AG70_(14)EN.pdf
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<h1>AG70_(14)EN.pdf</h1> <p>42.0</p> <p>Page 1/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 28.04.2016 <br />*</p> <p>Version number 14</p> <p>Revision: 28.04.2016</p> <p>SECTION 1: Identification of the substance/mixture and of the company/undertaking <br />· 1.1 Product identifier <br />· Trade name: AG 70 <br />· Article number: 205731 <br />· 1.2 Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture Primer/ Subcoating <br />· 1.3 Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH & Co. KG <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />Fax: ++49 (0)5231/953-123 <br />email: info@schomburg.de <br />web: www.schomburg.de <br />· Informing department: <br />Product Safety Department <br />Tel: ++49 (0)5231/953-193 <br />Fax: ++49 (0)5231/953-106 <br />email: guido.herfort@schomburg.de</p> <p>*</p> <p>SECTION 2: Hazards identification <br />· 2.1 Classification of the substance or mixture <br />· Classification according to Regulation (EC) No 1272/2008 <br />GHS02 flame <br />Flam. Liq. 2</p> <p>H225 Highly flammable liquid and vapour.</p> <p>GHS08 health hazard <br />Repr. 2 <br />Asp. Tox. 1</p> <p>H361d Suspected of damaging the unborn child. <br />H304 May be fatal if swallowed and enters airways.</p> <p>GHS05 corrosion <br />Eye Dam. 1</p> <p>H318 Causes serious eye damage.</p> <p>GHS09 environment <br />Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. <br />GHS07 <br />Skin Irrit. 2</p> <p>H315 Causes skin irritation. <br />(Contd. on page 2) <br />GB</p> <p>42.0</p> <p>Page 2/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 28.04.2016</p> <p>Version number 14</p> <p>Revision: 28.04.2016</p> <p>Trade name: AG 70 <br />(Contd. of page 1)</p> <p>STOT SE 3</p> <p>H336 May cause drowsiness or dizziness.</p> <p>· 2.2 Label elements <br />· Labelling according to Regulation (EC) No 1272/2008 <br />The product is classified and labelled according to the CLP regulation. <br />· Hazard pictograms GHS02, GHS05, GHS07, GHS08, GHS09 <br />· Signal word Danger <br />· Hazard-determining components of labelling: <br />Isoalkane C7-C10 <br />toluene <br />Butyltitanat(IV) <br />· Hazard statements <br />H225 Highly flammable liquid and vapour. <br />H315 Causes skin irritation. <br />H318 Causes serious eye damage. <br />H361d Suspected of damaging the unborn child. <br />H336 May cause drowsiness or dizziness. <br />H304 May be fatal if swallowed and enters airways. <br />H411 Toxic to aquatic life with long lasting effects. <br />· Precautionary statements <br />P210 <br />Keep away from heat, hot surfaces, sparks, open flames and other ignition <br />sources. No smoking. <br />P280 <br />Wear protective gloves/protective clothing/eye protection/face protection. <br />P301+P310 <br />IF SWALLOWED: Immediately call a POISON CENTER/ doctor. <br />P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact <br />lenses, if present and easy to do. Continue rinsing. <br />P405 <br />Store locked up. <br />P501 <br />Dispose of contents/container in accordance with local/regional/national/ <br />international regulations. <br />· 2.3 Other hazards <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />*</p> <p>SECTION 3: Composition/information on ingredients <br />· 3.2 Chemical characterisation: Mixtures <br />· Description: Solvent mixture with additives. <br />· Dangerous components: <br />CAS: 90622-56-3 Isoalkane C7-C10 <br />Flam. Liq. 1, H224; <br />Asp. Tox. 1, H304; <br />Aquatic Chronic 2, <br />H411; <br />Skin Irrit. 2, H315; STOT SE 3, H336 <br />CAS: 5593-70-4 <br />Butyltitanat(IV) <br />EINECS: 227-006-8 <br />Flam. Liq. 3, H226;</p> <p>50-100%</p> <p>2,5-10% <br />Skin Irrit. 2, H315; Eye Irrit. 2, H319</p> <p>CAS: 108-88-3 <br />toluene <br />EINECS: 203-625-9 <br />Flam. Liq. 2, H225; <br />Repr. 2, H361d; STOT RE 2, H373; Asp. <br />Tox. 1, H304; <br />Skin Irrit. 2, H315; STOT SE 3, H336</p> <p>2,5-10%</p> <p>CAS: 78-10-4 <br />tetraethyl orthosilicate <br />EINECS: 201-083-8 <br />Flam. Liq. 3, H226; <br />SE 3, H335</p> <p>< 2,5% <br />Acute Tox. 4, H332; Eye Irrit. 2, H319; STOT <br />GB</p> <p>(Contd. on page 3)</p> <p>42.0</p> <p>Page 3/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 28.04.2016</p> <p>Version number 14</p> <p>Revision: 28.04.2016</p> <p>Trade name: AG 70 <br />(Contd. of page 2)</p> <p>SECTION 4: First aid measures <br />· 4.1 Description of first aid measures <br />· General information <br />Personal protection for the First Aider. <br />It is possible to choke in case of vomiting in unconsciousness. <br />Bring unconscious persons into a stable position on side. <br />Keep the respiratory tract free (remove dentures and vomiting). <br />Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage <br />of breathing: artificial respiration. <br />Take up a doctor immediately! <br />· After skin contact Instantly wash with water and soap and rinse thoroughly. <br />· After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. <br />· After swallowing Drink copious amounts of water. Avert vomiting. Instantly call for doctor. <br />· 4.2 Most important symptoms and effects, both acute and delayed <br />No further relevant information available. <br />· 4.3 Indication of any immediate medical attention and special treatment needed <br />No further relevant information available. <br />*</p> <p>SECTION 5: Firefighting measures <br />· 5.1 Extinguishing media <br />· Suitable extinguishing agents <br />CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. <br />· For safety reasons unsuitable extinguishing agents Water with a full water jet. <br />· 5.2 Special hazards arising from the substance or mixture <br />No further relevant information available. <br />· 5.3 Advice for firefighters <br />· Protective equipment: Put on breathing apparatus.</p> <p>*</p> <p>SECTION 6: Accidental release measures <br />· 6.1 Personal precautions, protective equipment and emergency procedures <br />Wear protective equipment. Keep unprotected persons away. <br />Avoid eye- and skin contact. <br />· 6.2 Environmental precautions: Prevent material from reaching sewage system, holes and cellars. <br />· 6.3 Methods and material for containment and cleaning up: <br />Absorb with liquid-binding, inflammable material (sand, diatomite, acid binders, universal binder). <br />Ensure adequate ventilation. <br />· 6.4 Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />See Section 13 for information on disposal. <br />SECTION 7: Handling and storage <br />· 7.1 Precautions for safe handling <br />Ensure good ventilation/exhaustion at the workplace. <br />Keep away from heat and direct sunlight. <br />Handle with care. Avoid jolting, friction and impact. <br />Do not keep food in the area of work. <br />Do not store open containers. <br />Do not smoke. <br />Keep away from children. <br />Work with fresh air supply, keep doors and windows open. <br />Prevent formation of aerosols. <br />(Contd. on page 4) <br />GB</p> <p>42.0</p> <p>Page 4/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 28.04.2016</p> <p>Version number 14</p> <p>Revision: 28.04.2016</p> <p>Trade name: AG 70 <br />(Contd. of page 3)</p> <p>· Information about protection against explosions and fires: <br />Keep ignition sources away - Do not smoke. <br />Protect against electrostatic charges. <br />· 7.2 Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: Store in cool location. <br />· Information about storage in one common storage facility: <br />Please follow the rules of the VCI-Storage-Concept for chemicals. <br />· Further information about storage conditions: <br />Keep container tightly sealed. <br />Protect from heat and direct sunlight. <br />· 7.3 Specific end use(s) No further relevant information available. <br />*</p> <p>SECTION 8: Exposure controls/personal protection <br />· Additional information about design of technical systems: <br />It must be possible to wash the skin in the working area. <br />Eye-wash bottle must be available. <br />· 8.1 Control parameters <br />· Components with critical values that require monitoring at the workplace: <br />108-88-3 toluene (2.5-10%) <br />WEL Short-term value: 384 mg/m³, 100 ppm <br />Long-term value: 191 mg/m³, 50 ppm <br />Sk <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· 8.2 Exposure controls <br />· Personal protective equipment <br />· General protective and hygienic measures <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />Wash hands during breaks and at the end of the work. <br />Avoid contact with the eyes and skin. <br />Be sure to clean skin thoroughly after work and before breaks. <br />Do not carry cleaning cloths impregnated with the product in trouser pockets. <br />· Breathing equipment: <br />In not so good ventilated space the filter combination A2B2E2K1HgP3RD is to be used. <br />· Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. <br />· Material of gloves <br />Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min <br />· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and <br />has to be observed. <br />· Eye protection: Safety glasses <br />· Body protection: Protective work clothing.</p> <p>*</p> <p>SECTION 9: Physical and chemical properties <br />· 9.1 Information on basic physical and chemical properties <br />· General Information <br />· Appearance: <br />Form: <br />Fluid <br />Colour: <br />Light yellow <br />· Smell: <br />Weak, characteristic <br />(Contd. on page 5) <br />GB</p> <p>42.0</p> <p>Page 5/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 28.04.2016</p> <p>Version number 14</p> <p>Revision: 28.04.2016</p> <p>Trade name: AG 70 <br />(Contd. of page 4)</p> <p>· pH-value at 20 °C:</p> <p>7</p> <p>· Change in condition <br />Melting point/Melting range: Not determined <br />Boiling point/Boiling range: 116 °C <br />· Flash point:</p> <p>3 °C</p> <p>· Ignition temperature:</p> <p>370 °C</p> <p>· Self-inflammability:</p> <p>Product is not selfigniting.</p> <p>· Danger of explosion:</p> <p>Product is not explosive. However, formation of explosive air/ <br />steam mixtures is possible.</p> <p>· Critical values for explosion: <br />Lower: <br />0.9 % (V) <br />Upper: <br />7 % (V) <br />· Density at 20 °C</p> <p>0,76 g/cm³</p> <p>· Solubility in / Miscibility with <br />Water: <br />Not miscible or difficult to mix <br />· 9.2 Other information <br />No further relevant information available.</p> <p>SECTION 10: Stability and reactivity <br />· 10.1 Reactivity No further relevant information available. <br />· 10.2 Chemical stability <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· 10.3 Possibility of hazardous reactions No dangerous reactions known <br />· 10.4 Conditions to avoid No further relevant information available. <br />· 10.5 Incompatible materials: No further relevant information available. <br />· 10.6 Hazardous decomposition products: No dangerous decomposition products known <br />*</p> <p>SECTION 11: Toxicological information <br />· 11.1 Information on toxicological effects <br />· Acute toxicity Based on available data, the classification criteria are not met. <br />· LD/LC50 values that are relevant for classification: <br />90622-56-3 Isoalkane C7-C10 <br />Oral <br />LD50 <br />>10000 mg/kg (rats) <br />Dermal LD50 <br />>3000 mg/kg (rats) <br />Inhalative LC50/4 h 21 mg/l (rats) <br />108-88-3 toluene <br />Oral <br />LD50 <br />5000 mg/kg (rats) <br />Dermal LD50 <br />12300 mg/kg (rabbit) <br />Inhalative LC50/4 h 19 mg/l (rats) <br />LC50 <br />(8h) 5320 ppm (Maus) <br />78-10-4 tetraethyl orthosilicate <br />Oral <br />LD50 <br />6270 mg/kg (rats) <br />Dermal LD50 <br />5878 mg/kg (rabbit) <br />Inhalative LCLo <br />1000 ppm/4h (rats) <br />(Contd. on page 6) <br />GB</p> <p>42.0</p> <p>Page 6/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 28.04.2016</p> <p>Version number 14</p> <p>Revision: 28.04.2016</p> <p>Trade name: AG 70 <br />(Contd. of page 5)</p> <p>· Primary irritant effect: <br />· Skin corrosion/irritation <br />It is possible to irritate the skin. <br />Causes skin irritation. <br />· Serious eye damage/irritation <br />Light irritate-effect is possible. <br />Causes serious eye damage. <br />· Respiratory or skin sensitisation Based on available data, the classification criteria are not met. <br />· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) <br />· Germ cell mutagenicity Based on available data, the classification criteria are not met. <br />· Carcinogenicity Based on available data, the classification criteria are not met. <br />· Reproductive toxicity <br />Suspected of damaging the unborn child. <br />· STOT-single exposure <br />May cause drowsiness or dizziness. <br />· STOT-repeated exposure Based on available data, the classification criteria are not met. <br />· Aspiration hazard <br />May be fatal if swallowed and enters airways. <br />*</p> <p>SECTION 12: Ecological information <br />· 12.1 Toxicity <br />· Aquatic toxicity: <br />108-88-3 toluene <br />LC50/96h 1-10 mg/l (fish toxicity) <br />· 12.2 Persistence and degradability No further relevant information available. <br />· 12.3 Bioaccumulative potential No further relevant information available. <br />· 12.4 Mobility in soil No further relevant information available. <br />· Ecotoxical effects: <br />108-88-3 toluene <br />EC 50 6mg/l/48h mg/l (Daphnia magna) <br />· Additional ecological information: <br />· General notes: <br />Water hazard class 2 (Self-assessment): hazardous for water. <br />Do not allow product to reach ground water, water bodies or sewage system. <br />· 12.5 Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />· 12.6 Other adverse effects No further relevant information available. <br />SECTION 13: Disposal considerations <br />· 13.1 Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />· European waste catalogue <br />07 00 00 Wastes from organic chemical processes <br />07 01 00 waste from the manufacture, formulation, supply and use (MFSU) of basic organic <br />chemicals <br />07 01 04 other organic solvents, washing liquids and mother liquors <br />· Uncleaned packagings: <br />· Recommendation: Disposal must be made according to official regulations. <br />(Contd. on page 7) <br />GB</p> <p>42.0</p> <p>Page 7/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 28.04.2016</p> <p>Version number 14</p> <p>Revision: 28.04.2016</p> <p>Trade name: AG 70 <br />(Contd. of page 6)</p> <p>· Recommended cleaning agent: Water, if necessary with cleaning agent. <br />*</p> <p>SECTION 14: Transport information <br />· 14.1 UN-Number <br />· ADR, IMDG, IATA <br />· 14.2 UN proper shipping name <br />· ADR <br />· IMDG, IATA</p> <p>UN1993 <br />1993 FLAMMABLE LIQUID, N.O.S. (Isoalkane C7C10, TOLUENE), ENVIRONMENTALLY <br />HAZARDOUS, special provision 640D <br />FLAMMABLE LIQUID, N.O.S. (Isoalkane C7-C10, <br />TOLUENE)</p> <p>· 14.3 Transport hazard class(es) <br />· ADR</p> <p>· Class <br />· Label</p> <p>3 Flammable liquids. <br />3</p> <p>· IMDG, IATA</p> <p>· Class <br />· Label</p> <p>3 Flammable liquids. <br />3</p> <p>· 14.4 Packing group <br />· ADR, IMDG, IATA</p> <p>II</p> <p>· 14.5 Environmental hazards: <br />· Marine pollutant: <br />· Special marking (ADR):</p> <p>No <br />Symbol (fish and tree)</p> <p>· 14.6 Special precautions for user <br />· Kemler Number: <br />· EMS Number:</p> <p>Warning: Flammable liquids. <br />33 <br />F-E,S-E</p> <p>· 14.7 Transport in bulk according to Annex II <br />of Marpol and the IBC Code <br />Not applicable. <br />· Transport/Additional information: <br />· ADR <br />· Limited quantities (LQ) <br />· Transport category <br />· Tunnel restriction code <br />· UN "Model Regulation":</p> <p>Not dangerous according to the above <br />specifications. <br />1L <br />2 <br />D/E <br />UN1993, FLAMMABLE LIQUID, N.O.S. (Isoalkane <br />C7-C10, TOLUENE), special provision 640D, <br />ENVIRONMENTALLY HAZARDOUS, 3, II <br />GB</p> <p>(Contd. on page 8)</p> <p>42.0</p> <p>Page 8/8</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 28.04.2016</p> <p>Version number 14</p> <p>Revision: 28.04.2016</p> <p>Trade name: AG 70 <br />(Contd. of page 7)</p> <p>*</p> <p>SECTION 15: Regulatory information <br />· 15.1 Safety, health and environmental regulations/legislation specific for the substance or <br />mixture <br />· National regulations <br />· Technical instructions (air): <br />· Class Share in % <br />· II <br />4.9 <br />· Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. <br />· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. <br />SECTION 16: Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for <br />any specific product features and shall not establish a legally valid contractual relationship. <br />· Relevant phrases <br />H224 Extremely flammable liquid and vapour. <br />H225 Highly flammable liquid and vapour. <br />H226 Flammable liquid and vapour. <br />H304 May be fatal if swallowed and enters airways. <br />H315 Causes skin irritation. <br />H319 Causes serious eye irritation. <br />H332 Harmful if inhaled. <br />H335 May cause respiratory irritation. <br />H336 May cause drowsiness or dizziness. <br />H361d Suspected of damaging the unborn child. <br />H373 May cause damage to organs through prolonged or repeated exposure. <br />H411 Toxic to aquatic life with long lasting effects. <br />· Department issuing data specification sheet: Environment protection department. <br />· Contact: Mr. Guido Herfort <br />· Abbreviations and acronyms: <br />ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the <br />International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />GHS: Globally Harmonised System of Classification and Labelling of Chemicals <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />PBT: Persistent, Bioaccumulative and Toxic <br />vPvB: very Persistent and very Bioaccumulative <br />Flam. Liq. 1: Flammable liquids, Hazard Category 1 <br />Flam. Liq. 2: Flammable liquids, Hazard Category 2 <br />Flam. Liq. 3: Flammable liquids, Hazard Category 3 <br />Acute Tox. 4: Acute toxicity, Hazard Category 4 <br />Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 <br />Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1 <br />Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 <br />Repr. 2: Reproductive toxicity, Hazard Category 2 <br />STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 <br />STOT RE 2: Specific target organ toxicity - Repeated exposure, Hazard Category 2 <br />Asp. Tox. 1: Aspiration hazard, Hazard Category 1 <br />Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2</p> <p>· * Data compared to the previous version altered. <br />GB</p>
