52.0
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 02.03.2021 *
Version number 11
Revision: 02.03.2021
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: UNIFIX-S3 (B-Komp.) · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Tile adhesive · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 email: SDB@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 The product is not classified, according to the CLP regulation. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 Void · Hazard pictograms Void · Signal word Void · Hazard statements Void · Additional information: EUH208 Contains 2-methyl-2H-isothiazol-3-one, 1,2-benzisothiazol-3(2H)-one, reaction mass of: 5chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1). May produce an allergic reaction. EUH210 Safety data sheet available on request. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable.
SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: dispersion (Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 02.03.2021
Trade name: UNIFIX-S3 (B-Komp.) (Contd. of page 1)
· Dangerous components: CAS: 2634-33-5 1,2-benzisothiazol-3(2H)-one 0.005-<0.025% EINECS: 220-120-9 Eye Dam. 1, H318; Aquatic Acute 1, H400; Acute Tox. 4, H302; Skin Irrit. 2, H315; Skin Sens. 1, H317 Specific concentration limit: Skin Sens. 1; H317: C ≥ 0.05 % CAS: 2682-20-4 EINECS: 220-239-6
2-methyl-2H-isothiazol-3-one Acute Tox. 3, H301; Acute Tox. 3, H311; Acute Tox. 2, Skin Corr. 1B, H314; Eye Dam. 1, H318; H330; Aquatic Acute 1, H400 (M=10); Aquatic Chronic 1, H410 (M=1); Skin Sens. 1A, H317 Specific concentration limit: Skin Sens. 1A; H317: C ≥ 0.0015 %
<0.0015%
CAS: 55965-84-9 reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC <0.0015% EC number: 611-341-5 no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1) Acute Tox. 3, H301; Acute Tox. 2, H310; Acute Tox. 2, Skin Corr. 1C, H314; Eye Dam. 1, H318; H330; Aquatic Acute 1, H400 (M=100); Aquatic Chronic 1, H410 (M=100); Skin Sens. 1A, H317 Specific concentration limits: Skin Corr. 1C; H314: C ≥ 0.6 % Skin Irrit. 2; H315: 0.06 % ≤ C < 0.6 % Eye Dam. 1; H318: C ≥ 0.6 % Eye Irrit. 2; H319: 0.06 % ≤ C < 0.6 % Skin Sens. 1A; H317: C ≥ 0.0015 % · Additional information For the wording of the listed hazard phrases refer to section 16. SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. · After inhalation Supply fresh air; consult doctor in case of symptoms. · After skin contact After contact, clean the skin mechanical and rinse with water and soap. Change immediately heavy contaminated clothes. Don't use solvents to clean the skin. · After eye contact Rinse opened eye for several minutes under running water. · After swallowing Drink copious amounts of water. Avert vomiting. Instantly call for doctor. Do not give household remedys (milk, alcohol etc.) Show the pack or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. · 5.2 Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. (Contd. on page 3) GB
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Trade name: UNIFIX-S3 (B-Komp.) (Contd. of page 2)
· 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Product is inflammable during water-component is existing. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose of the material collected according to regulations. · 6.4 Reference to other sections No dangerous materials are released. See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. *
SECTION 7: Handling and storage · 7.1 Precautions for safe handling Keep away from children. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: None. · Storage class 12 · 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls Eye-wash bottle must be available. It must be possible to wash the skin in the working area. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Wash hands during breaks and at the end of the work. Avoid contact with the eyes and skin. Vacuum clean contaminated clothing. Do not blow or brush off contamination. · Breathing equipment: Not required. · Hand protection Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Break through time 480 min The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several (Contd. on page 4) GB
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Trade name: UNIFIX-S3 (B-Komp.) (Contd. of page 3)
substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye/face protection Safety glasses · Body protection: Protective work clothing. *
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Fluid · Colour: White · Smell: Ester-like · Odour threshold: Not determined. · Melting point/freezing point: Not determined · Boiling point or initial boiling point and boiling range 100 °C · Flammability Not applicable. · Lower and upper explosion limit · Lower: Not determined. · Upper: Not determined. · Flash point: Not applicable · Self-inflammability: Product is not selfigniting. · Decomposition temperature: Not determined. · pH at 20 °C 10 · Viscosity: · Kinematic viscosity Not determined. · dynamic at 20 °C: 40 mPas · Solubility · Water: miscible · Partition coefficient n-octanol/water (log value) Not determined. · Steam pressure: Not determined. · Density and/or relative density · Density at 20 °C 1 g/cm³ · Relative density Not determined. · Vapour density Not determined. · 9.2 Other information · Appearance: · Form: Liquid · Important information on protection of health and environment, and on safety. · Explosive properties: Product is not explosive. · Change in condition · Evaporation rate Not determined. · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids
Void Void Void Void Void Void (Contd. on page 5) GB
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Trade name: UNIFIX-S3 (B-Komp.) (Contd. of page 4)
· Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Void Void Void Void Void Void Void Void Void Void Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known *
SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 2634-33-5 1,2-benzisothiazol-3(2H)-one Oral LD50 670 mg/kg (rats) (OECD 401) Dermal LD50 >2,000 mg/kg (rats) (OECD 402) 2682-20-4 2-methyl-2H-isothiazol-3-one Oral LD50 120 mg/kg (rats) (EPA OPPTS 870.1100) Dermal LD50 242 mg/kg (rats) (OECD 402) 55965-84-9 reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1) Oral LD50 64 mg/kg (rats) Dermal LD50 87.12 mg/kg (Kan) Inhalative LC50/4 h 0.33 mg/l (rats) · Primary irritant effect: No irritant action known. · Skin corrosion/irritation Based on available data, the classification criteria are not met. · Serious eye damage/irritation Irritate-effect is possible. Based on available data, the classification criteria are not met. · Respiratory or skin sensitisation Based on available data, the classification criteria are not met. · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. (Contd. on page 6) GB
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Trade name: UNIFIX-S3 (B-Komp.) (Contd. of page 5)
· 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed. *
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 2634-33-5 1,2-benzisothiazol-3(2H)-one EC 50 0.11 mg/kg /72h (Selenastrum capricornutum) (OECD 201) LC50/96h 2.2 mg/l (rainbow trout) (OECD 203) EC50 (48h) 3.27 mg/l (Daphnia (acute) toxicity) (OECD 202) NOEC 1.2 mg/l /21d (Daphnia magna) (OECD 211) 0.04 mg/l /72h (Selenastrum capricornutum) (OECD 201) 0.21 mg/l /28d (rainbow trout) (OECD 215) 2682-20-4 2-methyl-2H-isothiazol-3-one LC50 (48h) 0.934 mg/l (Daphnia magna) (OECD 202) LC50/96h 4.77 mg/l (rainbow trout) (OECD 203) EC/LC50 (72h) 0.103 mg/l (algae toxicity) (OECD 201) NOEC 0.04 mg/l (Daphnia magna) ((21 d)) 2.1 mg/l (Pimephales promelas) ((33 d)) 55965-84-9 reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1) LC50 (48h) 0.16 mg/l (Daphnia magna) (vgl OECD 202) LC50/96h 0.19 mg/l (rainbow trout) (vgl. OECD 203) ERC50 0.0052 mg/l (algae toxicity) (48h, OECD 201) NOEC 0.1 mg/l (Daphnia magna) (21 d) 0.05 mg/l (rainbow trout) (14 d) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Endocrine disrupting properties The product does not contain substances with endocrine disrupting properties. · 12.7 Other adverse effects · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. (Contd. on page 7) GB
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Trade name: UNIFIX-S3 (B-Komp.) (Contd. of page 6)
· European waste catalogue 08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS 08 04 00 wastes from MFSU of adhesives and sealants (including waterproofing products) 08 04 10 waste adhesives and sealants other than those mentioned in 08 04 09 · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleaning agent: Water, if necessary with cleaning agent. *
SECTION 14: Transport information · 14.1 UN number or ID number · ADR, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards: · Marine pollutant:
No
· 14.6 Special precautions for user
Not applicable.
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. · UN "Model Regulation":
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · DIRECTIVE 2011/65/EU on the restriction of the use of certain hazardous substances in electrical and electronic equipment – Annex II None of the ingredients is listed. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H301 Toxic if swallowed. H302 Harmful if swallowed. H310 Fatal in contact with skin. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. (Contd. on page 8) GB
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Trade name: UNIFIX-S3 (B-Komp.) (Contd. of page 7)
H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H330 Fatal if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Date of previous version: 02.03.2021 · Version number of previous version: 10 · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 3: Acute toxicity - oral – Category 3 Acute Tox. 4: Acute toxicity - oral – Category 4 Acute Tox. 2: Acute toxicity - inhalation – Category 2 Skin Corr. 1B: Skin corrosion/irritation – Category 1B Skin Corr. 1C: Skin corrosion/irritation – Category 1C Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Skin Sens. 1: Skin sensitisation – Category 1 Skin Sens. 1A: Skin sensitisation – Category 1A Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1
· * Data compared to the previous version altered. GB