SDS_CRISTALLFUGE-EPOX (B-Komp.)_-_204204B_(17)EN.pdf
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<h1>SDS_CRISTALLFUGE-EPOX (B-Komp.)_-_204204B_(17)EN.pdf</h1> <p>53.1.0</p> <p>Page 1/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.09.2021</p> <p>Version number 17</p> <p>Revision: 16.09.2021</p> <p>SECTION 1: Identification of the substance/mixture and of the company/undertaking <br />· 1.1 Product identifier <br />· Trade name: CRISTALLFUGE-EPOX (B-Komp.) <br />· 1.2 Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture Hardener component <br />· 1.3 Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH & Co. KG <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />email: info@schomburg.de <br />· Informing department: <br />Product Safety Department <br />Tel: ++49 (0)5231/953-770 <br />email: SDB@schomburg.de <br />SECTION 2: Hazards identification <br />· 2.1 Classification of the substance or mixture <br />· Classification according to Regulation (EC) No 1272/2008 <br />corrosion <br />Skin Corr. 1A <br />Eye Dam. 1</p> <p>H314 Causes severe skin burns and eye damage. <br />H318 Causes serious eye damage.</p> <p>environment <br />Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.</p> <p>Skin Sens. 1</p> <p>H317 May cause an allergic skin reaction.</p> <p>· 2.2 Label elements <br />· Labelling according to Regulation (EC) No 1272/2008 <br />The product is classified and labelled according to the CLP regulation. <br />· Hazard pictograms GHS05, GHS07, GHS09 <br />· Signal word Danger <br />· Hazard-determining components of labelling: <br />polyamines adduct <br />3-aminomethyl-3,5,5-trimethylcyclohexylamine <br />Polyethylenpolyamin (Teta - Fraktion) <br />3,6,9 Triazaundecan, 1,11-diamin <br />3-(2-Aminoethylamino)-propyltrimethoxysilan <br />(Contd. on page 2) <br />GB</p> <p>53.1.0</p> <p>Page 2/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.09.2021</p> <p>Version number 17</p> <p>Revision: 16.09.2021</p> <p>Trade name: CRISTALLFUGE-EPOX (B-Komp.) <br />(Contd. of page 1)</p> <p>· Hazard statements <br />H314 Causes severe skin burns and eye damage. <br />H317 May cause an allergic skin reaction. <br />H411 Toxic to aquatic life with long lasting effects. <br />· Precautionary statements <br />P260 <br />Do not breathe dusts or mists. <br />P273 <br />Avoid release to the environment. <br />P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin <br />with water [or shower]. <br />P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact <br />lenses, if present and easy to do. Continue rinsing. <br />P405 <br />Store locked up. <br />P501 <br />Dispose of contents/container in accordance with local/regional/national/ <br />international regulations. <br />· 2.3 Other hazards <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />SECTION 3: Composition/information on ingredients <br />· 3.2 Chemical characterisation: Mixtures <br />· Description: Hardener, aminformulation <br />· Dangerous components: <br />CAS: 68410-23-1 <br />EC number: 614-452-7</p> <p>polyamines adduct <br />Eye Dam. 1, H318; <br />Aquatic Chronic 2, H411; <br />Irrit. 2, H315; Skin Sens. 1, H317</p> <p>50-100% <br />Skin</p> <p>CAS: 2855-13-2 <br />3-aminomethyl-3,5,5-trimethylcyclohexylamine <br />10-25% <br />EINECS: 220-666-8 <br />Skin Corr. 1B, H314; Eye Dam. 1, H318; <br />Acute Tox. 4, <br />Index number: 612-067-00-9 H302; Acute Tox. 4, H312; Skin Sens. 1, H317; Aquatic <br />Chronic 3, H412 <br />CAS: 90640-67-8</p> <p>Polyethylenpolyamin (Teta - Fraktion) <br />Skin Corr. 1B, H314; <br />Acute Tox. 4, H302; Acute Tox. <br />4, H312; Skin Sens. 1, H317; Aquatic Chronic 3, H412</p> <p>CAS: 90640-66-7 <br />EINECS: 292-587-7</p> <p>10-25% <br />3,6,9 Triazaundecan, 1,11-diamin <br />Skin Corr. 1A, H314; Eye Dam. 1, H318; <br />Aquatic <br />Chronic 2, H411; <br />Acute Tox. 4, H312; Skin Sens. 1, H317</p> <p>CAS: 1760-24-3 <br />EINECS: 217-164-6</p> <p><2.5%</p> <p>3-(2-Aminoethylamino)-propyltrimethoxysilan <br />Eye Dam. 1, H318; <br />Skin Sens. 1, H317; Aquatic <br />Chronic 3, H412 <br />· Additional information For the wording of the listed hazard phrases refer to section 16.</p> <p>10-25%</p> <p>SECTION 4: First aid measures <br />· 4.1 Description of first aid measures <br />· General information <br />Instantly remove any clothing soiled by the product. <br />Symptoms of poisoning may even occur after several hours; therefore medical observation for at <br />least 48 hours after the accident. <br />Personal protection for the First Aider. <br />It is possible to choke in case of vomiting in unconsciousness. <br />Bring unconscious persons into a stable position on side. <br />Keep the respiratory tract free (remove dentures and vomiting). <br />Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage <br />of breathing: artificial respiration. <br />(Contd. on page 3) <br />GB</p> <p>53.1.0</p> <p>Page 3/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.09.2021</p> <p>Version number 17</p> <p>Revision: 16.09.2021</p> <p>Trade name: CRISTALLFUGE-EPOX (B-Komp.) <br />(Contd. of page 2)</p> <p>Take up a doctor immediately! <br />· After inhalation <br />Supply fresh air or oxygen; call for doctor. <br />In case of unconsciousness bring patient into stable side position for transport. <br />· After skin contact <br />Instantly wash with water and soap and rinse thoroughly. <br />Change immediately contaminated clothes. <br />· After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. <br />· After swallowing <br />Drink copious amounts of water and provide fresh air. Instantly call for doctor. <br />Show the pack or the label to the doctor. <br />· 4.2 Most important symptoms and effects, both acute and delayed <br />No further relevant information available. <br />· 4.3 Indication of any immediate medical attention and special treatment needed <br />No further relevant information available. <br />SECTION 5: Firefighting measures <br />· 5.1 Extinguishing media <br />· Suitable extinguishing agents <br />CO2, extinguishing powder or water jet. Fight larger fires with water jet. <br />· 5.2 Special hazards arising from the substance or mixture <br />Formation of poisonous gases during heating or in fires. <br />· 5.3 Advice for firefighters <br />· Protective equipment: Wear self-contained breathing apparatus. <br />· Additional information <br />Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. <br />Follow the emergency-plan. <br />Burst- and explosion-danger by increasing pressure. <br />In case of fire chill the container with water spray. <br />SECTION 6: Accidental release measures <br />· 6.1 Personal precautions, protective equipment and emergency procedures <br />Bring persons out of danger. <br />Wear protective equipment. Keep unprotected persons away. <br />· 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. <br />· 6.3 Methods and material for containment and cleaning up: <br />Ensure adequate ventilation. <br />Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). <br />· 6.4 Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />See Section 13 for information on disposal. <br />SECTION 7: Handling and storage <br />· 7.1 Precautions for safe handling <br />Ensure good ventilation/exhaustion at the workplace. <br />Prevent formation of aerosols. <br />Keep away from children. <br />· Information about protection against explosions and fires: No special measures required. <br />· 7.2 Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: No special requirements. <br />(Contd. on page 4) <br />GB</p> <p>53.1.0</p> <p>Page 4/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.09.2021</p> <p>Version number 17</p> <p>Revision: 16.09.2021</p> <p>Trade name: CRISTALLFUGE-EPOX (B-Komp.) <br />(Contd. of page 3)</p> <p>· Information about storage in one common storage facility: <br />Please follow the rules of the VCI-Storage-Concept for chemicals. <br />· Further information about storage conditions: <br />Keep container tightly sealed. <br />Store in a locked cabinet and out of the reach of children. <br />· 7.3 Specific end use(s) No further relevant information available. <br />SECTION 8: Exposure controls/personal protection <br />· 8.1 Control parameters <br />· Additional information about design of technical systems: <br />It must be possible to wash the skin in the working area. <br />Eye-wash bottle must be available. <br />· Components with critical values that require monitoring at the workplace: <br />The product does not contain any relevant quantities of materials with critical values that have to be <br />monitored at the workplace. <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· 8.2 Exposure controls <br />· Personal protective equipment <br />· General protective and hygienic measures <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />Instantly remove any soiled and impregnated garments. <br />Avoid contact with the eyes and skin. <br />Be sure to clean skin thoroughly after work and before breaks. <br />· Breathing equipment: <br />In not so good ventilated space the filter combination A2B2E2K1HgP3RD is to be used. <br />· Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. <br />· Material of gloves <br />Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Penetration time 480 min <br />The selection of the suitable gloves does not only depend on the material, but also on further marks <br />of quality and varies from manufacturer to manufacturer. As the product is a preparation of several <br />substances, the resistance of the glove material can not be calculated in advance and has therefore <br />to be checked prior to the application. <br />· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and <br />has to be observed. <br />· Eye protection: Safety glasses <br />· Body protection: <br />Protective work clothing. <br />Contaminated protection clothes must be cleaned carefully before reuse. <br />SECTION 9: Physical and chemical properties <br />· 9.1 Information on basic physical and chemical properties <br />· General Information <br />· Appearance: <br />Form: <br />Liquid <br />Colour: <br />Yellowish <br />· Smell: <br />Amine-like <br />· Odour threshold: <br />Not determined. <br />· pH-value:</p> <p>Not determined.</p> <p>· Change in condition <br />Melting point/freezing point:</p> <p>Not determined <br />(Contd. on page 5) <br />GB</p> <p>53.1.0</p> <p>Page 5/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.09.2021</p> <p>Version number 17</p> <p>Revision: 16.09.2021</p> <p>Trade name: CRISTALLFUGE-EPOX (B-Komp.) <br />(Contd. of page 4)</p> <p>Initial boiling point and boiling range: >200 °C <br />· Flash point:</p> <p>Not applicable</p> <p>· Inflammability (solid, gaseous)</p> <p>Not applicable.</p> <p>· Decomposition temperature:</p> <p>Not determined.</p> <p>· Self-inflammability:</p> <p>Product is not selfigniting.</p> <p>· Explosive properties:</p> <p>Product is not explosive.</p> <p>· Critical values for explosion: <br />Lower: <br />Upper:</p> <p>Not determined. <br />Not determined.</p> <p>· Steam pressure:</p> <p>Not determined.</p> <p>· Density at 20 °C <br />· Relative density <br />· Vapour density <br />· Evaporation rate</p> <p>0.95 g/cm³ <br />Not determined. <br />Not determined. <br />Not determined.</p> <p>· Solubility in / Miscibility with <br />Water:</p> <p>Not miscible or difficult to mix</p> <p>· Partition coefficient: n-octanol/water:</p> <p>Not determined.</p> <p>· Viscosity: <br />dynamic at 20 °C: <br />kinematic:</p> <p>139 mPas <br />Not determined.</p> <p>· 9.2 Other information</p> <p>No further relevant information available.</p> <p>SECTION 10: Stability and reactivity <br />· 10.1 Reactivity No further relevant information available. <br />· 10.2 Chemical stability <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· 10.3 Possibility of hazardous reactions No dangerous reactions known <br />· 10.4 Conditions to avoid No further relevant information available. <br />· 10.5 Incompatible materials: No further relevant information available. <br />· 10.6 Hazardous decomposition products: No dangerous decomposition products known <br />SECTION 11: Toxicological information <br />· 11.1 Information on toxicological effects <br />· Acute toxicity Based on available data, the classification criteria are not met. <br />· LD/LC50 values that are relevant for classification: <br />68410-23-1 polyamines adduct <br />Oral <br />LD50 >2,000 mg/kg (rats) (OECD 423 method B1) <br />Dermal LD50 >2,000 mg/kg (rats) (OECD 402) <br />2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine <br />Oral <br />LD50 1,030 mg/kg (rats) (OECD 401) <br />Dermal LD50 1,840 mg/kg (rabbit) <br />>2,000 mg/kg (rats) <br />(Contd. on page 6) <br />GB</p> <p>53.1.0</p> <p>Page 6/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.09.2021</p> <p>Version number 17</p> <p>Revision: 16.09.2021</p> <p>Trade name: CRISTALLFUGE-EPOX (B-Komp.) <br />(Contd. of page 5)</p> <p>90640-67-8 Polyethylenpolyamin (Teta - Fraktion) <br />Oral <br />LD50 1,716 mg/kg (rats) (OECD 401) <br />Dermal LD50 1,465 mg/kg (Kan) (OECD 402) <br />90640-66-7 3,6,9 Triazaundecan, 1,11-diamin <br />Oral <br />LD50 3,221 mg/kg (rats) (experimental study) <br />Dermal LD50 1,260 mg/kg (rabbit) (experimental study) <br />· Primary irritant effect: <br />· Skin corrosion/irritation <br />Causes severe skin burns and eye damage. <br />· Serious eye damage/irritation <br />Causes serious eye damage. <br />· Respiratory or skin sensitisation <br />May cause an allergic skin reaction. <br />· Additional toxicological information: <br />· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) <br />· Germ cell mutagenicity Based on available data, the classification criteria are not met. <br />· Carcinogenicity Based on available data, the classification criteria are not met. <br />· Reproductive toxicity Based on available data, the classification criteria are not met. <br />· STOT-single exposure Based on available data, the classification criteria are not met. <br />· STOT-repeated exposure Based on available data, the classification criteria are not met. <br />· Aspiration hazard Based on available data, the classification criteria are not met. <br />SECTION 12: Ecological information <br />· 12.1 Toxicity <br />· Aquatic toxicity: <br />68410-23-1 polyamines adduct <br />LC50/96h 7.07 mg/l (zebra danio) (OECD 203) <br />EC50 (3h) 314 mg/l (activated sludge bacteria) (OECD 209) <br />EC50 <br />5.18 mg/l /48h (Daphnia magna) (OECD 202) <br />ERC50 <br />4.11 mg/l (Pseudokirchneriella subcapitata) (OECD 201) <br />NOEC <br />2.5 mg/l (Daphnia magna) <br />1.25 mg/l (Pseudokirchneriella subcapitata) <br />5 mg/l (zebra danio) <br />2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine <br />LC50/96h 110 mg/l (Leuciscus idus) (OECD 203) <br />EC50 (48h) 23 mg/l (Daphnia magna) (OECD TG 202) <br />EC/10/18h 1,120 mg/l (Pseudomas putida) (Bringmann and Kühn 10, 87-98 (1977)) <br />ERC50 <br />>50 mg/l (Scenedesmus subspicatus) (EG 88/302 (72h)) <br />· 12.2 Persistence and degradability No further relevant information available. <br />· 12.3 Bioaccumulative potential No further relevant information available. <br />· 12.4 Mobility in soil No further relevant information available. <br />· Ecotoxical effects: <br />· Remark: Harmful to fish <br />· Additional ecological information: <br />· General notes: <br />Water hazard class 2 (Self-assessment): hazardous for water. <br />Do not allow product to reach ground water, water bodies or sewage system. <br />Must not reach sewage water or drainage ditch undiluted or unneutralised. <br />Danger to drinking water if even small quantities leak into soil. <br />Harmful to aquatic organisms <br />(Contd. on page 7) <br />GB</p> <p>53.1.0</p> <p>Page 7/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.09.2021</p> <p>Version number 17</p> <p>Revision: 16.09.2021</p> <p>Trade name: CRISTALLFUGE-EPOX (B-Komp.) <br />(Contd. of page 6)</p> <p>· 12.5 Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />· 12.6 Other adverse effects No further relevant information available. <br />SECTION 13: Disposal considerations <br />· 13.1 Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />· Uncleaned packagings: <br />· Recommendation: Disposal must be made according to official regulations. <br />SECTION 14: Transport information <br />· 14.1 UN-Number <br />· ADR, IMDG, IATA <br />· 14.2 UN proper shipping name <br />· ADR</p> <p>· IMDG, IATA</p> <p>UN2735 <br />2735 AMINES, LIQUID, CORROSIVE, N.O.S. <br />(Polyethylenpolyamin (Teta - Fraktion), <br />ISOPHORONEDIAMINE), ENVIRONMENTALLY <br />HAZARDOUS <br />AMINES, LIQUID, CORROSIVE, N.O.S. <br />(Polyethylenpolyamin (Teta - Fraktion), <br />ISOPHORONEDIAMINE)</p> <p>· 14.3 Transport hazard class(es) <br />· ADR</p> <p>· Class <br />· Label</p> <p>8 Corrosive substances. <br />8</p> <p>· IMDG, IATA</p> <p>· Class <br />· Label</p> <p>8 Corrosive substances. <br />8</p> <p>· 14.4 Packing group <br />· ADR, IMDG, IATA</p> <p>II</p> <p>· 14.5 Environmental hazards: <br />· Special marking (ADR):</p> <p>Product contains environmentally hazardous <br />substances: polyamines adduct <br />Symbol (fish and tree)</p> <p>· 14.6 Special precautions for user <br />· Kemler Number: <br />· EMS Number: <br />· Segregation groups <br />· Stowage Category</p> <p>Warning: Corrosive substances. <br />80 <br />F-A,S-B <br />Alkalis <br />A <br />(Contd. on page 8) <br />GB</p> <p>53.1.0</p> <p>Page 8/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.09.2021</p> <p>Version number 17</p> <p>Revision: 16.09.2021</p> <p>Trade name: CRISTALLFUGE-EPOX (B-Komp.) <br />(Contd. of page 7)</p> <p>· Segregation Code</p> <p>SG35 Stow "separated from" SGG1-acids</p> <p>· 14.7 Transport in bulk according to Annex II <br />of Marpol and the IBC Code <br />Not applicable. <br />· Transport/Additional information: <br />· ADR <br />· Limited quantities (LQ) <br />· Excepted quantities (EQ) <br />· Transport category <br />· IMDG <br />· Limited quantities (LQ) <br />· Excepted quantities (EQ)</p> <p>· UN "Model Regulation":</p> <p>1L <br />Code: E2 <br />Maximum net quantity per inner packaging: 30 ml <br />Maximum net quantity per outer packaging: 500 ml <br />2 <br />1L <br />Code: E2 <br />Maximum net quantity per inner packaging: 30 ml <br />Maximum net quantity per outer packaging: 500 ml <br />UN 2735 AMINES, LIQUID, CORROSIVE, N.O.S. <br />(POLYETHYLENPOLYAMIN (TETA - FRAKTION), <br />ISOPHORONEDIAMINE), 8, II, <br />ENVIRONMENTALLY HAZARDOUS</p> <p>SECTION 15: Regulatory information <br />· 15.1 Safety, health and environmental regulations/legislation specific for the substance or <br />mixture <br />· Directive 2012/18/EU <br />· Named dangerous substances - ANNEX I None of the ingredients is listed. <br />· Seveso category E2 Hazardous to the Aquatic Environment <br />· Qualifying quantity (tonnes) for the application of lower-tier requirements 200 t <br />· Qualifying quantity (tonnes) for the application of upper-tier requirements 500 t <br />· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. <br />SECTION 16: Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for <br />any specific product features and shall not establish a legally valid contractual relationship. <br />· Relevant phrases <br />H302 Harmful if swallowed. <br />H312 Harmful in contact with skin. <br />H314 Causes severe skin burns and eye damage. <br />H315 Causes skin irritation. <br />H317 May cause an allergic skin reaction. <br />H318 Causes serious eye damage. <br />H411 Toxic to aquatic life with long lasting effects. <br />H412 Harmful to aquatic life with long lasting effects. <br />· Department issuing data specification sheet: Environment protection department. <br />· Contact: Environment protection department. <br />· Abbreviations and acronyms: <br />ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning <br />the International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />GHS: Globally Harmonised System of Classification and Labelling of Chemicals <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />(Contd. on page 9) <br />GB</p> <p>53.1.0</p> <p>Page 9/9</p> <p>Safety data sheet <br />according to 1907/2006/EC, Article 31 <br />Printing date 16.09.2021</p> <p>Version number 17</p> <p>Revision: 16.09.2021</p> <p>Trade name: CRISTALLFUGE-EPOX (B-Komp.) <br />(Contd. of page 8) <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />PBT: Persistent, Bioaccumulative and Toxic <br />vPvB: very Persistent and very Bioaccumulative <br />Acute Tox. 4: Acute toxicity – Category 4 <br />Skin Corr. 1A: Skin corrosion/irritation – Category 1A <br />Skin Corr. 1B: Skin corrosion/irritation – Category 1B <br />Skin Irrit. 2: Skin corrosion/irritation – Category 2 <br />Eye Dam. 1: Serious eye damage/eye irritation – Category 1 <br />Skin Sens. 1: Skin sensitisation – Category 1 <br />Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2 <br />Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3 <br />GB</p>
