SDS_ASO-EZ4_-_205527_(8)RU_EN.pdf
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<h1>SDS_ASO-EZ4_-_205527_(8)RU_EN.pdf</h1> <p>61.0.34</p> <p>Page 1/9</p> <p>Safety data sheet <br />According to 91/155 EEC <br />Date of issue: 05.12.2025</p> <p>Version number 8</p> <p>Revision: 05.12.2025</p> <p>1 Identification of the substance/mixture and of the company/undertaking <br />· Other means of identification <br />· Trade name: ASO-EZ4 <br />· Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture Binder <br />· Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH & Co. KG <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Detmold, Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />Fax: ++49 (0)5231/953-123 <br />Internet: www.schomburg.de <br />· Informing department: <br />Department: Environment and Safety <br />************************************ <br />If you have any questions about the Environment and Safety Department, please contact our <br />department. <br />e-mail: SDB@schomburg.de <br />· Emergency telephone number: <br />Poison centre Berlin (24 hours) <br />German & English <br />Tel: ++49 (0)30/30686700 <br />2 Hazards identification <br />· Classification of the substance or mixture <br />GHS05 corrosion <br />Eye Dam. 1 H318 Causes serious eye damage. <br />GHS07 <br />Skin Irrit. 2 H315 Causes skin irritation. <br />Skin Sens. 1 H317 May cause an allergic skin reaction. <br />STOT SE 3 H335 May cause respiratory irritation. <br />Acute Tox. 5 H333 May be harmful if inhaled. <br />· Label elements <br />· GHS label elements <br />The product is classified and labelled according to the Globally Harmonised System (GHS). <br />· Hazard pictograms GHS05, GHS07 <br />· Signal word Danger <br />(Contd. on page 2) <br />RU</p> <p>61.0.34</p> <p>Page 2/9</p> <p>Safety data sheet <br />According to 91/155 EEC <br />Date of issue: 05.12.2025</p> <p>Version number 8</p> <p>Revision: 05.12.2025</p> <p>Trade name: ASO-EZ4 <br />(Contd. of page 1)</p> <p>· Hazard-determining components of labelling: <br />Cement, portland, chemicals <br />Flue dust, portland cement <br />· Hazard statements <br />May be harmful if inhaled. <br />Causes skin irritation. <br />Causes serious eye damage. <br />May cause an allergic skin reaction. <br />May cause respiratory irritation. <br />· Precautionary statements <br />Avoid breathing dust/fume/gas/mist/vapours/spray. <br />Wear protective gloves / eye protection / face protection. <br />IF INHALED: Call a POISON CENTER/doctor if you feel unwell. <br />IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and <br />easy to do. Continue rinsing. <br />Store locked up. <br />Dispose of contents/container in accordance with local/regional/national/international regulations. <br />· Other hazards <br />With moisture, the dry product forms a highly alkaline solution that can irritate the skin and eyes. <br />Prolonged contact with the moist mortar can cause serious eye and skin damage. <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />3 Composition/information on ingredients <br />· Chemical characterisation: Mixtures <br />· Description: Product based on cement and mineral filler. <br />· Dangerous components: <br />CAS: 65997-15-1 Cement, portland, chemicals <br />EINECS: 266-043-4 <br />Eye Dam. 1, H318; <br />Skin Irrit. 2, H315; STOT SE 3, H335</p> <p>50-100%</p> <p>CAS: 65997-16-2 alumina cement clinker <br />EINECS: 266-045-5 Acute Tox. 5, H303</p> <p>2,5-10%</p> <p>CAS: 91051-01-3 Fatty acids, C16-18, zinc salts <br />EINECS: 293-049-4 Acute Tox. 5, H313; Acute Tox. 5, H333</p> <p><2,5%</p> <p>CAS: 68475-76-3 Flue dust, portland cement <br /><0,5% <br />EINECS: 270-659-9 <br />Eye Dam. 1, H318; <br />Skin Irrit. 2, H315; Skin Sens. 1, H317; <br />STOT SE 3, H335; Acute Tox. 5, H313; Acute Tox. 5, H333 <br />· Additional information <br />The chromate content in the cement is less than 2 ppm, so that the classification with H317 or <br />EUH203 is not applicable (see 1907/2006/EC, Annex XVII (47)). <br />For the wording of the listed hazard phrases refer to section 16. <br />4 First aid measures <br />· General information <br />Symptoms of poisoning may even occur after several hours; therefore medical observation for at <br />least 48 hours after the accident. <br />Personal protection for the First Aider. <br />It is possible to choke in case of vomiting in unconsciousness. <br />Bring unconscious persons into a stable position on side. <br />Keep the respiratory tract free (remove dentures and vomiting). <br />Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage <br />of breathing: artificial respiration. <br />Take up a doctor immediately! <br />(Contd. on page 3) <br />RU</p> <p>61.0.34</p> <p>Page 3/9</p> <p>Safety data sheet <br />According to 91/155 EEC <br />Date of issue: 05.12.2025</p> <p>Version number 8</p> <p>Revision: 05.12.2025</p> <p>Trade name: ASO-EZ4 <br />(Contd. of page 2)</p> <p>· After inhalation Supply fresh air or oxygen; call for doctor. <br />· After skin contact <br />In case of contact with skin, remove mechanically, wash thoroughly with plenty of soap and water. <br />Instantly wash with water and soap and rinse thoroughly. <br />Don't use solvents to clean the skin. <br />· After eye contact <br />Gently rinse the eyes under running water for at least 10 minutes with the eyelids open. If possible, <br />remove any contact lenses and continue rinsing. Consult a doctor. <br />· After swallowing <br />Show the packaging or the label to the doctor. <br />Drink copious amounts of water. Avert vomiting. Instantly call for doctor. <br />· Information for doctor <br />· Most important symptoms and effects, both acute and delayed <br />No further relevant information available. <br />· Indication of any immediate medical attention and special treatment needed <br />No further relevant information available. <br />5 Firefighting measures <br />· Suitable extinguishing agents <br />Product is not inflammable. <br />Use fire fighting measures that suit the environment. <br />· Special hazards arising from the substance or mixture No further relevant information available. <br />· Protective equipment: Wear self-contained breathing apparatus. <br />· Additional information <br />Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. <br />Follow the emergency-plan. <br />6 Accidental release measures <br />· Personal precautions, protective equipment and emergency procedures <br />Avoid causing dust. <br />Bring persons out of danger. <br />Wear protective equipment. Keep unprotected persons away. <br />Wear protective clothing. <br />· Environmental precautions: <br />Do not allow product to reach sewage system or water bodies. <br />Inform respective authorities in case product reaches water or sewage system. <br />· Methods and material for containment and cleaning up: <br />Ensure adequate ventilation. <br />Pick up the product mechanically, avoid dust formation. <br />· Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />See Section 13 for information on disposal. <br />7 Handling and storage <br />· Handling <br />· Precautions for safe handling <br />Keep away from heat and direct sunlight. <br />Prevent formation of dust. <br />Keep out of the reach of children <br />For personal protection equipment, see section 8. <br />Absorb spilt material dry, avoid stirring up, if necessary protect against drifting with tarpaulin. <br />Dispose of in accordance with section 13. Keep drop height low when decanting. Do not use <br />compressed air. Use suitable industrial vacuum cleaners/dust extractors of dust class M (DIN EN <br />60335-2-69) for cleaning. Wear a respirator (min. FFP2) in case of dust formation. Wear suitable <br />(Contd. on page 4) <br />RU</p> <p>61.0.34</p> <p>Page 4/9</p> <p>Safety data sheet <br />According to 91/155 EEC <br />Date of issue: 05.12.2025</p> <p>Version number 8</p> <p>Revision: 05.12.2025</p> <p>Trade name: ASO-EZ4 <br />(Contd. of page 3)</p> <p>personal protective equipment according to section 8. Avoid skin contact and inhalation of dust. <br />Allow mixed product to harden and dispose of in accordance with section 13. <br />· Information about protection against explosions and fires: No special measures required. <br />· Storage <br />· Requirements to be met by storerooms and containers: <br />Store only in the original container. <br />Protect against wetness and water. <br />Store in a dry place. <br />· Information about storage in one common storage facility: Not required. <br />· Further information about storage conditions: <br />Keep container tightly sealed. <br />Store in cool, dry conditions in well sealed containers. <br />Store in a locked cabinet and out of the reach of children. <br />· Specific end use(s) No further relevant information available. <br />8 Exposure controls/personal protection <br />· Appropriate engineering controls <br />It must be possible to wash the skin in the working area. <br />Eye-wash bottle must be available. <br />· Components with critical values that require monitoring at the workplace: <br />The product does not contain any relevant quantities of materials with critical values that have to be <br />monitored at the workplace. <br />· DNELs <br />68475-76-3 Flue dust, portland cement <br />Inhalative DNEL 840 mg/mg³ (human) <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· Personal protective equipment <br />· General protective and hygienic measures <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />Keep away from foodstuffs, beverages and food. <br />Instantly remove any soiled and impregnated garments. <br />Vacuum clean contaminated clothing. Do not blow or brush off contamination. <br />Avoid contact with the eyes and skin. <br />Do not eat, drink or smoke while working. <br />Use skin protection cream for preventive skin protection. <br />Be sure to clean skin thoroughly after work and before breaks. <br />· Breathing equipment: <br />Use respiratory protective equipment at formation of dust. <br />In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer <br />exposure use breathing apparatus that is independent of circulating air. <br />For work with higher dust loads: Particle filter class P2 <br />· Protection of hands: <br />Nitril-rubber-latex-cotton gloves. <br />Hand Protection: Nitril-rubber-latex-gloves. <br />In case of wearing synthetic protective gloves use cotton-gloves as underwear. <br />The glove material has to be impermeable and resistant to the product/ the substance/ the <br />preparation. <br />Selection of the glove material on consideration of the penetration times, rates of diffusion and the <br />degradation <br />· Material of gloves <br />Nitrile-soaked cotton gloves (layer thickness approx. 0.15 mm) <br />For activities using products containing cement, suitable protective gloves have been identified <br />(GISCODES ZP1). Suitable are, for example <br />Ampri: SolidSafety Cut 081101 / SolidSafety Tough 081201 / SolidSafetyTough Dots 081202 <br />Ansell: Flexitril L27 / Fleximax 27 or 35 / Hylite / Nitrotough N210 / Sol-Knit <br />KCL: Sahara / Gobi / Nitex <br />MAPA: Duo-Mix 405 / Enduro 328 / Stansolv AK 22 / Titanlite 397 / Titansuperlite <br />(Contd. on page 5) <br />RU</p> <p>61.0.34</p> <p>Page 5/9</p> <p>Safety data sheet <br />According to 91/155 EEC <br />Date of issue: 05.12.2025</p> <p>Version number 8</p> <p>Revision: 05.12.2025</p> <p>Trade name: ASO-EZ4 <br />(Contd. of page 4)</p> <p>UVEX: uvex Profi Ergo XG 20 / uvex phynomic pro <br />The selection of the suitable gloves does not only depend on the material, but also on further marks <br />of quality and varies from manufacturer to manufacturer. As the product is a preparation of several <br />substances, the resistance of the glove material can not be calculated in advance and has therefore <br />to be checked prior to the application. <br />· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and <br />has to be observed. <br />· For the permanent contact in work areas without heightened risk of injury (e.g. Laboratory) <br />gloves made of the following material are suitable: <br />Nitrile rubber, NBR <br />· Not suitable are gloves made of the following materials: <br />Leather gloves. <br />Gloves made of thick fabric. <br />· Eye protection: <br />Tightly sealed safety glasses. <br />Suitable safety goggles in accordance with DIN EN 166. <br />· Body protection: Protective work clothing. <br />9 Physical and chemical properties <br />· General Information <br />· Appearance: <br />· Form: <br />Powder <br />· Colour: <br />Grey <br />· Smell: <br />Characteristic <br />· Odour threshold: <br />Not determined. <br />· pH-value at 20 °C: <br />11,4 (1%) <br />· Change in condition <br />· Melting point/freezing point: <br />Not determined <br />· Initial boiling point and boiling range: not apply <br />· Flash point: <br />Not applicable <br />· Inflammability (solid, gaseous) <br />Not determined. <br />· Decomposition temperature: <br />Not determined. <br />· Self-inflammability: <br />Product is not selfigniting. <br />· Explosive properties: <br />Product is not explosive. <br />· Critical values for explosion: <br />· Lower: <br />Not determined. <br />· Upper: <br />Not determined. <br />· Steam pressure: <br />Not applicable. <br />· Density <br />bulk density <br />· Settled apparent density <br />1.060 kg/m³ <br />1,06 kg/dm³ <br />· Relative density <br />Not determined. <br />· Vapour density <br />Not applicable. <br />· Evaporation rate <br />Not applicable. <br />· Solubility in / Miscibility with <br />· Water: <br />miscible <br />· Partition coefficient: n-octanol/water: Not determined. <br />· Viscosity: <br />· dynamic: <br />Not applicable. <br />· kinematic: <br />Not applicable. <br />· Other information <br />· Particle characteristics</p> <p>Not determined. <br />(Contd. on page 6) <br />RU</p> <p>61.0.34</p> <p>Page 6/9</p> <p>Safety data sheet <br />According to 91/155 EEC <br />Date of issue: 05.12.2025</p> <p>Version number 8</p> <p>Revision: 05.12.2025</p> <p>Trade name: ASO-EZ4 <br />(Contd. of page 5)</p> <p>· Physical state</p> <p>Firm</p> <p>10 Stability and reactivity <br />· Reactivity No further relevant information available. <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· Possibility of hazardous reactions No dangerous reactions known <br />· Conditions to avoid No further relevant information available. <br />· Incompatible materials: No further relevant information available. <br />· Hazardous decomposition products: No dangerous decomposition products known <br />11 Toxicological information <br />· Information on toxicological effects <br />· Acute toxicity May be harmful if inhaled. <br />· LD/LC50 values that are relevant for classification: <br />65997-16-2 alumina cement clinker <br />Oral <br />LD50 <br />>2.000 mg/kg (rats) (OECD 423) <br />91051-01-3 Fatty acids, C16-18, zinc salts <br />Oral <br />LD50 <br />>5.000 mg/kg (rats) (OECD 401 (analogy)) <br />Dermal LD50 <br />>2.000 mg/kg (Kan) <br />Inhalative LC50/4 h >50 mg/l (rats) <br />68475-76-3 Flue dust, portland cement <br />Oral <br />LD50 <br />>1.848 mg/kg (rats) (OECD 422) <br />Dermal LD50 <br />>2.000 mg/kg (rats) (OECD 402) <br />Inhalative LC50/4 h >6,04 mg/l (rats) (OECD 436) <br />· Primary irritant effect: <br />· Skin corrosion/irritation <br />The product has an irritate-effect. <br />Causes skin irritation. <br />· Serious eye damage/irritation Causes serious eye damage. <br />· Respiratory or skin sensitisation May cause an allergic skin reaction. <br />· Germ cell mutagenicity Based on available data, the classification criteria are not met. <br />· Carcinogenicity Based on available data, the classification criteria are not met. <br />· Reproductive toxicity Based on available data, the classification criteria are not met. <br />· STOT-single exposure May cause respiratory irritation. <br />· STOT-repeated exposure Based on available data, the classification criteria are not met. <br />· Aspiration hazard Based on available data, the classification criteria are not met. <br />12 Ecological information <br />· Toxicity <br />· Aquatic toxicity: <br />65997-16-2 alumina cement clinker <br />LC50/96h <br />>100 mg/l (rainbow trout) (OECD 203) <br />EC50 (48h) 6,6 mg/l (Daphnia magna) (OECD 202) <br />ERC50 <br />>5,6 mg/l /72h (Pseudokirchneriella subcapitata) (OECD 201) <br />NOEC <br />1,8 mg/l /48h (Daphnia magna) (OECD 202) <br />3,2 mg/l /72h (Pseudokirchneriella subcapitata) (OECD 201) <br />(Contd. on page 7) <br />RU</p> <p>61.0.34</p> <p>Page 7/9</p> <p>Safety data sheet <br />According to 91/155 EEC <br />Date of issue: 05.12.2025</p> <p>Version number 8</p> <p>Revision: 05.12.2025</p> <p>Trade name: ASO-EZ4 <br />(Contd. of page 6)</p> <p>>100 mg/l /96h (rainbow trout) (OECD 203) <br />91051-01-3 Fatty acids, C16-18, zinc salts <br />LC50/96h <br />>10.000 mg/l (zebra danio) (67/548/EWG) <br />EC10 <br />3,31 mg/l /72h (Pseudokirchneriella subcapitata) (OECD 201) <br />EC50 (48h) >100 mg/l (Daphnia magna) (OECD 202) <br />EC50 <br />>100 mg/l /72h (Pseudokirchneriella subcapitata) (OECD 201) <br />NOEC (static) 1.560 mg/l /0,5h (Photobacterium phosphoreum) (DIN 38412 T 34) <br />19,3 mg/l /72h (Pseudokirchneriella subcapitata) (OECD 201) <br />· Persistence and degradability No further relevant information available. <br />· Behaviour in environmental systems: <br />· Bioaccumulative potential No further relevant information available. <br />· Mobility in soil No further relevant information available. <br />· Additional ecological information: <br />· General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />· Other adverse effects No further relevant information available. <br />13 Disposal considerations <br />· Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />· Uncleaned packagings: <br />· Recommendation: Disposal must be made according to official regulations. <br />· Recommended cleaning agent: Water, if necessary with cleaning agent. <br />14 Transport information <br />· UN-Number <br />· ADR, IMDG, IATA</p> <p>Void</p> <p>· UN proper shipping name <br />· ADR, IMDG, IATA</p> <p>Void</p> <p>· Transport hazard class(es) <br />· ADR, ADN, IMDG, IATA <br />· Class</p> <p>Void</p> <p>· Packing group <br />· ADR, IMDG, IATA</p> <p>Void</p> <p>· Environmental hazards:</p> <p>Not applicable.</p> <p>· Special precautions for user</p> <p>Not applicable.</p> <p>· Transport in bulk according to Annex II of <br />Marpol and the IBC Code <br />Not applicable. <br />(Contd. on page 8) <br />RU</p> <p>61.0.34</p> <p>Page 8/9</p> <p>Safety data sheet <br />According to 91/155 EEC <br />Date of issue: 05.12.2025</p> <p>Version number 8</p> <p>Revision: 05.12.2025</p> <p>Trade name: ASO-EZ4 <br />(Contd. of page 7)</p> <p>· Transport/Additional information: <br />· ADR <br />· Number/Letter: <br />· UN "Model Regulation":</p> <p>Void</p> <p>15 Regulatory information <br />· GHS label elements <br />The product is classified and labelled according to the Globally Harmonised System (GHS). <br />· Hazard pictograms GHS05, GHS07 <br />· Signal word Danger <br />· Hazard-determining components of labelling: <br />Cement, portland, chemicals <br />Flue dust, portland cement <br />· Hazard statements <br />May be harmful if inhaled. <br />Causes skin irritation. <br />Causes serious eye damage. <br />May cause an allergic skin reaction. <br />May cause respiratory irritation. <br />· Precautionary statements <br />Avoid breathing dust/fume/gas/mist/vapours/spray. <br />Wear protective gloves / eye protection / face protection. <br />IF INHALED: Call a POISON CENTER/doctor if you feel unwell. <br />IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and <br />easy to do. Continue rinsing. <br />Store locked up. <br />Dispose of contents/container in accordance with local/regional/national/international regulations. <br />· Directive 2012/18/EU <br />· Named dangerous substances - ANNEX I None of the ingredients is listed. <br />· Chemical safety assessment: A Chemical Safety Assessment has not been carried out. <br />16 Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for <br />any specific product features and shall not establish a legally valid contractual relationship. <br />· Relevant phrases <br />H303 May be harmful if swallowed. <br />H313 May be harmful in contact with skin. <br />H315 Causes skin irritation. <br />H317 May cause an allergic skin reaction. <br />H318 Causes serious eye damage. <br />H333 May be harmful if inhaled. <br />H335 May cause respiratory irritation. <br />· Department issuing data specification sheet: <br />· Abbreviations and acronyms: <br />ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning <br />the International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />DNEL: Derived No-Effect Level (REACH) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />(Contd. on page 9) <br />RU</p> <p>61.0.34</p> <p>Page 9/9</p> <p>Safety data sheet <br />According to 91/155 EEC <br />Date of issue: 05.12.2025</p> <p>Version number 8</p> <p>Revision: 05.12.2025</p> <p>Trade name: ASO-EZ4 <br />(Contd. of page 8) <br />PBT: Persistent, Bioaccumulative and Toxic <br />vPvB: very Persistent and very Bioaccumulative <br />Acute Tox. 5: Acute toxicity – Category 5 <br />Skin Irrit. 2: Skin corrosion/irritation – Category 2 <br />Eye Dam. 1: Serious eye damage/eye irritation – Category 1 <br />Skin Sens. 1: Skin sensitisation – Category 1 <br />STOT SE 3: Specific target organ toxicity (single exposure) – Category 3 <br />RU</p>
