods of analysis: TEM, XRD <br />· 9.2 Other information <br />· Appearance: <br />· Form: <br />Fluid <br />· Important information on protection of health <br />and environment, and on safety. <br />· Self-inflammability: <br />Product is not selfigniting. <br />· Explosive properties: <br />Product is not explosive. However, formation of <br />explosive air/steam mixtures is possible. <br />· Change in condition <br />· Evaporation rate <br />Not determined <br />· Information with regard to physical hazard <br />classes <br />· Explosives <br />· Flammable gases <br />· Aerosols <br />· Oxidising gases <br />· Gases under pressure <br />· Flammable liquids</p> <p>Void <br />Void <br />Void <br />Void <br />Void <br />Flammable liquid and vapour. <br />(Contd. on page 6) <br />GB</p> <p>63.3.7</p> <p>Page 6/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 07.10.2026</p> <p>Version number 28</p> <p>Revision: 07.10.2026</p> <p>Trade name: ASOLIN-WS <br />(Contd. of page 5)</p> <p>· Flammable solids <br />· Self-reactive substances and mixtures <br />· Pyrophoric liquids <br />· Pyrophoric solids <br />· Self-heating substances and mixtures <br />· Substances and mixtures, which emit <br />flammable gases in contact with water <br />· Oxidising liquids <br />· Oxidising solids <br />· Organic peroxides <br />· Corrosive to metals <br />· Desensitised explosives</p> <p>Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void</p> <p>SECTION 10: Stability and reactivity <br />· 10.1 Reactivity No further relevant information available. <br />· 10.2 Chemical stability <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· 10.3 Possibility of hazardous reactions No dangerous reactions known <br />· 10.4 Conditions to avoid No further relevant information available. <br />· 10.5 Incompatible materials: No further relevant information available. <br />· 10.6 Hazardous decomposition products: Inflammable gases/vapours <br />*</p> <p>SECTION 11: Toxicological information <br />· 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 <br />· Acute toxicity Based on available data, the classification criteria are not met. <br />· LD/LC50 values that are relevant for classification: <br />34396-03-7 trimethoxy(2,4,4-trimethylpentyl)silane <br />Oral LD50 2,000 mg/kg (rats) <br />· Primary irritant effect: No irritant action known. <br />· Skin corrosion/irritation Slight irritant effect possible. <br />· Serious eye damage/irritation Irritate-effect is possible. <br />· STOT-single exposure May cause drowsiness or dizziness. <br />· Aspiration hazard May be fatal if swallowed and enters airways. <br />· 11.2 Information on other hazards <br />· Endocrine disrupting properties <br />None of the ingredients is listed.</p> <p>*</p> <p>SECTION 12: Ecological information <br />· 12.1 Toxicity <br />· Aquatic toxicity: No further relevant information available. <br />· 12.2 Persistence and degradability No further relevant information available. <br />· 12.3 Bioaccumulative potential No further relevant information available. <br />· 12.4 Mobility in soil No further relevant information available. <br />· 12.5 Results of PBT and vPvB assessment <br />· PBT: Not applicable <br />· vPvB: Not applicable <br />· 12.6 Endocrine disrupting properties <br />The product does not contain substances with endocrine disrupting properties. <br />(Contd. on page 7) <br />GB</p> <p>63.3.7</p> <p>Page 7/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 07.10.2026</p> <p>Version number 28</p> <p>Revision: 07.10.2026</p> <p>Trade name: ASOLIN-WS <br />(Contd. of page 6)</p> <p>· 12.7 Other adverse effects <br />· Additional ecological information: <br />· General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. <br />SECTION 13: Disposal considerations <br />· 13.1 Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />· Uncleaned packagings: <br />· Recommendation: Disposal must be made according to official regulations. <br />SECTION 14: Transport information <br />· 14.1 UN number or ID number <br />· ADR, IMDG, IATA <br />· 14.2 UN proper shipping name <br />· ADR <br />· IMDG <br />· IATA</p> <p>UN3295 <br />3295 HYDROCARBONS, LIQUID, N.O.S. <br />HYDROCARBONS, LIQUID, N.O.S., MARINE <br />POLLUTANT <br />HYDROCARBONS, LIQUID, N.O.S.</p> <p>· 14.3 Transport hazard class(es) <br />· ADR, IATA</p> <p>· Class <br />· Label</p> <p>3 Flammable liquids. <br />3</p> <p>· IMDG</p> <p>· Class <br />· Label</p> <p>3 Flammable liquids. <br />3</p> <p>· 14.4 Packing group <br />· ADR, IMDG, IATA</p> <p>III</p> <p>· 14.5 Environmental hazards: <br />· Marine pollutant: <br />· 14.6 Special precautions for user <br />· Kemler Number: <br />· EMS Number: <br />· Stowage Category</p> <p>Yes <br />Symbol (fish and tree) <br />Warning: Flammable liquids. <br />30 <br />F-E,S-D <br />A</p> <p>· 14.7 Maritime transport in bulk according to <br />IMO instruments <br />Not applicable <br />(Contd. on page 8) <br />GB</p> <p>63.3.7</p> <p>Page 8/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 07.10.2026</p> <p>Version number 28</p> <p>Revision: 07.10.2026</p> <p>Trade name: ASOLIN-WS <br />(Contd. of page 7)</p> <p>· Transport/Additional information: <br />· ADR <br />· Limited quantities (LQ) <br />· Excepted quantities (EQ) <br />· Transport category <br />· IMDG <br />· Limited quantities (LQ) <br />· Excepted quantities (EQ)</p> <p>· UN "Model Regulation":</p> <p>5L <br />Code: E1 <br />Maximum net quantity per inner packaging: 30 ml <br />Maximum net quantity per outer packaging: 1000 ml <br />3 <br />5L <br />Code: E1 <br />Maximum net quantity per inner packaging: 30 ml <br />Maximum net quantity per outer packaging: 1000 ml <br />UN 3295 HYDROCARBONS, LIQUID, N.O.S. 3, III</p> <p>SECTION 15: Regulatory information <br />· 15.1 Safety, health and environmental regulations/legislation specific for the substance or <br />mixture <br />· Poisons Act <br />· Regulated explosives precursors <br />None of the ingredients is listed. <br />· Regulated poisons <br />None of the ingredients is listed. <br />· Reportable explosives precursors <br />None of the ingredients is listed. <br />· Reportable poisons <br />None of the ingredients is listed. <br />· Directive 2012/18/EU <br />· Named dangerous substances - ANNEX I None of the ingredients is listed. <br />· Seveso category P5c FLAMMABLE LIQUIDS <br />· Qualifying quantity (tonnes) for the application of lower-tier requirements 5,000 t <br />· Qualifying quantity (tonnes) for the application of upper-tier requirements 50,000 t <br />· National regulations <br />· Technical instructions (air): <br />· Class Share in % <br />· NK <br />94.1 <br />· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. <br />*</p> <p>SECTION 16: Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for <br />any specific product features and shall not establish a legally valid contractual relationship. <br />· Relevant phrases <br />H226 Flammable liquid and vapour. <br />H304 May be fatal if swallowed and enters airways. <br />H317 May cause an allergic skin reaction. <br />H336 May cause drowsiness or dizziness. <br />· Department issuing data specification sheet: Environment protection department. <br />· Abbreviations and acronyms: <br />ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning <br />the International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />GHS: Globally Harmonised System of Classification and Labelling of Chemicals <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />(Contd. on page 9) <br />GB</p> <p>63.3.7</p> <p>Page 9/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 07.10.2026</p> <p>Version number 28</p> <p>Revision: 07.10.2026</p> <p>Trade name: ASOLIN-WS <br />(Contd. of page 8) <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />DNEL: Derived No-Effect Level (UK REACH) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />PBT: Persistent, Bioaccumulative and Toxic <br />vPvB: very Persistent and very Bioaccumulative <br />Flam. Liq. 3: Flammable liquids – Category 3 <br />Skin Sens. 1B: Skin sensitisation – Category 1B <br />STOT SE 3: Specific target organ toxicity (single exposure) – Category 3 <br />Asp. Tox. 1: Aspiration hazard – Category 1</p> <p>· * Data compared to the previous version altered. <br />GB</p>
