ASO-R008_-_205809_(12)GB.pdf
7 页数
202.3 KB
Download
<h1>ASO-R008_-_205809_(12)GB.pdf</h1> <p>51.1.24</p> <p>Page 1/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 28.10.2020 <br />*</p> <p>Version number 12</p> <p>Revision: 28.10.2020</p> <p>SECTION 1: Identification of the substance/mixture and of the company/undertaking <br />· 1.1 Product identifier <br />· Trade name: ASO-R008 <br />· 1.2 Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture Cleaning agent/ Cleaner <br />· 1.3 Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH & Co. KG <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />Fax: ++49 (0)5231/953-123 <br />email: info@schomburg.de <br />web: www.schomburg.de <br />· Informing department: <br />Product Safety Department <br />Tel: ++49 (0)5231/953-193 <br />Fax: ++49 (0)5231/953-106 <br />email: SDB@schomburg.de <br />SECTION 2: Hazards identification <br />· 2.1 Classification of the substance or mixture <br />· Classification according to Regulation (EC) No 1272/2008 <br />GHS07 <br />Skin Irrit. 2 H315 Causes skin irritation. <br />Eye Irrit. 2 H319 Causes serious eye irritation. <br />· 2.2 Label elements <br />· Labelling according to Regulation (EC) No 1272/2008 <br />The product is classified and labelled according to the CLP regulation. <br />· Hazard pictograms GHS07 <br />· Signal word Warning <br />· Hazard-determining components of labelling: <br />sodium hydroxide <br />· Hazard statements <br />H315 Causes skin irritation. <br />H319 Causes serious eye irritation. <br />· Precautionary statements <br />P264 <br />Wash thoroughly after handling. <br />P280 <br />Wear protective gloves / eye protection / face protection. <br />P302+P352 <br />IF ON SKIN: Wash with plenty of water. <br />P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact <br />lenses, if present and easy to do. Continue rinsing. <br />P332+P313 <br />If skin irritation occurs: Get medical advice/attention. <br />P337+P313 <br />If eye irritation persists: Get medical advice/attention. <br />· 2.3 Other hazards <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />(Contd. on page 2) <br />GB</p> <p>51.1.24</p> <p>Page 2/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 28.10.2020</p> <p>Version number 12</p> <p>Revision: 28.10.2020</p> <p>Trade name: ASO-R008 <br />(Contd. of page 1)</p> <p>· vPvB: Not applicable. <br />SECTION 3: Composition/information on ingredients <br />· 3.2 Chemical characterisation: Mixtures <br />· Description: aqueous combination of washing and surface active substances <br />· Dangerous components: <br />CAS: 111-76-2 <br />2-butoxyethanol <br />EINECS: 203-905-0 <br />Acute Tox. 4, H302; Acute Tox. 4, H312; Acute Tox. 4, H332; Skin <br />Irrit. 2, H315; Eye Irrit. 2, H319 <br />CAS: 1310-73-2 <br />sodium hydroxide <br />EINECS: 215-185-5 <br />Skin Corr. 1A, H314; <br />Acute Tox. 4, H302 <br />Specific concentration limits: Skin Corr. 1A; H314: C ≥ 5 % <br />Skin Corr. 1B; H314: 2 % ≤ C < 5 % <br />Skin Irrit. 2; H315: 0.5 % ≤ C < 2 % <br />Eye Irrit. 2; H319: 0.5 % ≤ C < 2 % <br />· Additional information For the wording of the listed hazard phrases refer to section 16.</p> <p><2.5%</p> <p><1%</p> <p>SECTION 4: First aid measures <br />· 4.1 Description of first aid measures <br />· General information <br />Personal protection for the First Aider. <br />It is possible to choke in case of vomiting in unconsciousness. <br />Bring unconscious persons into a stable position on side. <br />Keep the respiratory tract free (remove dentures and vomiting). <br />Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage <br />of breathing: artificial respiration. <br />Take up a doctor immediately! <br />· After inhalation Supply fresh air or oxygen; call for doctor. <br />· After skin contact Instantly wash with water and soap and rinse thoroughly. <br />· After eye contact <br />Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. <br />· After swallowing <br />Drink copious amounts of water and provide fresh air. Instantly call for doctor. <br />Show the pack or the label to the doctor. <br />· 4.2 Most important symptoms and effects, both acute and delayed <br />No further relevant information available. <br />· 4.3 Indication of any immediate medical attention and special treatment needed <br />No further relevant information available. <br />SECTION 5: Firefighting measures <br />· 5.1 Extinguishing media <br />· Suitable extinguishing agents <br />CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. <br />· 5.2 Special hazards arising from the substance or mixture <br />No further relevant information available. <br />· 5.3 Advice for firefighters <br />· Protective equipment: Wear self-contained breathing apparatus. <br />· Additional information <br />Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. <br />Follow the emergency-plan. <br />GB</p> <p>(Contd. on page 3)</p> <p>51.1.24</p> <p>Page 3/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 28.10.2020</p> <p>Version number 12</p> <p>Revision: 28.10.2020</p> <p>Trade name: ASO-R008 <br />(Contd. of page 2)</p> <p>SECTION 6: Accidental release measures <br />· 6.1 Personal precautions, protective equipment and emergency procedures <br />Bring persons out of danger. <br />Wear protective equipment. Keep unprotected persons away. <br />· 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. <br />· 6.3 Methods and material for containment and cleaning up: <br />Dispose of the material collected according to regulations. <br />· 6.4 Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />See Section 13 for information on disposal. <br />SECTION 7: Handling and storage <br />· 7.1 Precautions for safe handling <br />Ensure good ventilation/exhaustion at the workplace. <br />Keep away from children. <br />· Information about protection against explosions and fires: No special measures required. <br />· 7.2 Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: No special requirements. <br />· Information about storage in one common storage facility: <br />Please follow the rules of the VCI-Storage-Concept for chemicals. <br />Keep dry. <br />· Further information about storage conditions: Keep container tightly sealed. <br />· 7.3 Specific end use(s) No further relevant information available. <br />SECTION 8: Exposure controls/personal protection <br />· Additional information about design of technical systems: <br />It must be possible to wash the skin in the working area. <br />Eye-wash bottle must be available. <br />· 8.1 Control parameters <br />· Components with critical values that require monitoring at the workplace: <br />111-76-2 2-butoxyethanol (<2.5%) <br />WEL Short-term value: 246 mg/m³, 50 ppm <br />Long-term value: 123 mg/m³, 25 ppm <br />Sk, BMGV <br />· Ingredients with biological limit values: <br />111-76-2 2-butoxyethanol (<2.5%) <br />BMGV 240 mmol/mol creatinine <br />Medium: urine <br />Sampling time: post shift <br />Parameter: butoxyacetic acid <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· 8.2 Exposure controls <br />· Personal protective equipment <br />· General protective and hygienic measures <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />Instantly remove any soiled and impregnated garments. <br />Avoid contact with the eyes and skin. <br />Be sure to clean skin thoroughly after work and before breaks. <br />· Breathing equipment: Not required. <br />· Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. <br />(Contd. on page 4) <br />GB</p> <p>51.1.24</p> <p>Page 4/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 28.10.2020</p> <p>Version number 12</p> <p>Revision: 28.10.2020</p> <p>Trade name: ASO-R008 <br />(Contd. of page 3)</p> <p>· Material of gloves <br />Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Break through time 480 min <br />· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and <br />has to be observed. <br />· Eye protection: Safety glasses <br />· Body protection: Protective work clothing. <br />SECTION 9: Physical and chemical properties <br />· 9.1 Information on basic physical and chemical properties <br />· General Information <br />· Appearance: <br />Form: <br />Fluid <br />Colour: <br />Colourless <br />· Smell: <br />Characteristic <br />· Odour threshold: <br />Not determined. <br />· pH-value at 20 °C:</p> <p>11.5</p> <p>· Change in condition <br />Melting point/freezing point: <br />Not determined <br />Initial boiling point and boiling range: >100 °C <br />· Flash point:</p> <p>Not applicable</p> <p>· Inflammability (solid, gaseous)</p> <p>Not applicable.</p> <p>· Ignition temperature:</p> <p>>240 °C <br />240 °C</p> <p>· Decomposition temperature:</p> <p>Not determined.</p> <p>· Self-inflammability:</p> <p>Product is not selfigniting.</p> <p>· Explosive properties:</p> <p>Product is not explosive.</p> <p>· Critical values for explosion: <br />Lower: <br />Upper:</p> <p>Not determined. <br />Not determined.</p> <p>· Steam pressure at 20 °C:</p> <p>23 hPa <br />23 mbar 20° C</p> <p>· Density at 20 °C <br />· Relative density <br />· Vapour density <br />· Evaporation rate</p> <p>1.02 g/cm³ <br />Not determined. <br />Not determined. <br />Not determined.</p> <p>· Solubility in / Miscibility with <br />Water:</p> <p>miscible</p> <p>· Partition coefficient: n-octanol/water:</p> <p>Not determined.</p> <p>· Viscosity: <br />dynamic: <br />kinematic: <br />· 9.2 Other information</p> <p>Not determined. <br />Not determined. <br />No further relevant information available.</p> <p>SECTION 10: Stability and reactivity <br />· 10.1 Reactivity No further relevant information available. <br />(Contd. on page 5) <br />GB</p> <p>51.1.24</p> <p>Page 5/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 28.10.2020</p> <p>Version number 12</p> <p>Revision: 28.10.2020</p> <p>Trade name: ASO-R008 <br />(Contd. of page 4)</p> <p>· 10.2 Chemical stability <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· 10.3 Possibility of hazardous reactions No dangerous reactions known <br />· 10.4 Conditions to avoid No further relevant information available. <br />· 10.5 Incompatible materials: Acids <br />· 10.6 Hazardous decomposition products: No dangerous decomposition products known <br />SECTION 11: Toxicological information <br />· 11.1 Information on toxicological effects <br />· Acute toxicity Based on available data, the classification criteria are not met. <br />· LD/LC50 values that are relevant for classification: <br />111-76-2 2-butoxyethanol <br />Oral <br />LD50 <br />1,480 mg/kg (rats) <br />Dermal LD50 <br />1,500 mg/kg (rabbit) <br />Inhalative LC50/4 h 15 mg/l (rats) <br />1310-73-2 sodium hydroxide <br />Oral <br />LD50 <br />325-500 mg/kg (rats) <br />· Primary irritant effect: <br />· Skin corrosion/irritation <br />Causes skin irritation. <br />· Serious eye damage/irritation <br />Causes serious eye irritation. <br />· Respiratory or skin sensitisation Based on available data, the classification criteria are not met. <br />· Additional toxicological information: Sensitizing <br />· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) <br />· Germ cell mutagenicity Based on available data, the classification criteria are not met. <br />· Carcinogenicity Based on available data, the classification criteria are not met. <br />· Reproductive toxicity Based on available data, the classification criteria are not met. <br />· STOT-single exposure Based on available data, the classification criteria are not met. <br />· STOT-repeated exposure Based on available data, the classification criteria are not met. <br />· Aspiration hazard Based on available data, the classification criteria are not met. <br />SECTION 12: Ecological information <br />· 12.1 Toxicity <br />· Aquatic toxicity: <br />111-76-2 2-butoxyethanol <br />LC50/96h 1,474 mg/l (for) <br />EC50 (48h) 1,550 mg/l (Daphnia magna) <br />1310-73-2 sodium hydroxide <br />LC50 (48h) 133 mg/l (orfe) <br />LC50/96h 35-189 mg/l (orfe) <br />EC50 (48h) 40 mg/l (water flea (Ceriodaphnia spec) <br />· 12.2 Persistence and degradability No further relevant information available. <br />· 12.3 Bioaccumulative potential No further relevant information available. <br />· 12.4 Mobility in soil No further relevant information available. <br />· Additional ecological information: <br />· General notes: <br />Water hazard class 1 (Self-assessment): slightly hazardous for water. <br />Do not allow undiluted product or large quantities of it to reach ground water, water bodies or <br />sewage system. <br />(Contd. on page 6) <br />GB</p> <p>51.1.24</p> <p>Page 6/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 28.10.2020</p> <p>Version number 12</p> <p>Revision: 28.10.2020</p> <p>Trade name: ASO-R008 <br />(Contd. of page 5)</p> <p>Must not reach sewage water or drainage ditch undiluted or unneutralised. <br />Rinse off of bigger amounts into drains or the aquatic environment may lead to increased pH-values. <br />A high pH-value harms aquatic organisms. In the dilution of the use-level the pH-value is <br />considerably reduced, so that after the use of the product the aqueous waste, emptied into drains, is <br />only low water-dangerous. <br />· 12.5 Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />· 12.6 Other adverse effects No further relevant information available. <br />SECTION 13: Disposal considerations <br />· 13.1 Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />· European waste catalogue <br />07 00 00 WASTES FROM ORGANIC CHEMICAL PROCESSES <br />07 06 00 wastes from the MFSU of fats, grease, soaps, detergents, disinfectants and cosmetics <br />07 06 01* aqueous washing liquids and mother liquors <br />· Uncleaned packagings: <br />· Recommendation: Disposal must be made according to official regulations. <br />· Recommended cleaning agent: Water, if necessary with cleaning agent. <br />SECTION 14: Transport information <br />· 14.1 UN-Number <br />· ADR, ADN, IMDG, IATA</p> <p>Void</p> <p>· 14.2 UN proper shipping name <br />· ADR, ADN, IMDG, IATA</p> <p>Void</p> <p>· 14.3 Transport hazard class(es) <br />· ADR, ADN, IMDG, IATA <br />· Class</p> <p>Void</p> <p>· 14.4 Packing group <br />· ADR, IMDG, IATA</p> <p>Void</p> <p>· 14.5 Environmental hazards: <br />· Marine pollutant:</p> <p>No</p> <p>· 14.6 Special precautions for user</p> <p>Not applicable.</p> <p>· 14.7 Transport in bulk according to Annex II <br />of Marpol and the IBC Code <br />Not applicable. <br />· UN "Model Regulation":</p> <p>*</p> <p>Void</p> <p>SECTION 15: Regulatory information <br />· 15.1 Safety, health and environmental regulations/legislation specific for the substance or <br />mixture <br />· Directive 2012/18/EU <br />· Named dangerous substances - ANNEX I None of the ingredients is listed. <br />(Contd. on page 7) <br />GB</p> <p>51.1.24</p> <p>Page 7/7</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 28.10.2020</p> <p>Version number 12</p> <p>Revision: 28.10.2020</p> <p>Trade name: ASO-R008 <br />(Contd. of page 6)</p> <p>· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3 <br />· DIRECTIVE 2011/65/EU on the restriction of the use of certain hazardous substances in <br />electrical and electronic equipment – Annex II <br />None of the ingredients is listed. <br />· National regulations <br />· Technical instructions (air): <br />· Class Share in % <br />· NK <br />1.5 <br />· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. <br />SECTION 16: Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for <br />any specific product features and shall not establish a legally valid contractual relationship. <br />· Relevant phrases <br />H302 Harmful if swallowed. <br />H312 Harmful in contact with skin. <br />H314 Causes severe skin burns and eye damage. <br />H315 Causes skin irritation. <br />H319 Causes serious eye irritation. <br />H332 Harmful if inhaled. <br />· Department issuing data specification sheet: Environment protection department. <br />· Contact: Mr. Guido Herfort <br />· Abbreviations and acronyms: <br />ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the <br />International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />GHS: Globally Harmonised System of Classification and Labelling of Chemicals <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />PBT: Persistent, Bioaccumulative and Toxic <br />vPvB: very Persistent and very Bioaccumulative <br />Acute Tox. 4: Acute toxicity - oral – Category 4 <br />Skin Corr. 1A: Skin corrosion/irritation – Category 1A <br />Skin Irrit. 2: Skin corrosion/irritation – Category 2 <br />Eye Irrit. 2: Serious eye damage/eye irritation – Category 2</p> <p>· * Data compared to the previous version altered. <br />GB</p>
