52.1.9
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 26.03.2021 *
Version number 8
Revision: 26.03.2021
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: COMBIDIC-2K-CLASSIC (A-Komp.) · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture bituminous coating · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 email: SDB@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 The product is not classified, according to the CLP regulation. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 Void · Hazard pictograms Void · Signal word Void · Hazard statements Void · Additional information: EUH208 Contains reaction products of paraformaldehyde with 2-hydroxypropylamine (ratio 1:1). May produce an allergic reaction. EUH210 Safety data sheet available on request. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable.
SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Modified anionic Bitumina-Emulsion. · Dangerous components: <0.5% Index number: 612-291-00-7 reaction products of paraformaldehyde with 2hydroxypropylamine (ratio 1:1) Muta. 2, H341; Carc. 1B, H350; STOT RE 2, H373; Skin Corr. 1C, H314; Eye Dam. 1, H318; Aquatic Chronic 2, H411; Acute Tox. 4, H302; Acute Tox. 4, H332; Skin Sens. 1A, H317, EUH071 · Additional information For the wording of the listed hazard phrases refer to section 16. GB
(Contd. on page 2)
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 26.03.2021
Trade name: COMBIDIC-2K-CLASSIC (A-Komp.) (Contd. of page 1)
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact Don't use solvents to clean the skin. Wash with water and soap. · After eye contact Rinse opened eye for several minutes under running water. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Show the pack or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. · 5.2 Special hazards arising from the substance or mixture No further relevant information available. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Follow the emergency-plan. Burst- and explosion-danger by increasing pressure. In case of fire chill the container with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Avoid eye- and skin contact. Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Solid material can be moved mechanically. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · 6.4 Reference to other sections No dangerous materials are released. See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. *
SECTION 7: Handling and storage · 7.1 Precautions for safe handling Keep away from heat and direct sunlight. Do not store open containers. Keep away from children. · Information about protection against explosions and fires: No special measures required. (Contd. on page 3) GB
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Trade name: COMBIDIC-2K-CLASSIC (A-Komp.) (Contd. of page 2)
· 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Protect from frost. · Storage class 12 · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 8052-42-4 Asphalt (25-50%) WEL Short-term value: 10 mg/m³ Long-term value: 5 mg/m³ 9004-34-6 Cellulose (<2.5%) WEL Short-term value: 20* mg/m³ Long-term value: 10* 4** mg/m³ *inhalable dust **respirable · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures Wash hands during breaks and at the end of the work. The usual precautionary measures should be adhered to in handling the chemicals. Avoid contact with eyes and skin. Change clothes which heavy contaminate with the product. · Breathing equipment: Not required. · Hand protection Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Break through time 480 min The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye/face protection Safety glasses · Body protection: Protective work clothing.
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Fluid · Colour: Dark brown · Smell: bitumen · Odour threshold: Not determined. (Contd. on page 4) GB
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Trade name: COMBIDIC-2K-CLASSIC (A-Komp.) (Contd. of page 3)
· Melting point/freezing point: · Boiling point or initial boiling point and boiling range · Flammability · Lower and upper explosion limit · Lower: · Upper: · Flash point: · Self-inflammability: · Decomposition temperature: · pH at 20 °C · Viscosity: · Kinematic viscosity · dynamic at 20 °C: · Solubility · Water: · Partition coefficient n-octanol/water (log value) · Steam pressure: · Density and/or relative density · Density at 20 °C · Relative density · Vapour density
Not determined Not determined Not applicable. Not determined. Not determined. Not applicable Product is not selfigniting. Not determined. 11 Not determined. 8,500 mPas miscible Not determined. Not determined. 0.7 g/cm³ Not determined. Not determined.
· 9.2 Other information · Appearance: · Form: Viscous · Important information on protection of health and environment, and on safety. · Explosive properties: Product is not explosive. · Change in condition · Evaporation rate Not determined. · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. (Contd. on page 5) GB
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Trade name: COMBIDIC-2K-CLASSIC (A-Komp.) (Contd. of page 4)
· 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known *
SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity · LD/LC50 values that are relevant for classification: 8052-42-4 Asphalt Oral LD50 >5,000 mg/kg (rats) (vgl. OECD 401) Dermal LD50 >2,000 mg/kg (rabbit) (vgl. OECD 402) LL/EL/IL50 >1,000 mg/l (algae toxicity) ((72h) QSAR Computer) >1,000 mg/l (Daphnia (acute) toxicity) ((48h) QSAR Computer) >1,000 mg/l (fish toxicity) ((96h) QSAR Computer) 1-Propanaminium, 3-amino-N-(carboxymethyl)-N,N-dimethyl-, N-(C12-18(even numbered acyl) derivs., hydroxides, inner salts Oral LD50 2,335 mg/kg (rats) reaction products of paraformaldehyde with 2-hydroxypropylamine (ratio 1:1) Oral LD50 960 mg/kg (rats) (OECD 401) Dermal LD50 >2,000 mg/kg (rats) (OECD 402) · Primary irritant effect: No irritant action known. · Serious eye damage/irritation Irritate-effect is possible. · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed.
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 8052-42-4 Asphalt LL50 >1,000 mg/l (algae toxicity) ((72h) QSAR Computer) >1,000 mg/l (Daphnia (acute) toxicity) ((48h) QSAR Computer) >1,000 mg/l (fish toxicity) ((96h) QSAR Computer) 1-Propanaminium, 3-amino-N-(carboxymethyl)-N,N-dimethyl-, N-(C12-18(even numbered acyl) derivs., hydroxides, inner salts EC 50 1.5 mg/kg /72h (Desmodesmus subspicatus) (DIN 38412 T.9 (analogy)) LC50/96h 1.11 mg/l (Calamus penna) (OECD 203 (analogy)) EC0 3,000 mg/l /16h (Pseudomas putida) EC50 (48h) 6.5 mg/l (Daphnia magna) (OECD 202 (analogy)) LOEC 0.56 mg/l /21d (Daphnia magna) (OECD 211 (analogy)) NOEC 0.32 mg/l /21d (Daphnia magna) (OECD 211 (analogy)) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. (Contd. on page 6) GB
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Trade name: COMBIDIC-2K-CLASSIC (A-Komp.) (Contd. of page 5)
· 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Endocrine disrupting properties The product does not contain substances with endocrine disrupting properties. · 12.7 Other adverse effects · Additional ecological information: · General notes: Generally not hazardous for water. *
SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Packaging can be reused or recycled after cleaning. · Recommended cleaning agent: Water, if necessary with cleaning agent.
SECTION 14: Transport information · 14.1 UN number or ID number · ADR, ADN, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, ADN, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards:
Not applicable.
· 14.6 Special precautions for user
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. · UN "Model Regulation":
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · National regulations · Water hazard class: Generally not hazardous for water. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. GB
(Contd. on page 7)
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Trade name: COMBIDIC-2K-CLASSIC (A-Komp.) (Contd. of page 6)
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H332 Harmful if inhaled. H341 Suspected of causing genetic defects. H350 May cause cancer. H373 May cause damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. EUH071 Corrosive to the respiratory tract. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity – Category 4 Skin Corr. 1C: Skin corrosion/irritation – Category 1C Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Skin Sens. 1A: Skin sensitisation – Category 1A Muta. 2: Germ cell mutagenicity – Category 2 Carc. 1B: Carcinogenicity – Category 1B STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
· * Data compared to the previous version altered. GB