ESCO-FLUAT_-_204146_(20)EN.pdf
8 页数
857.3 KB
Download
<h1>ESCO-FLUAT_-_204146_(20)EN.pdf</h1> <p>50.0.4</p> <p>Page 1/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 27.04.2020 <br />*</p> <p>Version number 20</p> <p>Revision: 27.04.2020</p> <p>SECTION 1: Identification of the substance/mixture and of the company/undertaking <br />· 1.1 Product identifier <br />· Trade name: ESCO-FLUAT <br />· 1.2 Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture salt treatment (neutralization agent) <br />· 1.3 Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH & Co. KG <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />Fax: ++49 (0)5231/953-123 <br />email: info@schomburg.de <br />web: www.schomburg.de <br />· Informing department: <br />Product Safety Department <br />Tel: ++49 (0)5231/953-193 <br />Fax: ++49 (0)5231/953-106 <br />email: SDB@schomburg.de</p> <p>*</p> <p>SECTION 2: Hazards identification <br />· 2.1 Classification of the substance or mixture <br />· Classification according to Regulation (EC) No 1272/2008 <br />GHS05 corrosion <br />Skin Corr. 1A <br />Eye Dam. 1</p> <p>H314 Causes severe skin burns and eye damage. <br />H318 Causes serious eye damage.</p> <p>GHS09 environment <br />Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. <br />GHS07 <br />Acute Tox. 4 <br />Acute Tox. 4 <br />Acute Tox. 4</p> <p>H302 Harmful if swallowed. <br />H312 Harmful in contact with skin. <br />H332 Harmful if inhaled.</p> <p>· 2.2 Label elements <br />· Labelling according to Regulation (EC) No 1272/2008 <br />The product is classified and labelled according to the CLP regulation. <br />· Hazard pictograms GHS05, GHS07, GHS09 <br />· Signal word Danger</p> <p>(Contd. on page 2) <br />GB</p> <p>50.0.4</p> <p>Page 2/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 27.04.2020</p> <p>Version number 20</p> <p>Revision: 27.04.2020</p> <p>Trade name: ESCO-FLUAT <br />(Contd. of page 1)</p> <p>· Hazard-determining components of labelling: <br />zinc hexafluorosilicate <br />· Hazard statements <br />H302+H312+H332 Harmful if swallowed, in contact with skin or if inhaled. <br />H314 <br />Causes severe skin burns and eye damage. <br />H411 <br />Toxic to aquatic life with long lasting effects. <br />· Precautionary statements <br />P260 <br />Do not breathe dusts or mists. <br />P280 <br />Wear protective gloves/protective clothing/eye protection/face protection/hearing <br />protection. <br />P301+P312 <br />IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. <br />P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with <br />water [or shower]. <br />P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, <br />if present and easy to do. Continue rinsing. <br />P501 <br />Dispose of contents/container in accordance with local/regional/national/international <br />regulations. <br />· 2.3 Other hazards <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />*</p> <p>SECTION 3: Composition/information on ingredients <br />· 3.2 Chemical characterisation: Mixtures <br />· Description: aqueous hexafluorosilicate solution <br />· Dangerous components: <br />CAS: 16871-71-9 zinc hexafluorosilicate <br />EINECS: 240-894-1 <br />Acute Tox. 3, H301; Acute Tox. 3, H311; Acute Tox. 3, H331; <br />Skin <br />Corr. 1A, H314; Eye Dam. 1, H318; <br />Aquatic Acute 1, H400; Aquatic <br />Chronic 1, H410</p> <p>10-25%</p> <p>SECTION 4: First aid measures <br />· 4.1 Description of first aid measures <br />· General information <br />Personal protection for the First Aider. <br />Symptoms of poisoning may even occur after several hours; therefore medical observation for at least <br />48 hours after the accident. <br />Instantly remove any clothing soiled by the product. <br />It is possible to choke in case of vomiting in unconsciousness. <br />Bring unconscious persons into a stable position on side. <br />Keep the respiratory tract free (remove dentures and vomiting). <br />Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of <br />breathing: artificial respiration. <br />Take up a doctor immediately! <br />· After inhalation Supply fresh air or oxygen; call for doctor. <br />· After skin contact <br />Change immediately contaminated clothes. <br />Instantly wash with water and soap and rinse thoroughly. <br />· After eye contact Rinse opened eye for several minutes under running water. <br />· After swallowing Do not induce vomiting; instantly call for medical help.</p> <p>(Contd. on page 3) <br />GB</p> <p>50.0.4</p> <p>Page 3/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 27.04.2020</p> <p>Version number 20</p> <p>Revision: 27.04.2020</p> <p>Trade name: ESCO-FLUAT</p> <p>· 4.2 Most important symptoms and effects, both acute and delayed <br />No further relevant information available. <br />· 4.3 Indication of any immediate medical attention and special treatment needed <br />No further relevant information available.</p> <p>(Contd. of page 2)</p> <p>SECTION 5: Firefighting measures <br />· 5.1 Extinguishing media <br />· Suitable extinguishing agents <br />Product is not inflammable. <br />Use fire fighting measures that suit the environment. <br />· 5.2 Special hazards arising from the substance or mixture No further relevant information available. <br />· 5.3 Advice for firefighters <br />· Protective equipment: <br />Wear self-contained breathing apparatus. <br />Wear full protective suit. <br />· Additional information <br />Cool endangered containers with water spray jet. <br />Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. <br />SECTION 6: Accidental release measures <br />· 6.1 Personal precautions, protective equipment and emergency procedures <br />Wear protective equipment. Keep unprotected persons away. <br />Ensure adequate ventilation <br />· 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. <br />· 6.3 Methods and material for containment and cleaning up: <br />Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). <br />· 6.4 Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />*</p> <p>SECTION 7: Handling and storage <br />· 7.1 Precautions for safe handling <br />Ensure good ventilation/exhaustion at the workplace. <br />Open and handle container with care. <br />· Information about protection against explosions and fires: Protect from heat. <br />· 7.2 Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: Provide floor trough without outlet. <br />· Information about storage in one common storage facility: <br />Store away from foodstuffs. <br />Please follow the rules of the VCI-Storage-Concept for chemicals. <br />· Further information about storage conditions: Protect from frost. <br />· 7.3 Specific end use(s) No further relevant information available.</p> <p>*</p> <p>SECTION 8: Exposure controls/personal protection <br />· Additional information about design of technical systems: No further data; see item 7 MSDS.</p> <p>(Contd. on page 4) <br />GB</p> <p>50.0.4</p> <p>Page 4/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 27.04.2020</p> <p>Version number 20</p> <p>Revision: 27.04.2020</p> <p>Trade name: ESCO-FLUAT <br />(Contd. of page 3)</p> <p>· 8.1 Control parameters <br />· Components with critical values that require monitoring at the workplace: <br />The product does not contain any relevant quantities of materials with critical values that have to be <br />monitored at the workplace. <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· 8.2 Exposure controls <br />· Personal protective equipment <br />· General protective and hygienic measures <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />Wash hands during breaks and at the end of the work. <br />Avoid contact with the eyes and skin. <br />Ensure that washing facilities are available in the work place. <br />· Breathing equipment: <br />Self-contained breathing apparatus must be used in case of bad fresh-air-supply or no adequate <br />removal suction is available. <br />· Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. <br />· Material of gloves <br />Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Break through time 480 min <br />· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and has to <br />be observed. <br />· Eye protection: Tightly sealed safety glasses. <br />· Body protection: Acid resistant protective clothing <br />SECTION 9: Physical and chemical properties <br />· 9.1 Information on basic physical and chemical properties <br />· General Information <br />· Appearance: <br />Form: <br />Fluid <br />Colour: <br />Clear <br />· Smell: <br />Odourless <br />· pH-value at 20 °C:</p> <p><1</p> <p>· Change in condition <br />Melting point/freezing point: <br />Not determined <br />Initial boiling point and boiling range: Not determined <br />· Flash point:</p> <p>Not applicable</p> <p>· Self-inflammability:</p> <p>Product is not selfigniting.</p> <p>· Explosive properties:</p> <p>Product is not explosive.</p> <p>· Steam pressure:</p> <p>Not determined.</p> <p>· Density at 20 °C</p> <p>1.18 g/cm³</p> <p>· Solubility in / Miscibility with <br />Water:</p> <p>Fully miscible</p> <p>· Viscosity: <br />dynamic: <br />kinematic:</p> <p>Not determined. <br />Not determined. <br />(Contd. on page 5) <br />GB</p> <p>50.0.4</p> <p>Page 5/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 27.04.2020</p> <p>Version number 20</p> <p>Revision: 27.04.2020</p> <p>Trade name: ESCO-FLUAT <br />(Contd. of page 4)</p> <p>· 9.2 Other information</p> <p>No further relevant information available.</p> <p>SECTION 10: Stability and reactivity <br />· 10.1 Reactivity No further relevant information available. <br />· 10.2 Chemical stability <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· 10.3 Possibility of hazardous reactions No dangerous reactions known <br />· 10.4 Conditions to avoid No further relevant information available. <br />· 10.5 Incompatible materials: No further relevant information available. <br />· 10.6 Hazardous decomposition products: No dangerous decomposition products known <br />*</p> <p>SECTION 11: Toxicological information <br />· 11.1 Information on toxicological effects <br />· Acute toxicity <br />Harmful if swallowed, in contact with skin or if inhaled. <br />· LD/LC50 values that are relevant for classification: <br />16871-71-9 zinc hexafluorosilicate <br />Oral <br />LD50 <br />100 mg/kg (Akute Toxizität) (Aligned to GHS category) <br />Dermal LD50 <br />300 mg/kg (Akute Toxizität) (Aligned to GHS category) <br />Inhalative LC50/4 h 3 mg/l (Akute Toxizität) (Aligned to GHS category) <br />· Primary irritant effect: <br />· Skin corrosion/irritation <br />Causes severe skin burns and eye damage. <br />· Serious eye damage/irritation <br />Causes serious eye damage. <br />· Respiratory or skin sensitisation Based on available data, the classification criteria are not met. <br />· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) <br />· Germ cell mutagenicity Based on available data, the classification criteria are not met. <br />· Carcinogenicity Based on available data, the classification criteria are not met. <br />· Reproductive toxicity Based on available data, the classification criteria are not met. <br />· STOT-single exposure Based on available data, the classification criteria are not met. <br />· STOT-repeated exposure Based on available data, the classification criteria are not met. <br />· Aspiration hazard Based on available data, the classification criteria are not met. <br />SECTION 12: Ecological information <br />· 12.1 Toxicity <br />· Aquatic toxicity: No further relevant information available. <br />· 12.2 Persistence and degradability No further relevant information available. <br />· 12.3 Bioaccumulative potential No further relevant information available. <br />· 12.4 Mobility in soil No further relevant information available. <br />· Additional ecological information: <br />· General notes: <br />Water hazard class 2 (Self-assessment): hazardous for water. <br />Do not allow product to reach ground water, water bodies or sewage system. <br />· 12.5 Results of PBT and vPvB assessment <br />· PBT: Not applicable.</p> <p>(Contd. on page 6) <br />GB</p> <p>50.0.4</p> <p>Page 6/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 27.04.2020</p> <p>Version number 20</p> <p>Revision: 27.04.2020</p> <p>Trade name: ESCO-FLUAT</p> <p>· vPvB: Not applicable. <br />· 12.6 Other adverse effects No further relevant information available.</p> <p>(Contd. of page 5)</p> <p>SECTION 13: Disposal considerations <br />· 13.1 Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />· European waste catalogue <br />06 00 00 WASTES FROM INORGANIC CHEMICAL PROCESSES <br />06 03 00 wastes from the MFSU of salts and their solutions and metallic oxides <br />06 03 13* solid salts and solutions containing heavy metals <br />· Uncleaned packagings: <br />· Recommendation: Disposal must be made according to official regulations. <br />· Recommended cleaning agent: Water, if necessary with cleaning agent. <br />*</p> <p>SECTION 14: Transport information <br />· 14.1 UN-Number <br />· ADR, IMDG, IATA <br />· 14.2 UN proper shipping name <br />· ADR <br />· IMDG <br />· IATA</p> <p>UN3082 <br />3082 ENVIRONMENTALLY HAZARDOUS <br />SUBSTANCE, LIQUID, N.O.S. (ZINC <br />FLUOROSILICATE) <br />ENVIRONMENTALLY HAZARDOUS SUBSTANCE, <br />LIQUID, N.O.S. (ZINC FLUOROSILICATE), MARINE <br />POLLUTANT <br />ENVIRONMENTALLY HAZARDOUS SUBSTANCE, <br />LIQUID, N.O.S. (ZINC FLUOROSILICATE)</p> <p>· 14.3 Transport hazard class(es) <br />· ADR, IMDG, IATA</p> <p>· Class <br />· Label</p> <p>9 Miscellaneous dangerous substances and articles. <br />9</p> <p>· 14.4 Packing group <br />· ADR, IMDG, IATA</p> <p>III</p> <p>· 14.5 Environmental hazards: <br />· Marine pollutant: <br />· Special marking (ADR): <br />· Special marking (IATA):</p> <p>Symbol (fish and tree) <br />Symbol (fish and tree) <br />Symbol (fish and tree)</p> <p>· 14.6 Special precautions for user <br />· Kemler Number:</p> <p>Warning: Miscellaneous dangerous substances and <br />articles. <br />90 <br />(Contd. on page 7) <br />GB</p> <p>50.0.4</p> <p>Page 7/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 27.04.2020</p> <p>Version number 20</p> <p>Revision: 27.04.2020</p> <p>Trade name: ESCO-FLUAT <br />(Contd. of page 6)</p> <p>· EMS Number: <br />· Segregation groups <br />· Stowage Category</p> <p>F-A,S-F <br />Heavy metals and their salts (including their <br />organometallic compounds) <br />A</p> <p>· 14.7 Transport in bulk according to Annex II of <br />Marpol and the IBC Code <br />Not applicable. <br />· Transport/Additional information: <br />· ADR <br />· Limited quantities (LQ) <br />· Excepted quantities (EQ) <br />· Transport category <br />· Tunnel restriction code <br />· IMDG <br />· Limited quantities (LQ) <br />· Excepted quantities (EQ)</p> <p>· UN "Model Regulation":</p> <p>*</p> <p>5L <br />Code: E1 <br />Maximum net quantity per inner packaging: 30 ml <br />Maximum net quantity per outer packaging: 1000 ml <br />3 <br />5L <br />Code: E1 <br />Maximum net quantity per inner packaging: 30 ml <br />Maximum net quantity per outer packaging: 1000 ml <br />UN 3082 ENVIRONMENTALLY HAZARDOUS <br />SUBSTANCE, LIQUID, N.O.S. (ZINC <br />FLUOROSILICATE), 9, III</p> <p>SECTION 15: Regulatory information <br />· 15.1 Safety, health and environmental regulations/legislation specific for the substance or <br />mixture <br />· Directive 2012/18/EU <br />· Named dangerous substances - ANNEX I None of the ingredients is listed. <br />· Seveso category E2 Hazardous to the Aquatic Environment <br />· Qualifying quantity (tonnes) for the application of lower-tier requirements 200 t <br />· Qualifying quantity (tonnes) for the application of upper-tier requirements 500 t <br />· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3 <br />· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.</p> <p>*</p> <p>SECTION 16: Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for any <br />specific product features and shall not establish a legally valid contractual relationship. <br />· Relevant phrases <br />H301 Toxic if swallowed. <br />H311 Toxic in contact with skin. <br />H314 Causes severe skin burns and eye damage. <br />H318 Causes serious eye damage. <br />H331 Toxic if inhaled. <br />H400 Very toxic to aquatic life. <br />H410 Very toxic to aquatic life with long lasting effects. <br />· Department issuing data specification sheet: Environment protection department. <br />(Contd. on page 8) <br />GB</p> <p>50.0.4</p> <p>Page 8/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 27.04.2020</p> <p>Version number 20</p> <p>Revision: 27.04.2020</p> <p>Trade name: ESCO-FLUAT</p> <p>· Contact: Mr. Guido Herfort <br />· Abbreviations and acronyms:</p> <p>(Contd. of page 7)</p> <p>ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the <br />International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />GHS: Globally Harmonised System of Classification and Labelling of Chemicals <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />PBT: Persistent, Bioaccumulative and Toxic <br />vPvB: very Persistent and very Bioaccumulative <br />Acute Tox. 3: Acute toxicity - oral – Category 3 <br />Acute Tox. 4: Acute toxicity - oral – Category 4 <br />Skin Corr. 1A: Skin corrosion/irritation – Category 1A <br />Eye Dam. 1: Serious eye damage/eye irritation – Category 1 <br />Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1 <br />Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1 <br />Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2</p> <p>· * Data compared to the previous version altered.</p> <p>GB</p>
