SDS_ASO-R005_-_206400_(28)EN.pdf
9 页数
239.7 KB
Download
<h1>SDS_ASO-R005_-_206400_(28)EN.pdf</h1> <p>61.0.6</p> <p>Page 1/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 25.07.2025 <br />*</p> <p>Version number 28</p> <p>Revision: 25.07.2025</p> <p>SECTION 1: Identification of the substance/mixture and of the company/undertaking <br />· 1.1 Product identifier <br />· Trade name: ASO-R005 <br />· UFI: 6DME-QK73-700Y-0KH7 <br />· 1.2 Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture Cleaning agent/ Cleaner <br />· 1.3 Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH & Co. KG <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Detmold, Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />Fax: ++49 (0)5231/953-123 <br />Internet: www.schomburg.de <br />· Informing department: <br />Department: Environment and Safety <br />************************************ <br />If you have any questions about the Environment and Safety Department, please contact our <br />department. <br />e-mail: SDB@schomburg.de <br />· 1.4 Emergency telephone number: <br />Poison centre Berlin (24 hours) <br />German & English <br />Tel: ++49 (0)30/30686700</p> <p>*</p> <p>SECTION 2: Hazards identification <br />· 2.1 Classification of the substance or mixture <br />· Classification according to Regulation (EC) No 1272/2008 <br />GHS05 corrosion <br />Met. Corr.1 H290 May be corrosive to metals. <br />Skin Corr. 1B H314 Causes severe skin burns and eye damage. <br />Eye Dam. 1 H318 Causes serious eye damage. <br />GHS07 <br />Acute Tox. 4 H302 Harmful if swallowed. <br />Acute Tox. 4 H332 Harmful if inhaled. <br />· 2.2 Label elements <br />· Labelling according to Regulation (EC) No 1272/2008 <br />The product is classified and labelled according to the GB CLP regulation. <br />· Hazard pictograms GHS05, GHS07 <br />· Signal word Danger <br />(Contd. on page 2) <br />GB</p> <p>61.0.6</p> <p>Page 2/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 25.07.2025</p> <p>Version number 28</p> <p>Revision: 25.07.2025</p> <p>Trade name: ASO-R005 <br />(Contd. of page 1)</p> <p>· Hazard-determining components of labelling: <br />formic acid <br />· Hazard statements <br />H290 <br />May be corrosive to metals. <br />H302+H332 Harmful if swallowed or if inhaled. <br />H314 <br />Causes severe skin burns and eye damage. <br />· Precautionary statements <br />P260 <br />Do not breathe dusts or mists. <br />P280 <br />Wear protective gloves/protective clothing/eye protection/face protection/hearing <br />protection. <br />P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin <br />with water [or shower]. <br />P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact <br />lenses, if present and easy to do. Continue rinsing. <br />P405 <br />Store locked up. <br />P501 <br />Dispose of contents/container in accordance with local/regional/national/ <br />international regulations. <br />· Additional information: <br />EUH071 Corrosive to the respiratory tract. <br />· 2.3 Other hazards not applicable <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />SECTION 3: Composition/information on ingredients <br />· 3.2 Mixtures <br />· Description: Aqueous solution of an organic acid. <br />· Dangerous components: <br />CAS: 64-18-6 <br />formic acid <br />25-50% <br />EINECS: 200-579-1 <br />Flam. Liq. 3, H226; <br />Acute Tox. 3, H331; <br />Met. Corr.1, <br />Index number: 607-001-00-0 H290; Skin Corr. 1A, H314; Eye Dam. 1, H318; <br />Acute Tox. <br />4, H302, EUH071 <br />ATE: LD50 oral: 500 mg/kg <br />LC50/4 h inhalative: 7.4 mg/l <br />Specific concentration limits: Flam. Liq. 3; H226: C ≥ 85 % <br />Skin Corr. 1A; H314: C ≥ 90 % <br />Skin Corr. 1B; H314: 10 % ≤ C < <br />90 % <br />Skin Irrit. 2; H315: 2 % ≤ C < 10 <br />% <br />Eye Dam. 1; H318: C ≥ 10 % <br />Eye Irrit. 2; H319: 2 % ≤ C < 10 <br />% <br />· Additional information For the wording of the listed hazard phrases refer to section 16. <br />*</p> <p>SECTION 4: First aid measures <br />· 4.1 Description of first aid measures <br />· General information <br />Instantly remove any clothing soiled by the product. <br />Symptoms of poisoning may even occur after several hours; therefore medical observation for at <br />least 48 hours after the accident. <br />Personal protection for the First Aider. <br />It is possible to choke in case of vomiting in unconsciousness. <br />Bring unconscious persons into a stable position on side. <br />Keep the respiratory tract free (remove dentures and vomiting). <br />(Contd. on page 3) <br />GB</p> <p>61.0.6</p> <p>Page 3/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 25.07.2025</p> <p>Version number 28</p> <p>Revision: 25.07.2025</p> <p>Trade name: ASO-R005 <br />(Contd. of page 2)</p> <p>Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage <br />of breathing: artificial respiration. <br />Take up a doctor immediately! <br />· After inhalation Supply fresh air or oxygen; call for doctor. <br />· After skin contact <br />Instantly wash with water and soap and rinse thoroughly. <br />Immediate medical treatment necessary. Failure to treat burns can prevent wounds from healing. <br />Change immediately contaminated clothes. <br />· After eye contact <br />Gently rinse the eyes under running water for at least 10 minutes with the eyelids open. If possible, <br />remove any contact lenses and continue rinsing. Consult a doctor. <br />· After swallowing <br />Show the packaging or the label to the doctor. <br />Drink copious amounts of water. Avert vomiting. Instantly call for doctor. <br />· 4.2 Most important symptoms and effects, both acute and delayed <br />No further relevant information available. <br />· 4.3 Indication of any immediate medical attention and special treatment needed <br />No further relevant information available. <br />*</p> <p>SECTION 5: Firefighting measures <br />· 5.1 Extinguishing media <br />· Suitable extinguishing agents <br />CO2, extinguishing powder or water jet. Fight larger fires with water jet. <br />Use fire fighting measures that suit the environment. <br />· 5.2 Special hazards arising from the substance or mixture <br />Formation of poisonous gases during heating or in fires. <br />· 5.3 Advice for firefighters <br />· Protective equipment: <br />Wear PVC-boots, protective gloves and clothing. <br />Wear self-contained breathing apparatus. <br />· Additional information <br />Collect contaminated fire fighting water separately. It must not enter drains. <br />Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. <br />Follow the emergency-plan. <br />Burst- and explosion-danger by increasing pressure. <br />In case of fire chill the container with water spray.</p> <p>*</p> <p>SECTION 6: Accidental release measures <br />· 6.1 Personal precautions, protective equipment and emergency procedures <br />Bring persons out of danger. <br />Wear protective equipment. Keep unprotected persons away. <br />Wear protective clothing. <br />· 6.2 Environmental precautions: <br />Do not allow product to reach sewage system or water bodies. <br />Inform respective authorities in case product reaches water or sewage system. <br />· 6.3 Methods and material for containment and cleaning up: <br />Use neutralising agent. <br />Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). <br />Ensure adequate ventilation. <br />· 6.4 Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />See Section 13 for information on disposal. <br />GB</p> <p>(Contd. on page 4)</p> <p>61.0.6</p> <p>Page 4/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 25.07.2025</p> <p>Version number 28</p> <p>Revision: 25.07.2025</p> <p>Trade name: ASO-R005 <br />(Contd. of page 3)</p> <p>*</p> <p>SECTION 7: Handling and storage <br />· 7.1 Precautions for safe handling <br />Keep away from heat and direct sunlight. <br />Ensure good ventilation/extraction at the workplace. <br />Prevent formation of aerosols. <br />Keep out of the reach of children <br />· Information about protection against explosions and fires: No special measures required. <br />· 7.2 Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: Store only in the original container. <br />· Information about storage in one common storage facility: <br />Please follow the rules of the VCI-Storage-Concept for chemicals. <br />· Further information about storage conditions: <br />Protect from frost. <br />Keep container tightly sealed. <br />Store in cool, dry conditions in well sealed containers. <br />Store in a locked cabinet and out of the reach of children. <br />· 7.3 Specific end use(s) No further relevant information available.</p> <p>*</p> <p>SECTION 8: Exposure controls/personal protection <br />· 8.1 Control parameters <br />· Components with critical values that require monitoring at the workplace: <br />64-18-6 formic acid (25-50%) <br />WEL Long-term value: 9.6 mg/m³, 5 ppm <br />· Regulatory information WEL: EH40/2020 <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· 8.2 Exposure controls <br />· Appropriate engineering controls <br />It must be possible to wash the skin in the working area. <br />Eye-wash bottle must be available. <br />· Individual protection measures, such as personal protective equipment <br />· General protective and hygienic measures <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />Keep away from foodstuffs, beverages and food. <br />Instantly remove any soiled and impregnated garments. <br />Do not inhale gases / fumes / aerosols. <br />Avoid contact with the eyes and skin. <br />Do not eat, drink or smoke while working. <br />Use skin protection cream for preventive skin protection. <br />Be sure to clean skin thoroughly after work and before breaks. <br />· Breathing equipment: <br />In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer <br />exposure use breathing apparatus that is independent of circulating air. <br />· Hand protection <br />Hand Protection: Nitril-rubber-latex-gloves. <br />Only use chemical-protective gloves with CE-labelling of category III. <br />In case of wearing synthetic protective gloves use cotton-gloves as underwear. <br />The glove material has to be impermeable and resistant to the product/ the substance/ the <br />preparation. <br />Selection of the glove material on consideration of the penetration times, rates of diffusion and the <br />degradation <br />· Material of gloves <br />The selection of the suitable gloves does not only depend on the material, but also on further marks <br />of quality and varies from manufacturer to manufacturer. As the product is a preparation of several <br />substances, the resistance of the glove material can not be calculated in advance and has therefore <br />to be checked prior to the application. <br />(Contd. on page 5) <br />GB</p> <p>61.0.6</p> <p>Page 5/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 25.07.2025</p> <p>Version number 28</p> <p>Revision: 25.07.2025</p> <p>Trade name: ASO-R005 <br />(Contd. of page 4)</p> <p>· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and <br />has to be observed. <br />· Not suitable are gloves made of the following materials: <br />Leather gloves. <br />Gloves made of thick fabric. <br />· Eye/face protection <br />Suitable safety goggles in accordance with DIN EN 166. <br />In case of splashing use protecting basket-glasses. <br />· Body protection: <br />Acid resistant protective clothing <br />Apron <br />Protective work clothing. <br />*</p> <p>SECTION 9: Physical and chemical properties <br />· 9.1 Information on basic physical and chemical properties <br />· General Information <br />· Physical state <br />Liquid <br />· Colour: <br />Colourless <br />· Smell: <br />Pungent <br />· Odour threshold: <br />Not determined. <br />· Melting point/freezing point: <br />-13 °C <br />· Boiling point or initial boiling point and <br />boiling range <br />>100 °C (64-18-6 formic acid) <br />· Flammability <br />Not applicable. <br />· Lower and upper explosion limit <br />· Lower: <br />14.9 Vol % (64-18-6 formic acid) <br />· Upper: <br />47.6 Vol % (64-18-6 formic acid) <br />· Flash point: <br />62 °C (64-18-6 formic acid) <br />· Auto-ignition temperature: <br />>500 °C (64-18-6 formic acid) <br />· Decomposition temperature: <br />Not determined. <br />· pH at 20 °C <br />2.2 <br />· Viscosity: <br />· Kinematic viscosity <br />Not determined. <br />· dynamic at 20 °C: <br />1.6 mPas <br />· Solubility <br />· Water: <br />miscible <br />· Partition coefficient n-octanol/water (log <br />value) <br />Not determined. <br />· Steam pressure at 20 °C: <br />21 hPa (64-18-6 formic acid) <br />· Density and/or relative density <br />· Density at 20 °C <br />1.2 g/cm³ <br />· Relative density <br />1.6 <br />· Vapour density <br />Not determined. <br />· 9.2 Other information <br />· Appearance: <br />· Form: <br />Fluid <br />· Important information on protection of health <br />and environment, and on safety. <br />· Self-inflammability: <br />Product is not selfigniting. <br />· Explosive properties: <br />Product is not explosive. <br />· Solvent separation test <br />· Solids content: <br />>20-60 % <br />(Contd. on page 6) <br />GB</p> <p>61.0.6</p> <p>Page 6/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 25.07.2025</p> <p>Version number 28</p> <p>Revision: 25.07.2025</p> <p>Trade name: ASO-R005 <br />(Contd. of page 5)</p> <p>· Change in condition <br />· Evaporation rate <br />· Information with regard to physical hazard <br />classes <br />· Explosives <br />· Flammable gases <br />· Aerosols <br />· Oxidising gases <br />· Gases under pressure <br />· Flammable liquids <br />· Flammable solids <br />· Self-reactive substances and mixtures <br />· Pyrophoric liquids <br />· Pyrophoric solids <br />· Self-heating substances and mixtures <br />· Substances and mixtures, which emit <br />flammable gases in contact with water <br />· Oxidising liquids <br />· Oxidising solids <br />· Organic peroxides <br />· Corrosive to metals <br />· Desensitised explosives</p> <p>Not determined.</p> <p>Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />May be corrosive to metals. <br />Void</p> <p>SECTION 10: Stability and reactivity <br />· 10.1 Reactivity No further relevant information available. <br />· 10.2 Chemical stability <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· 10.3 Possibility of hazardous reactions No dangerous reactions known <br />· 10.4 Conditions to avoid No further relevant information available. <br />· 10.5 Incompatible materials: No further relevant information available. <br />· 10.6 Hazardous decomposition products: No dangerous decomposition products known <br />*</p> <p>SECTION 11: Toxicological information <br />· 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 <br />· Acute toxicity Harmful if swallowed or if inhaled. <br />· LD/LC50 values that are relevant for classification: <br />64-18-6 formic acid <br />Oral <br />LD50 <br />500 mg/kg (ATE) <br />730 mg/kg (rats) (OECD 401) <br />Inhalative LC50/4 h 7.4 mg/l (ATE) <br />7.85 mg/l (rats) (OECD 403) <br />· Primary irritant effect: <br />· Skin corrosion/irritation Causes severe skin burns and eye damage. <br />· Serious eye damage/irritation Causes serious eye damage. <br />· 11.2 Information on other hazards <br />· Endocrine disrupting properties <br />None of the ingredients is listed. <br />GB</p> <p>(Contd. on page 7)</p> <p>61.0.6</p> <p>Page 7/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 25.07.2025</p> <p>Version number 28</p> <p>Revision: 25.07.2025</p> <p>Trade name: ASO-R005 <br />(Contd. of page 6)</p> <p>*</p> <p>SECTION 12: Ecological information <br />· 12.1 Toxicity <br />· Aquatic toxicity: <br />64-18-6 formic acid <br />LC50/96h <br />1,720 mg/l (fish toxicity) <br />EC/LC50 (48h) 365 mg/l (Daphnia magna) (OECD 202) <br />EC/LC50 (17h) 46.7 mg/l (bacterial toxicity) <br />ERC50 <br />1,240 mg/l /72h (Pseudokirchneriella subcapitata) <br />LOEC <br />≥100 mg/l /21d (Daphnia magna) (OECD 211) <br />NOEC <br />≥100 mg/l /21d (Daphnia magna) (OECD 211) <br />· 12.2 Persistence and degradability No further relevant information available. <br />· 12.3 Bioaccumulative potential No further relevant information available. <br />· 12.4 Mobility in soil No further relevant information available. <br />· 12.5 Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />· 12.6 Endocrine disrupting properties <br />The product does not contain substances with endocrine disrupting properties. <br />· 12.7 Other adverse effects <br />· Additional ecological information: <br />· General notes: <br />Water hazard class 1 (Self-assessment): slightly hazardous for water. <br />Do not allow undiluted product or large quantities of it to reach ground water, water bodies or <br />sewage system. <br />Must not reach sewage water or drainage ditch undiluted or unneutralised. <br />SECTION 13: Disposal considerations <br />· 13.1 Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />· Uncleaned packagings: <br />· Recommendation: Disposal must be made according to official regulations. <br />· Recommended cleaning agent: Water, if necessary with cleaning agent. <br />SECTION 14: Transport information <br />· 14.1 UN number or ID number <br />· ADR, IMDG, IATA</p> <p>UN3412</p> <p>· 14.2 UN proper shipping name <br />· ADR <br />· IMDG, IATA</p> <p>3412 FORMIC ACID <br />FORMIC ACID</p> <p>· 14.3 Transport hazard class(es) <br />· ADR, IMDG, IATA</p> <p>· Class</p> <p>8 Corrosive substances. <br />(Contd. on page 8) <br />GB</p> <p>61.0.6</p> <p>Page 8/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 25.07.2025</p> <p>Version number 28</p> <p>Revision: 25.07.2025</p> <p>Trade name: ASO-R005 <br />(Contd. of page 7)</p> <p>· Label</p> <p>8</p> <p>· 14.4 Packing group <br />· ADR, IMDG, IATA</p> <p>II</p> <p>· 14.5 Environmental hazards:</p> <p>Not applicable.</p> <p>· 14.6 Special precautions for user <br />· Kemler Number: <br />· EMS Number: <br />· Segregation groups <br />· Stowage Category <br />· Stowage Code</p> <p>Warning: Corrosive substances. <br />80 <br />F-A,S-B <br />(SGG1) Acids <br />A <br />SW2 Clear of living quarters.</p> <p>· 14.7 Maritime transport in bulk according to <br />IMO instruments <br />Not applicable. <br />· Transport/Additional information: <br />· ADR <br />· Limited quantities (LQ) <br />· Excepted quantities (EQ) <br />· Transport category <br />· IMDG <br />· Limited quantities (LQ) <br />· Excepted quantities (EQ)</p> <p>· UN "Model Regulation":</p> <p>*</p> <p>1L <br />Code: E2 <br />Maximum net quantity per inner packaging: 30 ml <br />Maximum net quantity per outer packaging: 500 ml <br />2 <br />1L <br />Code: E2 <br />Maximum net quantity per inner packaging: 30 ml <br />Maximum net quantity per outer packaging: 500 ml <br />UN 3412 FORMIC ACID, 8, II</p> <p>SECTION 15: Regulatory information <br />· 15.1 Safety, health and environmental regulations/legislation specific for the substance or <br />mixture <br />· Poisons Act <br />· Regulated explosives precursors <br />None of the ingredients is listed. <br />· Regulated poisons <br />None of the ingredients is listed. <br />· Reportable explosives precursors <br />None of the ingredients is listed. <br />· Reportable poisons <br />64-18-6 formic acid: 25% <br />· Directive 2012/18/EU <br />· Named dangerous substances - ANNEX I None of the ingredients is listed. <br />· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.</p> <p>*</p> <p>SECTION 16: Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for <br />any specific product features and shall not establish a legally valid contractual relationship. <br />· Reasons for alterations None <br />· Relevant phrases <br />H226 <br />Flammable liquid and vapour. <br />(Contd. on page 9) <br />GB</p> <p>61.0.6</p> <p>Page 9/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 25.07.2025</p> <p>Version number 28</p> <p>Revision: 25.07.2025</p> <p>Trade name: ASO-R005 <br />(Contd. of page 8)</p> <p>H290 <br />May be corrosive to metals. <br />H302 <br />Harmful if swallowed. <br />H314 <br />Causes severe skin burns and eye damage. <br />H315 <br />Causes skin irritation. <br />H318 <br />Causes serious eye damage. <br />H319 <br />Causes serious eye irritation. <br />H331 <br />Toxic if inhaled. <br />EUH071 Corrosive to the respiratory tract. <br />· Department issuing data specification sheet: Environment protection department. <br />· Abbreviations and acronyms: <br />ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning <br />the International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />GHS: Globally Harmonised System of Classification and Labelling of Chemicals <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />PBT: Persistent, Bioaccumulative and Toxic <br />vPvB: very Persistent and very Bioaccumulative <br />ATE: Acute toxicity estimate values <br />Flam. Liq. 3: Flammable liquids – Category 3 <br />Met. Corr.1: Corrosive to metals – Category 1 <br />Acute Tox. 4: Acute toxicity – Category 4 <br />Acute Tox. 3: Acute toxicity – Category 3 <br />Skin Corr. 1A: Skin corrosion/irritation – Category 1A <br />Skin Corr. 1B: Skin corrosion/irritation – Category 1B <br />Eye Dam. 1: Serious eye damage/eye irritation – Category 1</p> <p>· * Data compared to the previous version altered. <br />GB</p>
