ASODUR-GH-S_(B-Komp.)_(1)EN.pdf
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<h1>ASODUR-GH-S_(B-Komp.)_(1)EN.pdf</h1> <p>50.0.4</p> <p>Page 1/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 20.01.2020</p> <p>Version number 1</p> <p>Revision: 20.01.2020</p> <p>SECTION 1: Identification of the substance/mixture and of the company/undertaking <br />· 1.1 Product identifier <br />· Trade name: ASODUR-GH-S (B-Komp.) <br />· 1.2 Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture Reaction resin <br />· 1.3 Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH & Co. KG <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />Fax: ++49 (0)5231/953-123 <br />email: info@schomburg.de <br />web: www.schomburg.de <br />· Informing department: <br />Product Safety Department <br />Tel: ++49 (0)5231/953-193 <br />Fax: ++49 (0)5231/953-106 <br />email: SDB@schomburg.de <br />SECTION 2: Hazards identification <br />· 2.1 Classification of the substance or mixture <br />· Classification according to Regulation (EC) No 1272/2008 <br />GHS08 health hazard <br />Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />Carc. 2 <br />H351 Suspected of causing cancer. <br />STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. <br />GHS07 <br />Acute Tox. 4 <br />Skin Irrit. 2 <br />Eye Irrit. 2 <br />Skin Sens. 1 <br />STOT SE 3</p> <p>H332 Harmful if inhaled. <br />H315 Causes skin irritation. <br />H319 Causes serious eye irritation. <br />H317 May cause an allergic skin reaction. <br />H335 May cause respiratory irritation.</p> <p>· 2.2 Label elements <br />· Labelling according to Regulation (EC) No 1272/2008 <br />The product is classified and labelled according to the CLP regulation. <br />· Hazard pictograms GHS07, GHS08 <br />· Signal word Danger</p> <p>(Contd. on page 2) <br />GB</p> <p>50.0.4</p> <p>Page 2/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 20.01.2020</p> <p>Version number 1</p> <p>Revision: 20.01.2020</p> <p>Trade name: ASODUR-GH-S (B-Komp.) <br />(Contd. of page 1)</p> <p>· Hazard-determining components of labelling: <br />diphenylmethanediisocyanate,isomeres and homologues <br />· Hazard statements <br />H332 Harmful if inhaled. <br />H315 Causes skin irritation. <br />H319 Causes serious eye irritation. <br />H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />H317 May cause an allergic skin reaction. <br />H351 Suspected of causing cancer. <br />H335 May cause respiratory irritation. <br />H373 May cause damage to organs through prolonged or repeated exposure. <br />· Precautionary statements <br />P261 <br />Avoid breathing dust/fume/gas/mist/vapours/spray. <br />P281 <br />Use personal protective equipment as required. <br />P302+P352 <br />IF ON SKIN: Wash with plenty of water. <br />P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, <br />if present and easy to do. Continue rinsing. <br />P342+P311 <br />If experiencing respiratory symptoms: Call a POISON CENTER/doctor. <br />P501 <br />Dispose of contents/container in accordance with local/regional/national/international <br />regulations. <br />· Additional information: <br />EUH204 Contains isocyanates. May produce an allergic reaction. <br />· 2.3 Other hazards <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />SECTION 3: Composition/information on ingredients <br />· 3.2 Chemical characterisation: Mixtures <br />· Description: Produkt based on polyisocyanate. <br />· Dangerous components: <br />9016-87-9 diphenylmethanediisocyanate,isomeres and homologues <br />50-100% <br />Resp. Sens. 1, H334; Carc. 2, H351; STOT RE 2, H373; <br />Acute Tox. 4, H332; <br />Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335 <br />· Additional information For the wording of the listed hazard phrases refer to section 16. <br />SECTION 4: First aid measures <br />· 4.1 Description of first aid measures <br />· General information <br />Symptoms of poisoning may even occur after several hours; therefore medical observation for at least <br />48 hours after the accident. <br />Personal protection for the First Aider. <br />It is possible to choke in case of vomiting in unconsciousness. <br />Bring unconscious persons into a stable position on side. <br />Keep the respiratory tract free (remove dentures and vomiting). <br />Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of <br />breathing: artificial respiration. <br />Take up a doctor immediately! <br />· After inhalation <br />Supply fresh air or oxygen; call for doctor. <br />(Contd. on page 3) <br />GB</p> <p>50.0.4</p> <p>Page 3/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 20.01.2020</p> <p>Version number 1</p> <p>Revision: 20.01.2020</p> <p>Trade name: ASODUR-GH-S (B-Komp.) <br />(Contd. of page 2)</p> <p>In case of unconsciousness bring patient into stable side position for transport. <br />· After skin contact <br />Instantly wash with water and soap and rinse thoroughly. <br />Change immediately contaminated clothes. <br />· After eye contact <br />Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. <br />· After swallowing <br />Do not induce vomiting; instantly call for medical help. <br />Show the pack or the label to the doctor. <br />· 4.2 Most important symptoms and effects, both acute and delayed <br />No further relevant information available. <br />· 4.3 Indication of any immediate medical attention and special treatment needed <br />No further relevant information available. <br />SECTION 5: Firefighting measures</p> <p>· 5.1 Extinguishing media <br />· Suitable extinguishing agents <br />CO2, extinguishing powder or water jet. Fight larger fires with water jet. <br />Use fire fighting measures that suit the environment. <br />· 5.2 Special hazards arising from the substance or mixture <br />Formation of poisonous gases during heating or in fires. <br />Carbon monoxide (CO) <br />Nitrogen oxides (NOx) <br />Hydrogen cyanide (HCN) <br />· 5.3 Advice for firefighters <br />· Protective equipment: <br />Wear self-contained breathing apparatus. <br />Wear full protective suit. <br />· Additional information <br />Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. <br />Follow the emergency-plan. <br />Burst- and explosion-danger by increasing pressure. <br />In case of fire chill the container with water spray. <br />SECTION 6: Accidental release measures <br />· 6.1 Personal precautions, protective equipment and emergency procedures <br />Wear protective equipment. Keep unprotected persons away. <br />Ensure adequate ventilation <br />· 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. <br />· 6.3 Methods and material for containment and cleaning up: <br />Ensure adequate ventilation. <br />Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). <br />· 6.4 Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />See Section 13 for information on disposal. <br />GB</p> <p>(Contd. on page 4)</p> <p>50.0.4</p> <p>Page 4/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 20.01.2020</p> <p>Version number 1</p> <p>Revision: 20.01.2020</p> <p>Trade name: ASODUR-GH-S (B-Komp.) <br />(Contd. of page 3)</p> <p>SECTION 7: Handling and storage <br />· 7.1 Precautions for safe handling <br />Ensure good ventilation/exhaustion at the workplace. <br />Prevent formation of aerosols. <br />· Information about protection against explosions and fires: No special measures required. <br />· 7.2 Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: <br />The Product reacts with water and CO2-Gas will be given off. <br />In tight closed containers pressure may arise and the cover can burst. <br />Store only in unopened original containers. <br />· Information about storage in one common storage facility: <br />Please follow the rules of the VCI-Storage-Concept for chemicals. <br />Store away from water. <br />Do not store together with oxidising and acidic materials. <br />· Further information about storage conditions: <br />Keep container tightly sealed. <br />Store in a locked cabinet and out of the reach of children. <br />Store under dry conditions. <br />· 7.3 Specific end use(s) No further relevant information available. <br />SECTION 8: Exposure controls/personal protection <br />· Additional information about design of technical systems: No further data; see item 7 MSDS. <br />· 8.1 Control parameters <br />· Components with critical values that require monitoring at the workplace: <br />9016-87-9 diphenylmethanediisocyanate,isomeres and homologues (50-100%) <br />WEL Short-term value: 0.07 mg/m³ <br />Long-term value: 0.02 mg/m³ <br />Sen; as -NCO <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· 8.2 Exposure controls <br />· Personal protective equipment <br />· General protective and hygienic measures <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />Keep away from foodstuffs, beverages and food. <br />Instantly remove any soiled and impregnated garments. <br />Avoid contact with the eyes and skin. <br />Be sure to clean skin thoroughly after work and before breaks. <br />· Breathing equipment: <br />In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer <br />exposure use breathing apparatus that is independent of circulating air. <br />· Protection of hands: <br />Selection of the glove material on consideration of the penetration times, rates of diffusion and the <br />degradation <br />Hand Protection: Nitril-rubber-latex-gloves. <br />· Material of gloves <br />The selection of the suitable gloves does not only depend on the material, but also on further marks of <br />quality and varies from manufacturer to manufacturer. <br />(Contd. on page 5) <br />GB</p> <p>50.0.4</p> <p>Page 5/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 20.01.2020</p> <p>Version number 1</p> <p>Revision: 20.01.2020</p> <p>Trade name: ASODUR-GH-S (B-Komp.)</p> <p>Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Break through time 480 min</p> <p>(Contd. of page 4)</p> <p>· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and has to <br />be observed. <br />· Eye protection: Safety glasses <br />· Body protection: <br />Contaminated protection clothes must be cleaned carefully before reuse. <br />Protective work clothing. <br />SECTION 9: Physical and chemical properties <br />· 9.1 Information on basic physical and chemical properties <br />· General Information <br />· Appearance: <br />Form: <br />Liquid <br />Colour: <br />Various colours <br />· Smell: <br />Weak, characteristic <br />· Odour threshold: <br />Not determined. <br />· pH-value:</p> <p>Not determined.</p> <p>· Change in condition <br />Melting point/freezing point: <br />Not determined <br />Initial boiling point and boiling range: >200 °C <br />· Flash point:</p> <p>>100 °C</p> <p>· Inflammability (solid, gaseous)</p> <p>Not applicable.</p> <p>· Ignition temperature:</p> <p>530 °C</p> <p>· Decomposition temperature:</p> <p>Not determined.</p> <p>· Self-inflammability:</p> <p>Not determined.</p> <p>· Explosive properties:</p> <p>Product is not explosive.</p> <p>· Critical values for explosion: <br />Lower: <br />Upper:</p> <p>Not determined. <br />Not determined.</p> <p>· Steam pressure:</p> <p>Not determined.</p> <p>· Density at 20 °C <br />· Relative density <br />· Vapour density <br />· Evaporation rate</p> <p>1.12 g/cm³ <br />Not determined. <br />Not determined. <br />Not determined.</p> <p>· Solubility in / Miscibility with <br />Water:</p> <p>Not miscible or difficult to mix</p> <p>· Partition coefficient: n-octanol/water:</p> <p>Not determined.</p> <p>· Viscosity: <br />dynamic at 20 °C: <br />kinematic:</p> <p>160 mPas <br />Not determined. <br />(Contd. on page 6) <br />GB</p> <p>50.0.4</p> <p>Page 6/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 20.01.2020</p> <p>Version number 1</p> <p>Revision: 20.01.2020</p> <p>Trade name: ASODUR-GH-S (B-Komp.) <br />(Contd. of page 5)</p> <p>· 9.2 Other information</p> <p>No further relevant information available.</p> <p>SECTION 10: Stability and reactivity <br />· 10.1 Reactivity No further relevant information available. <br />· 10.2 Chemical stability <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· 10.3 Possibility of hazardous reactions No dangerous reactions known <br />· 10.4 Conditions to avoid No further relevant information available. <br />· 10.5 Incompatible materials: No further relevant information available. <br />· 10.6 Hazardous decomposition products: No dangerous decomposition products known <br />SECTION 11: Toxicological information <br />· 11.1 Information on toxicological effects <br />· Acute toxicity <br />Harmful if inhaled. <br />· LD/LC50 values that are relevant for classification: <br />9016-87-9 diphenylmethanediisocyanate,isomeres and homologues <br />Oral <br />LD50 <br />>5,000 mg/kg (rats) <br />Dermal LD50 <br />>9,400 mg/kg (rabbit) (OECD Guideline 404) <br />Inhalative LC50/4 h 0.49 mg/l (rats) (OECD Guideline 403) <br />· Primary irritant effect: <br />· Skin corrosion/irritation <br />The product has an irritate-effect. <br />Causes skin irritation. <br />· Serious eye damage/irritation <br />Causes serious eye irritation. <br />· Respiratory or skin sensitisation <br />May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />May cause an allergic skin reaction. <br />· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) <br />· Germ cell mutagenicity Based on available data, the classification criteria are not met. <br />· Carcinogenicity <br />Suspected of causing cancer. <br />· Reproductive toxicity Based on available data, the classification criteria are not met. <br />· STOT-single exposure <br />May cause respiratory irritation. <br />· STOT-repeated exposure <br />May cause damage to organs through prolonged or repeated exposure. <br />· Aspiration hazard Based on available data, the classification criteria are not met. <br />SECTION 12: Ecological information <br />· 12.1 Toxicity <br />· Aquatic toxicity: <br />9016-87-9 diphenylmethanediisocyanate,isomeres and homologues <br />EC 50 <br />>1,000 mg/kg (daphnia magna) (OECD Guideline 202)</p> <p>(Contd. on page 7) <br />GB</p> <p>50.0.4</p> <p>Page 7/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 20.01.2020</p> <p>Version number 1</p> <p>Revision: 20.01.2020</p> <p>Trade name: ASODUR-GH-S (B-Komp.) <br />(Contd. of page 6)</p> <p>>1,640 mg/kg (Grünalge (Scenedesmus subspicatus)) (OECD Guideline 201) <br />LC50/96h >1,000 mg/l (zebra danio) (OECD Guideline 203) <br />NOEC <br />>10 mg/l (daphnia magna) (OECD Guideline 211) <br />· 12.2 Persistence and degradability No further relevant information available. <br />· 12.3 Bioaccumulative potential No further relevant information available. <br />· 12.4 Mobility in soil No further relevant information available. <br />· Additional ecological information: <br />· General notes: <br />Water danger class 3 (Self-assessment): extremely hazardous for water. <br />Do not allow product to reach ground water, water bodies or sewage system, even in small quantities. <br />Danger to drinking water if even extremely small quantities leak into soil. <br />· 12.5 Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />· 12.6 Other adverse effects No further relevant information available. <br />SECTION 13: Disposal considerations <br />· 13.1 Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />· European waste catalogue <br />08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF <br />COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS <br />AND PRINTING INKS <br />08 05 00 wastes not otherwise specified in 08 <br />08 05 01* waste isocyanates <br />15 00 00 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND <br />PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED <br />15 01 00 packaging (including separately collected municipal packaging waste) <br />15 01 10* packaging containing residues of or contaminated by hazardous substances <br />· Uncleaned packagings: <br />· Recommendation: Disposal must be made according to official regulations. <br />SECTION 14: Transport information <br />· 14.1 UN-Number <br />· ADR, IMDG, IATA</p> <p>Void</p> <p>· 14.2 UN proper shipping name <br />· ADR, IMDG, IATA</p> <p>Void</p> <p>· 14.3 Transport hazard class(es) <br />· ADR, ADN, IMDG, IATA <br />· Class</p> <p>Void</p> <p>· 14.4 Packing group <br />· ADR, IMDG, IATA</p> <p>Void <br />(Contd. on page 8) <br />GB</p> <p>50.0.4</p> <p>Page 8/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 20.01.2020</p> <p>Version number 1</p> <p>Revision: 20.01.2020</p> <p>Trade name: ASODUR-GH-S (B-Komp.) <br />(Contd. of page 7)</p> <p>· 14.5 Environmental hazards:</p> <p>Not applicable.</p> <p>· 14.6 Special precautions for user</p> <p>Not applicable.</p> <p>· 14.7 Transport in bulk according to Annex II of <br />Marpol and the IBC Code <br />Not applicable. <br />· UN "Model Regulation":</p> <p>Void</p> <p>SECTION 15: Regulatory information <br />· 15.1 Safety, health and environmental regulations/legislation specific for the substance or <br />mixture <br />· Directive 2012/18/EU <br />· Named dangerous substances - ANNEX I None of the ingredients is listed. <br />· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3 <br />· National regulations <br />· Technical instructions (air): <br />· Class Share in % <br />· I <br />75.0 <br />· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. <br />SECTION 16: Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for any <br />specific product features and shall not establish a legally valid contractual relationship. <br />· Relevant phrases <br />H315 Causes skin irritation. <br />H317 May cause an allergic skin reaction. <br />H319 Causes serious eye irritation. <br />H332 Harmful if inhaled. <br />H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />H335 May cause respiratory irritation. <br />H351 Suspected of causing cancer. <br />H373 May cause damage to organs through prolonged or repeated exposure. <br />· Department issuing data specification sheet: Environment protection department. <br />· Contact: Mr. Guido Herfort <br />· Abbreviations and acronyms: <br />ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the <br />International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />GHS: Globally Harmonised System of Classification and Labelling of Chemicals <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />PBT: Persistent, Bioaccumulative and Toxic <br />vPvB: very Persistent and very Bioaccumulative <br />Acute Tox. 4: Acute toxicity - inhalation – Category 4 <br />Skin Irrit. 2: Skin corrosion/irritation – Category 2 <br />Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 <br />Resp. Sens. 1: Respiratory sensitisation – Category 1 <br />(Contd. on page 9) <br />GB</p> <p>50.0.4</p> <p>Page 9/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 20.01.2020</p> <p>Version number 1</p> <p>Revision: 20.01.2020</p> <p>Trade name: ASODUR-GH-S (B-Komp.) <br />(Contd. of page 8) <br />Skin Sens. 1: Skin sensitisation – Category 1 <br />Carc. 2: Carcinogenicity – Category 2 <br />STOT SE 3: Specific target organ toxicity (single exposure) – Category 3 <br />STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2 <br />GB</p>
