SDS_ESCOSIL-2000-ST_-_205592001_(20)EN.pdf
7 页数
189.5 KB
Download
<h1>SDS_ESCOSIL-2000-ST_-_205592001_(20)EN.pdf</h1> <p>53.1.0</p> <p>Page 1/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 05.07.2021 <br />*</p> <p>Version number 20</p> <p>Revision: 05.07.2021</p> <p>SECTION 1: Identification of the substance/mixture and of the company/undertaking <br />· 1.1 Product identifier <br />· Trade name: ESCOSIL-2000-ST <br />· 1.2 Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture Spacings sealent <br />· 1.3 Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH & Co. KG <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />email: info@schomburg.de <br />web: www.schomburg.de <br />· Informing department: <br />Product Safety Department <br />Tel: ++49 (0)5231/953-770 <br />email: SDB@schomburg.de</p> <p>*</p> <p>SECTION 2: Hazards identification <br />· 2.1 Classification of the substance or mixture <br />· Classification according to Regulation (EC) No 1272/2008 <br />The product is not classified, according to the CLP regulation. <br />· Additional information: Avoid skin contact. <br />· 2.2 Label elements <br />· Labelling according to Regulation (EC) No 1272/2008 Void <br />· Hazard pictograms Void <br />· Signal word Void <br />· Hazard statements Void <br />· Additional information: <br />EUH208 Contains 2-octyl-2H-isothiazol-3-one, 3-aminopropyltriethoxysilane. May produce an <br />allergic reaction. <br />EUH210 Safety data sheet available on request. <br />EUH211 Warning! Hazardous respirable droplets may be formed when sprayed. Do not breathe <br />spray or mist. <br />· 2.3 Other hazards <br />During the processing and hardening of the material, chemical substances are released into the air <br />(see point 11). Therefore ensure good room ventilation and, if necessary, suction. <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable.</p> <p>*</p> <p>SECTION 3: Composition/information on ingredients <br />· 3.2 Chemical characterisation: Mixtures <br />· Description: Preparation based on Polydimethylsiloxan, filler, additives and Oximosilan-interlinks. <br />(Contd. on page 2) <br />GB</p> <p>53.1.0</p> <p>Page 2/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 05.07.2021</p> <p>Version number 20</p> <p>Revision: 05.07.2021</p> <p>Trade name: ESCOSIL-2000-ST <br />(Contd. of page 1)</p> <p>· Dangerous components: <br />CAS: 1170315-90-8 <br />EC number: 700-833-6 <br />CAS: 37859-55-5 <br />ELINCS: 484-460-1</p> <p>2-Pentanone, 2,2',2''-[O,O',O''-(phenylsilylidyne)trioxime] <br />Acute Tox. 4, H302; Eye Irrit. 2, H319</p> <p>2.5-10%</p> <p>O, O', O''-(methylsilylidyne)trioxime 2-pentanone <br />STOT RE 2, H373; <br />Acute Tox. 4, H302; Eye Irrit. 2, <br />H319</p> <p><2.5%</p> <p>CAS: 13463-67-7 <br />titanium dioxide <br />EINECS: 236-675-5 <br />Carc. 2, H351 <br />Index number: 022-006-00-2 <br />· Additional information For the wording of the listed hazard phrases refer to section 16. <br />*</p> <p><2.5%</p> <p>SECTION 4: First aid measures <br />· 4.1 Description of first aid measures <br />· General information Personal protection for the First Aider. <br />· After inhalation <br />Keep the person at fresh air. <br />Seek medical treatment in case of complaints. <br />· After skin contact <br />After contact, clean the skin mechanical and rinse with water and soap. <br />If skin irritation continues, consult a doctor. <br />· After eye contact Rinse opened eye for several minutes under running water. <br />· After swallowing <br />Don't cause vomiting <br />Call a doctor immediately. <br />Show the pack or the label to the doctor. <br />· 4.2 Most important symptoms and effects, both acute and delayed <br />No further relevant information available. <br />· 4.3 Indication of any immediate medical attention and special treatment needed <br />No further relevant information available.</p> <p>*</p> <p>SECTION 5: Firefighting measures <br />· 5.1 Extinguishing media <br />· Suitable extinguishing agents <br />CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. <br />· For safety reasons unsuitable extinguishing agents None known <br />· 5.2 Special hazards arising from the substance or mixture <br />Formation of toxic gases is possible during heating or in case of fire. <br />· 5.3 Advice for firefighters <br />· Protective equipment: <br />Wear self-contained breathing apparatus. <br />Do not inhale explosion gases or combustion gases. <br />· Additional information Follow the emergency-plan.</p> <p>*</p> <p>SECTION 6: Accidental release measures <br />· 6.1 Personal precautions, protective equipment and emergency procedures <br />Ensure adequate ventilation <br />· 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. <br />· 6.3 Methods and material for containment and cleaning up: Collect mechanically. <br />· 6.4 Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />(Contd. on page 3) <br />GB</p> <p>53.1.0</p> <p>Page 3/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 05.07.2021</p> <p>Version number 20</p> <p>Revision: 05.07.2021</p> <p>Trade name: ESCOSIL-2000-ST <br />(Contd. of page 2)</p> <p>See Section 13 for information on disposal. <br />*</p> <p>SECTION 7: Handling and storage <br />· 7.1 Precautions for safe handling <br />Work with fresh air supply, keep doors and windows open. <br />Keep away from children. <br />· Information about protection against explosions and fires: No special measures required. <br />· 7.2 Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: <br />Containers must be stored thick closed at a cool, ventilated place. <br />· Information about storage in one common storage facility: <br />Store away from foodstuffs. <br />Please follow the rules of the VCI-Storage-Concept for chemicals. <br />· Further information about storage conditions: <br />Protect from frost. <br />Protect from heat and direct sunlight. <br />· 7.3 Specific end use(s) No further relevant information available.</p> <p>*</p> <p>SECTION 8: Exposure controls/personal protection <br />· 8.1 Control parameters <br />· Additional information about design of technical systems: <br />It must be possible to wash the skin in the working area. <br />Eye-wash bottle must be available. <br />· Components with critical values that require monitoring at the workplace: <br />The product does not contain any relevant quantities of materials with critical values that have to be <br />monitored at the workplace. <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· 8.2 Exposure controls <br />· Personal protective equipment <br />· General protective and hygienic measures <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />Avoid contact with eyes and skin. Change clothes which heavy contaminate with the product. <br />Be sure to clean skin thoroughly after work and before breaks. <br />When the material is hardened on the skin, remove it carfully mechanically. <br />· Breathing equipment: <br />Use breathing protection in case of insufficient ventilation. <br />Protective mask with appropriate gas filter (type ABEK according to EN 14387). <br />· Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. <br />· Material of gloves <br />Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Penetration time 480 min <br />The selection of the suitable gloves does not only depend on the material, but also on further marks <br />of quality and varies from manufacturer to manufacturer. As the product is a preparation of several <br />substances, the resistance of the glove material can not be calculated in advance and has therefore <br />to be checked prior to the application. <br />· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and <br />has to be observed. <br />· Eye protection: Safety glasses <br />· Body protection: Protective work clothing. <br />GB</p> <p>(Contd. on page 4)</p> <p>53.1.0</p> <p>Page 4/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 05.07.2021</p> <p>Version number 20</p> <p>Revision: 05.07.2021</p> <p>Trade name: ESCOSIL-2000-ST <br />(Contd. of page 3)</p> <p>*</p> <p>SECTION 9: Physical and chemical properties <br />· 9.1 Information on basic physical and chemical properties <br />· General Information <br />· Appearance: <br />Form: <br />Pasty <br />Colour: <br />According to product specification <br />· Smell: <br />Characteristic <br />· Odour threshold: <br />Not determined. <br />· pH-value:</p> <p>Not determined.</p> <p>· Change in condition <br />Melting point/freezing point: <br />Not determined <br />Initial boiling point and boiling range: Not determined</p> <p>*</p> <p>· Flash point:</p> <p>Not applicable</p> <p>· Inflammability (solid, gaseous)</p> <p>Not applicable.</p> <p>· Decomposition temperature:</p> <p>Not determined.</p> <p>· Self-inflammability:</p> <p>Product is not selfigniting.</p> <p>· Explosive properties:</p> <p>Product is not explosive.</p> <p>· Critical values for explosion: <br />Lower: <br />Upper:</p> <p>Not determined. <br />Not determined.</p> <p>· Steam pressure:</p> <p>Not determined.</p> <p>· Density at 20 °C <br />· Relative density <br />· Vapour density <br />· Evaporation rate</p> <p>1 g/cm³ <br />Not determined. <br />Not determined. <br />Not determined.</p> <p>· Solubility in / Miscibility with <br />Water:</p> <p>Not miscible or difficult to mix</p> <p>· Partition coefficient: n-octanol/water:</p> <p>Not determined.</p> <p>· Viscosity: <br />dynamic: <br />kinematic:</p> <p>Not determined. <br />Not determined.</p> <p>· 9.2 Other information</p> <p>No further relevant information available.</p> <p>SECTION 10: Stability and reactivity <br />· 10.1 Reactivity No further relevant information available. <br />· 10.2 Chemical stability <br />· Thermal decomposition / conditions to be avoided: Avoid excessive heat. <br />· 10.3 Possibility of hazardous reactions No dangerous reactions known <br />· 10.4 Conditions to avoid No further relevant information available. <br />· 10.5 Incompatible materials: No further relevant information available. <br />· 10.6 Hazardous decomposition products: <br />By heating about 150°C in present of air, could be realase small amounts of formaldehyde.</p> <p>*</p> <p>SECTION 11: Toxicological information <br />· 11.1 Information on toxicological effects <br />· Acute toxicity Based on available data, the classification criteria are not met. <br />(Contd. on page 5) <br />GB</p> <p>53.1.0</p> <p>Page 5/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 05.07.2021</p> <p>Version number 20</p> <p>Revision: 05.07.2021</p> <p>Trade name: ESCOSIL-2000-ST <br />(Contd. of page 4)</p> <p>· LD/LC50 values that are relevant for classification: <br />1170315-90-8 2-Pentanone, 2,2',2''-[O,O',O''-(phenylsilylidyne)trioxime] <br />Oral <br />LD50 <br />1,514 mg/kg (rats) <br />37859-55-5 O, O', O''-(methylsilylidyne)trioxime 2-pentanone <br />Oral <br />LD50 <br />1,234 mg/kg (rats) (OECD 425) <br />Dermal LD50 <br />>2,000 mg/kg (rats) <br />13463-67-7 titanium dioxide <br />Oral <br />LD50 <br />>5,000 mg/kg (rats) <br />Dermal LD50 <br />>10,000 mg/kg (rbt) <br />Inhalative LC50/4 h 6.8 mg/l (rats) <br />919-30-2 3-aminopropyltriethoxysilane <br />Oral <br />LD50 <br />1,490 mg/kg (rats) (EPA Method) <br />Dermal LD50 <br />>2,000 mg/kg (Kan) (EPA Method) <br />Inhalative LC50 <br />>144 mg/l /(6h) (rats) <br />· Specific symptoms in biological assay: <br />919-30-2 3-aminopropyltriethoxysilane <br />NOAEL 200 mg/kg (rats) (OECD TG 408) <br />· Primary irritant effect: No irritant action known. <br />· Skin corrosion/irritation It is possible to irritate the skin. <br />· Serious eye damage/irritation Based on available data, the classification criteria are not met. <br />· Respiratory or skin sensitisation <br />After longer exposition sensitization by skin contact or breath in is possible. <br />· Other information (about experimental toxicology): <br />2-Pentanonoxim During the application and subsequent curing of the product (CAS 623-40-5), which <br />evaporates. 2-Pentanonoxim causes serious eye irritation. If 2-Pentanonoxim inhaled in high <br />concentrations (for example, when there is inadequate ventilation) over long periods, it may cause <br />irreversible damage to health. <br />· Additional toxicological information: <br />· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) <br />· Germ cell mutagenicity Based on available data, the classification criteria are not met. <br />· Carcinogenicity Based on available data, the classification criteria are not met. <br />· Reproductive toxicity Based on available data, the classification criteria are not met. <br />· STOT-single exposure Based on available data, the classification criteria are not met. <br />· STOT-repeated exposure Based on available data, the classification criteria are not met. <br />· Aspiration hazard Based on available data, the classification criteria are not met. <br />*</p> <p>SECTION 12: Ecological information <br />· 12.1 Toxicity <br />· Aquatic toxicity: <br />37859-55-5 O, O', O''-(methylsilylidyne)trioxime 2-pentanone <br />EC 50 <br />>113 mg/kg /48h (Daphnia magna) (OECD 202) <br />100 mg/kg /72h (Pseudokirchneriella subcapitata) (OECD 201) <br />LC50/96h <br />>113 mg/l (rainbow trout) (OECD 203) <br />NOEC <br />≥113 mg/l /48h (Daphnia magna) <br />36 mg/l /72h (Pseudokirchneriella subcapitata) <br />113 mg/l /96h (rainbow trout) <br />13463-67-7 titanium dioxide <br />LC 0 <br />48 mg/l (Leuciscus idus) <br />EC0 <br />30 mg/l (Daphnia magna) <br />(Contd. on page 6) <br />GB</p> <p>53.1.0</p> <p>Page 6/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 05.07.2021</p> <p>Version number 20</p> <p>Revision: 05.07.2021</p> <p>Trade name: ESCOSIL-2000-ST <br />(Contd. of page 5)</p> <p>24 mg/l (Pseudomonas flourescens) <br />919-30-2 3-aminopropyltriethoxysilane <br />LC 0 <br />>934 mg/l /(96h) (Brachydanio rerio) (OECD TG 203) <br />EC10 <br />13 mg/l /(5.75h) (Pseudomas putida) (Bringmann & Kühn, 10, 87-98 (1977)) <br />EC50 (48h) <br />331 mg/l (Daphnia magna) (OECD TG 202) <br />EC/LC50 (72h) >1,000 mg/l (Desmodesmus subspicatus) (OECD TG 201) <br />· 12.2 Persistence and degradability No further relevant information available. <br />· 12.3 Bioaccumulative potential No further relevant information available. <br />· 12.4 Mobility in soil No further relevant information available. <br />· Additional ecological information: <br />· General notes: <br />Water hazard class 1 (Self-assessment): slightly hazardous for water. <br />Do not allow undiluted product or large quantities of it to reach ground water, water bodies or <br />sewage system. <br />· 12.5 Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />· 12.6 Other adverse effects No further relevant information available. <br />*</p> <p>SECTION 13: Disposal considerations <br />· 13.1 Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />· Uncleaned packagings: <br />· Recommendation: <br />Non contaminated packagings can be treated like household garbage. <br />Packagings that cannot be cleaned are to be disposed of in the same manner as the product. <br />SECTION 14: Transport information <br />· 14.1 UN-Number <br />· ADR, IMDG, IATA</p> <p>Void</p> <p>· 14.2 UN proper shipping name <br />· ADR, IMDG, IATA</p> <p>Void</p> <p>· 14.3 Transport hazard class(es) <br />· ADR, ADN, IMDG, IATA <br />· Class</p> <p>Void</p> <p>· 14.4 Packing group <br />· ADR, IMDG, IATA</p> <p>Void</p> <p>· 14.5 Environmental hazards: <br />· Marine pollutant:</p> <p>No</p> <p>· 14.6 Special precautions for user</p> <p>Not applicable.</p> <p>· 14.7 Transport in bulk according to Annex II <br />of Marpol and the IBC Code <br />Not applicable. <br />· UN "Model Regulation":</p> <p>Void <br />GB</p> <p>(Contd. on page 7)</p> <p>53.1.0</p> <p>Page 7/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 05.07.2021</p> <p>Version number 20</p> <p>Revision: 05.07.2021</p> <p>Trade name: ESCOSIL-2000-ST <br />(Contd. of page 6)</p> <p>*</p> <p>SECTION 15: Regulatory information <br />· 15.1 Safety, health and environmental regulations/legislation specific for the substance or <br />mixture <br />· Directive 2012/18/EU <br />· Named dangerous substances - ANNEX I None of the ingredients is listed. <br />· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.</p> <p>*</p> <p>SECTION 16: Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for <br />any specific product features and shall not establish a legally valid contractual relationship. <br />· Relevant phrases <br />H302 Harmful if swallowed. <br />H319 Causes serious eye irritation. <br />H351 Suspected of causing cancer. <br />H373 May cause damage to organs through prolonged or repeated exposure. <br />· Department issuing data specification sheet: Environment protection department. <br />· Contact: Environment protection department. <br />· Abbreviations and acronyms: <br />ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning <br />the International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />GHS: Globally Harmonised System of Classification and Labelling of Chemicals <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />PBT: Persistent, Bioaccumulative and Toxic <br />vPvB: very Persistent and very Bioaccumulative <br />Acute Tox. 4: Acute toxicity – Category 4 <br />Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 <br />Carc. 2: Carcinogenicity – Category 2 <br />STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2</p> <p>· * Data compared to the previous version altered. <br />GB</p>
