SDS_AQUAFIN-P1_-_205220_(14)EN.pdf
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<h1>SDS_AQUAFIN-P1_-_205220_(14)EN.pdf</h1> <p>54.0</p> <p>Page 1/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 01.02.2022 <br />*</p> <p>Version number 14</p> <p>Revision: 01.02.2022</p> <p>SECTION 1: Identification of the substance/mixture and of the company/undertaking <br />· 1.1 Product identifier <br />· Trade name: AQUAFIN-P1 <br />· 1.2 Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture Reaction resin <br />· 1.3 Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH & Co. KG <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />email: info@schomburg.de <br />· Informing department: <br />Product Safety Department <br />Tel: ++49 (0)5231/953-770 <br />email: SDB@schomburg.de</p> <p>*</p> <p>SECTION 2: Hazards identification <br />· 2.1 Classification of the substance or mixture <br />· Classification according to Regulation (EC) No 1272/2008 <br />health hazard <br />Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />Carc. 2 <br />H351 Suspected of causing cancer. <br />STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.</p> <p>Acute Tox. 4 <br />Skin Irrit. 2 <br />Eye Irrit. 2 <br />Skin Sens. 1 <br />STOT SE 3</p> <p>H332 Harmful if inhaled. <br />H315 Causes skin irritation. <br />H319 Causes serious eye irritation. <br />H317 May cause an allergic skin reaction. <br />H335 May cause respiratory irritation.</p> <p>· 2.2 Label elements <br />· Labelling according to Regulation (EC) No 1272/2008 <br />The product is classified and labelled according to the CLP regulation. <br />· Hazard pictograms GHS07, GHS08 <br />· Signal word Danger <br />· Hazard-determining components of labelling: <br />diphenylmethanediisocyanate,isomeres and homologues <br />· Hazard statements <br />H332 Harmful if inhaled. <br />H315 Causes skin irritation. <br />H319 Causes serious eye irritation. <br />(Contd. on page 2) <br />GB</p> <p>54.0</p> <p>Page 2/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 01.02.2022</p> <p>Version number 14</p> <p>Revision: 01.02.2022</p> <p>Trade name: AQUAFIN-P1 <br />(Contd. of page 1)</p> <p>H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />H317 May cause an allergic skin reaction. <br />H351 Suspected of causing cancer. <br />H335 May cause respiratory irritation. <br />H373 May cause damage to organs through prolonged or repeated exposure. <br />· Precautionary statements <br />P260 <br />Do not breathe dust/fume/gas/mist/vapours/spray. <br />P280 <br />Wear protective gloves/protective clothing/eye protection/face protection/hearing <br />protection. <br />P284 <br />[In case of inadequate ventilation] wear respiratory protection. <br />P302+P352 <br />IF ON SKIN: Wash with plenty of soap and water. <br />P304+P340 <br />IF INHALED: Remove person to fresh air and keep comfortable for breathing. <br />P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact <br />lenses, if present and easy to do. Continue rinsing. <br />· Additional information: <br />EUH204 Contains isocyanates. May produce an allergic reaction. <br />· 2.3 Other hazards <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />*</p> <p>SECTION 3: Composition/information on ingredients <br />· 3.2 Chemical characterisation: Mixtures <br />· Description: Preparation based on Diphenylmethan-Diisocyanat-Prepolymers. (MDI) <br />· Dangerous components: <br />CAS: 9016-87-9 <br />diphenylmethanediisocyanate,isomeres and homologues <br />50-100% <br />Index number: 615-005-00-9 <br />Resp. Sens. 1, H334; Carc. 2, H351; STOT RE 2, H373; <br />Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; <br />Skin Sens. 1, H317; STOT SE 3, H335 <br />Specific concentration limits: Eye Irrit. 2; H319: C ≥ 5 % <br />Skin Irrit. 2; H315: C ≥ 5 % <br />Resp. Sens. 1; H334: C ≥ 0.1 % <br />STOT SE 3; C ≥ 5 % <br />CAS: 78-40-0 <br />triethyl phosphate <br />EINECS: 201-114-5 <br />Acute Tox. 4, H302 <br />Index number: 015-013-00-7 <br />· Additional information For the wording of the listed hazard phrases refer to section 16.</p> <p>*</p> <p>10-25%</p> <p>SECTION 4: First aid measures <br />· 4.1 Description of first aid measures <br />· General information <br />Symptoms of poisoning may even occur after several hours; therefore medical observation for at <br />least 48 hours after the accident. <br />Personal protection for the First Aider. <br />Do not leave affected persons unsupervised. <br />Instantly remove any clothing soiled by the product. <br />· After inhalation <br />Supply fresh air or oxygen; call for doctor. <br />In case of cardiac- or breath arrest: artificial respiration and cardiac massage. <br />Use a respiration bag or breathing device. <br />· After skin contact <br />Instantly wash with water and soap and rinse thoroughly. <br />Change immediately contaminated clothes. <br />If symptoms appearance, call the doctor. <br />(Contd. on page 3) <br />GB</p> <p>54.0</p> <p>Page 3/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 01.02.2022</p> <p>Version number 14</p> <p>Revision: 01.02.2022</p> <p>Trade name: AQUAFIN-P1 <br />(Contd. of page 2)</p> <p>· After eye contact <br />Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. <br />· After swallowing <br />Do not induce vomiting; instantly call for medical help. <br />Show the packaging or the label to the doctor. <br />· 4.2 Most important symptoms and effects, both acute and delayed <br />Allergic reactions <br />Asthma attacks <br />Irritation of skin, eyes and respiratory organ. <br />· 4.3 Indication of any immediate medical attention and special treatment needed <br />The symptoms are to be treated. <br />*</p> <p>SECTION 5: Firefighting measures <br />· 5.1 Extinguishing media <br />· Suitable extinguishing agents <br />CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. <br />Use fire fighting measures that suit the environment. <br />· 5.2 Special hazards arising from the substance or mixture <br />Formation of toxic gases is possible during heating or in case of fire. <br />· 5.3 Advice for firefighters <br />· Protective equipment: <br />Wear self-contained breathing apparatus. <br />Wear full protective suit. <br />· Additional information <br />Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. <br />Follow the emergency-plan.</p> <p>*</p> <p>SECTION 6: Accidental release measures <br />· 6.1 Personal precautions, protective equipment and emergency procedures <br />Wear protective equipment. Keep unprotected persons away. <br />Ensure adequate ventilation <br />· 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. <br />· 6.3 Methods and material for containment and cleaning up: <br />Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). <br />· 6.4 Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />See Section 13 for information on disposal.</p> <p>*</p> <p>SECTION 7: Handling and storage <br />· 7.1 Precautions for safe handling <br />Ensure good ventilation/exhaustion at the workplace. <br />Prevent formation of aerosols. <br />Keep away from children. <br />· Information about protection against explosions and fires: Keep breathing equipment ready. <br />· 7.2 Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: <br />Store only in the original container. <br />The Product reacts with water and CO2-Gas will be given off. <br />In tight closed containers pressure may arise and the cover can burst. <br />· Information about storage in one common storage facility: <br />Please follow the rules of the VCI-Storage-Concept for chemicals. <br />(Contd. on page 4) <br />GB</p> <p>54.0</p> <p>Page 4/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 01.02.2022</p> <p>Version number 14</p> <p>Revision: 01.02.2022</p> <p>Trade name: AQUAFIN-P1 <br />(Contd. of page 3)</p> <p>· Further information about storage conditions: <br />Store under dry conditions. <br />Store container in a well ventilated position. <br />Keep container tightly sealed. <br />Store in a locked cabinet and out of the reach of children. <br />· 7.3 Specific end use(s) No further relevant information available. <br />*</p> <p>SECTION 8: Exposure controls/personal protection <br />· 8.1 Control parameters <br />· Additional information about design of technical systems: <br />It must be possible to wash the skin in the working area. <br />Eye-wash bottle must be available. <br />· Components with critical values that require monitoring at the workplace: <br />9016-87-9 diphenylmethanediisocyanate,isomeres and homologues (50-100%) <br />WEL Short-term value: 0.07 mg/m³ <br />Long-term value: 0.02 mg/m³ <br />Sen; as -NCO <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· 8.2 Exposure controls <br />· Personal protective equipment <br />· General protective and hygienic measures <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />Instantly remove any soiled and impregnated garments. <br />Avoid contact with the eyes and skin. <br />Be sure to clean skin thoroughly after work and before breaks. <br />When the material is hardened on the skin, remove it carfully mechanically. <br />· Breathing equipment: <br />In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer <br />exposure use breathing apparatus that is independent of circulating air. <br />Recommended Filter type A <br />· Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. <br />· Material of gloves <br />Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Penetration time 480 min <br />The selection of the suitable gloves does not only depend on the material, but also on further marks <br />of quality and varies from manufacturer to manufacturer. As the product is a preparation of several <br />substances, the resistance of the glove material can not be calculated in advance and has therefore <br />to be checked prior to the application. <br />· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and <br />has to be observed. <br />· Eye protection: Tightly sealed safety glasses. <br />· Body protection: Protective work clothing.</p> <p>*</p> <p>SECTION 9: Physical and chemical properties <br />· 9.1 Information on basic physical and chemical properties <br />· General Information <br />· Appearance: <br />Form: <br />Fluid <br />Colour: <br />Brown <br />· Smell: <br />Characteristic <br />· Odour threshold: <br />Not determined. <br />· pH-value:</p> <p>Mixture is non-soluble (in water). <br />(Contd. on page 5) <br />GB</p> <p>54.0</p> <p>Page 5/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 01.02.2022</p> <p>Version number 14</p> <p>Revision: 01.02.2022</p> <p>Trade name: AQUAFIN-P1 <br />(Contd. of page 4)</p> <p>· Change in condition <br />Melting point/freezing point: <br />Not determined <br />Initial boiling point and boiling range: >260 °C</p> <p>*</p> <p>· Flash point:</p> <p>200 °C</p> <p>· Inflammability (solid, gaseous)</p> <p>Not applicable.</p> <p>· Decomposition temperature:</p> <p>Not determined.</p> <p>· Self-inflammability:</p> <p>Product is not selfigniting.</p> <p>· Explosive properties:</p> <p>Product is not explosive.</p> <p>· Critical values for explosion: <br />Lower: <br />Upper:</p> <p>Not determined. <br />Not determined.</p> <p>· Steam pressure at 20 °C:</p> <p><5 hPa</p> <p>· Density at 20 °C <br />· Relative density <br />· Vapour density <br />· Evaporation rate</p> <p>1.14 g/cm³ <br />Not determined. <br />Not determined. <br />Not determined.</p> <p>· Solubility in / Miscibility with <br />Water:</p> <p>Not miscible or difficult to mix</p> <p>· Partition coefficient: n-octanol/water:</p> <p>Not determined.</p> <p>· Viscosity: <br />dynamic at 20 °C: <br />kinematic:</p> <p>230 mPas <br />Not determined.</p> <p>· 9.2 Other information</p> <p>No further relevant information available.</p> <p>SECTION 10: Stability and reactivity <br />· 10.1 Reactivity No further relevant information available. <br />· 10.2 Chemical stability <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· 10.3 Possibility of hazardous reactions No dangerous reactions known <br />· 10.4 Conditions to avoid No further relevant information available. <br />· 10.5 Incompatible materials: <br />Acids <br />Water <br />Alkalis <br />Amine <br />Alkoholes <br />· 10.6 Hazardous decomposition products: No dangerous decomposition products known</p> <p>*</p> <p>SECTION 11: Toxicological information <br />· 11.1 Information on toxicological effects <br />· Acute toxicity <br />Harmful if inhaled. <br />· LD/LC50 values that are relevant for classification: <br />9016-87-9 diphenylmethanediisocyanate,isomeres and homologues <br />Oral <br />LD50 <br />>10,000 mg/kg (rats) (OECD 401) <br />(Contd. on page 6) <br />GB</p> <p>54.0</p> <p>Page 6/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 01.02.2022</p> <p>Version number 14</p> <p>Revision: 01.02.2022</p> <p>Trade name: AQUAFIN-P1 <br />(Contd. of page 5)</p> <p>Dermal</p> <p>LD50</p> <p>>9,400 mg/kg (rabbit) (OECD 402)</p> <p>78-40-0 triethyl phosphate <br />Oral <br />LD50 <br />800 mg/kg (rats) <br />Dermal LD50 <br />20,000 mg/kg (Kan) <br />Inhalative LC50/4 h 8,817 mg/l (rats) <br />· Primary irritant effect: <br />· Skin corrosion/irritation <br />The product has an irritate-effect. <br />Causes skin irritation. <br />· Serious eye damage/irritation <br />Causes serious eye irritation. <br />· Respiratory or skin sensitisation <br />May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />May cause an allergic skin reaction. <br />· Additional toxicological information: <br />· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) <br />· Germ cell mutagenicity Based on available data, the classification criteria are not met. <br />· Carcinogenicity <br />Suspected of causing cancer. <br />· Reproductive toxicity Based on available data, the classification criteria are not met. <br />· STOT-single exposure <br />May cause respiratory irritation. <br />· STOT-repeated exposure <br />May cause damage to organs through prolonged or repeated exposure. <br />· Aspiration hazard Based on available data, the classification criteria are not met. <br />*</p> <p>SECTION 12: Ecological information <br />· 12.1 Toxicity <br />· Aquatic toxicity: <br />LC50/96h >1,000 mg/l (Leuciscus idus) <br />EC50 (48h) >1,000 mg/l (Daphnia magna) <br />IC50 <br />>1,000 mg/l /72h (Scenedesmus subspicatus) <br />9016-87-9 diphenylmethanediisocyanate,isomeres and homologues <br />EC 50 <br />>1,000 mg/kg (dam) (OECD 202 (24 h)) <br />>1,640 mg/kg (Grünalge (Scenedesmus subspicatus)) (OECD 201) <br />LC50/96h >1,000 mg/l (zebra danio) (OECD 203) <br />EC50 (3h) >100 mg/l (Atmungshem. von kommunalem Belebtschlamm) (OECD 209) <br />ERC50 <br />>1,640 mg/l (Grünalge (Scenedesmus subspicatus)) (OECD 201 (72 h)) <br />NOEC <br />>1,000 mg/kg (Avena sativa) (OECD 208 (14 d)) <br />>1,000 mg/kg (Eisenia fetida) (OECD 207 (14 d)) <br />>1,000 mg/kg (Lactuca sativa) (OECD 208 (14 d)) <br />NOEC <br />>10 mg/l (dam) (OECD 202 (21 d)) <br />· 12.2 Persistence and degradability No further relevant information available. <br />· 12.3 Bioaccumulative potential No further relevant information available. <br />· 12.4 Mobility in soil No further relevant information available. <br />· Additional ecological information: <br />· General notes: <br />Water hazard class 1 (Self-assessment): slightly hazardous for water. <br />Do not allow undiluted product or large quantities of it to reach ground water, water bodies or <br />sewage system. <br />· 12.5 Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />(Contd. on page 7) <br />GB</p> <p>54.0</p> <p>Page 7/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 01.02.2022</p> <p>Version number 14</p> <p>Revision: 01.02.2022</p> <p>Trade name: AQUAFIN-P1 <br />(Contd. of page 6)</p> <p>· vPvB: Not applicable. <br />· 12.6 Other adverse effects No further relevant information available. <br />*</p> <p>SECTION 13: Disposal considerations <br />· 13.1 Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />· Uncleaned packagings: <br />· Recommendation: Disposal must be made according to official regulations. <br />SECTION 14: Transport information <br />· 14.1 UN-Number <br />· ADR, ADN, IMDG, IATA</p> <p>Void</p> <p>· 14.2 UN proper shipping name <br />· ADR, ADN, IMDG, IATA</p> <p>Void</p> <p>· 14.3 Transport hazard class(es) <br />· ADR, ADN, IMDG, IATA <br />· Class</p> <p>Void</p> <p>· 14.4 Packing group <br />· ADR, IMDG, IATA</p> <p>Void</p> <p>· 14.5 Environmental hazards: <br />· Marine pollutant:</p> <p>No</p> <p>· 14.6 Special precautions for user</p> <p>Not applicable.</p> <p>· 14.7 Transport in bulk according to Annex II <br />of Marpol and the IBC Code <br />Not applicable. <br />· UN "Model Regulation":</p> <p>*</p> <p>Void</p> <p>SECTION 15: Regulatory information <br />· 15.1 Safety, health and environmental regulations/legislation specific for the substance or <br />mixture <br />· Directive 2012/18/EU <br />· Named dangerous substances - ANNEX I None of the ingredients is listed. <br />· National regulations <br />· Technical instructions (air): <br />· Class Share in % <br />· I <br />75.0 <br />NK <br />21.0 <br />· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.</p> <p>*</p> <p>SECTION 16: Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for <br />any specific product features and shall not establish a legally valid contractual relationship. <br />(Contd. on page 8) <br />GB</p> <p>54.0</p> <p>Page 8/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 01.02.2022</p> <p>Version number 14</p> <p>Revision: 01.02.2022</p> <p>Trade name: AQUAFIN-P1 <br />(Contd. of page 7)</p> <p>· Relevant phrases <br />H302 Harmful if swallowed. <br />H315 Causes skin irritation. <br />H317 May cause an allergic skin reaction. <br />H319 Causes serious eye irritation. <br />H332 Harmful if inhaled. <br />H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />H335 May cause respiratory irritation. <br />H351 Suspected of causing cancer. <br />H373 May cause damage to organs through prolonged or repeated exposure. <br />· Department issuing data specification sheet: Environment protection department. <br />· Contact: Environment protection department. <br />· Abbreviations and acronyms: <br />ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning <br />the International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />GHS: Globally Harmonised System of Classification and Labelling of Chemicals <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />PBT: Persistent, Bioaccumulative and Toxic <br />vPvB: very Persistent and very Bioaccumulative <br />Acute Tox. 4: Acute toxicity – Category 4 <br />Skin Irrit. 2: Skin corrosion/irritation – Category 2 <br />Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 <br />Resp. Sens. 1: Respiratory sensitisation – Category 1 <br />Skin Sens. 1: Skin sensitisation – Category 1 <br />Carc. 2: Carcinogenicity – Category 2 <br />STOT SE 3: Specific target organ toxicity (single exposure) – Category 3 <br />STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2</p> <p>· * Data compared to the previous version altered. <br />GB</p>
