53.1.0
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 15.09.2021 *
Version number 15
Revision: 08.04.2021
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: SOLOFLEX · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Tile adhesive · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 email: info@schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-770 email: SDB@schomburg.de SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 corrosion Eye Dam. 1 H318 Causes serious eye damage.
Skin Irrit. 2 H315 Causes skin irritation. STOT SE 3 H335 May cause respiratory irritation. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS05, GHS07 · Signal word Danger · Hazard-determining components of labelling: Cement, portland, chemicals · Hazard statements H315 Causes skin irritation. H318 Causes serious eye damage. H335 May cause respiratory irritation. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves / eye protection / face protection. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. (Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 15.09.2021
Trade name: SOLOFLEX (Contd. of page 1)
P405 P501
Store locked up. Dispose of contents/container in accordance with local/regional/national/ international regulations.
· 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Product based on cement and mineral filler. · Dangerous components: CAS: 65997-15-1 Cement, portland, chemicals EINECS: 266-043-4 Eye Dam. 1, H318; Skin Irrit. 2, H315; STOT SE 3, H335 · Additional information For the wording of the listed hazard phrases refer to section 16.
25-50%
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. · After inhalation Supply fresh air; consult doctor in case of symptoms. · After skin contact Instantly wash with water and soap and rinse thoroughly. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. · After swallowing Drink copious amounts of water. Avert vomiting. Instantly call for doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents Product is not inflammable. Use fire fighting measures that suit the environment. · 5.2 Special hazards arising from the substance or mixture No further relevant information available. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Follow the emergency-plan. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Avoid causing dust. Avoid eye- and skin contact. Wear protective clothing. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Pick up the product mechanically, avoid dust formation. · 6.4 Reference to other sections See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. (Contd. on page 3) GB
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Trade name: SOLOFLEX (Contd. of page 2)
See Section 7 for information on safe handling *
SECTION 7: Handling and storage · 7.1 Precautions for safe handling Thorough dedusting. Prevent formation of dust. Keep away from children. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Protect from humidity and keep away from water. Keep container tightly sealed. Store in a locked cabinet and out of the reach of children. · 7.3 Specific end use(s) No further relevant information available. SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. No further data; see item 7 MSDS. · Components with critical values that require monitoring at the workplace: 65997-15-1 Cement, portland, chemicals (25-50%) WEL Long-term value: 10* 4** mg/m³ *inhalable dust **respirable dust · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Be sure to clean skin thoroughly after work and before breaks. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. · Breathing equipment: Use respiratory protective equipment at formation of dust. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Penetration time 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing. GB
(Contd. on page 4)
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Trade name: SOLOFLEX (Contd. of page 3)
*
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Powder Colour: Grey · Smell: Weak, characteristic · Odour threshold: Not determined. · pH-value at 20 °C:
11.7 (1%)
· Change in condition Melting point/freezing point: Not determined Initial boiling point and boiling range: not apply · Flash point:
Not applicable
· Inflammability (solid, gaseous)
Not determined.
· Decomposition temperature:
· Self-inflammability:
Product is not selfigniting.
· Explosive properties:
Product is not explosive.
· Critical values for explosion: Lower: Upper:
Not determined. Not determined.
· Steam pressure:
Not applicable.
· Density
bulk density
· Settled apparent density · Relative density · Vapour density · Evaporation rate
1.37 kg/dm³ Not determined. Not applicable. Not applicable.
· Solubility in / Miscibility with Water:
miscible
· Partition coefficient: n-octanol/water:
· Viscosity: dynamic: kinematic:
Not applicable. Not applicable.
· 9.2 Other information
No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known GB
(Contd. on page 5)
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Trade name: SOLOFLEX (Contd. of page 4)
SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 544-17-2 Calciumformiat Oral LD50 3,050 mg/kg (rats) (OECD 401) Dermal LD50 >2,000 mg/kg (rats) (OECD 402) · Primary irritant effect: · Skin corrosion/irritation Causes skin irritation. · Serious eye damage/irritation Causes serious eye damage. · Respiratory or skin sensitisation Based on available data, the classification criteria are not met. · Additional toxicological information: · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure May cause respiratory irritation. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met.
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 544-17-2 Calciumformiat LC 0 >1,000 mg/l /48h (Brachydanio rerio) EC50 (48h) >1,000 mg/l (Daphnia magna) (EPA-660/3-75-009) EC50 >1,000 mg/l /72h (Pseudokirchneriella subcapitata) (ASTM E-47.01) NOEC ≥100 mg/l /21d (Daphnia magna) (OECD 211) ≥22.1 mg/l /29d (bacterial toxicity) (OECD 306) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. Must not reach sewage water or drainage ditch undiluted or unneutralised. Rinse off of bigger amounts into drains or the aquatic environment may lead to increased pH-values. A high pH-value harms aquatic organisms. In the dilution of the use-level the pH-value is considerably reduced, so that after the use of the product the aqueous waste, emptied into drains, is only low water-dangerous. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. GB
(Contd. on page 6)
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Trade name: SOLOFLEX (Contd. of page 5)
SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleaning agent: Water, if necessary with cleaning agent.
SECTION 14: Transport information · 14.1 UN-Number · ADR, ADN, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, ADN, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards:
· 14.6 Special precautions for user
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · UN "Model Regulation":
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H315 Causes skin irritation. H318 Causes serious eye damage. H335 May cause respiratory irritation. · Department issuing data specification sheet: Environment protection department. · Contact: Environment protection department. · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals (Contd. on page 7) GB
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Trade name: SOLOFLEX (Contd. of page 6) EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Dam. 1: Serious eye damage/eye irritation – Category 1 STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
· * Data compared to the previous version altered. GB