55.1.4
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 23.09.2022
Version number 2
Revision: 23.09.2022
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: CRISTALLIT-FLEX MAX · 1.2 Relevant identified uses of the substance or mixture and uses advised against · Sector of Use SU19 Building and construction work · Application of the substance / the mixture Construction chemicals Tile adhesive · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department technical information info@maxfrank.de Safety Data Sheet sicherheitsdatenblatt@maxfrank.de SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 corrosion Skin Corr. 1A H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage.
STOT SE 3
H335 May cause respiratory irritation.
· 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the GB CLP regulation. · Hazard pictograms GHS05, GHS07 · Signal word Danger · Hazard-determining components of labelling: Cement, portland, chemicals · Hazard statements H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. (Contd. on page 2) GB
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Trade name: CRISTALLIT-FLEX MAX (Contd. of page 1)
· Precautionary statements P260 Do not breathe dusts or mists. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Product based on cement and mineral filler. · Dangerous components: CAS: 65997-15-1 Cement, portland, chemicals 10-25% EINECS: 266-043-4 Eye Dam. 1, H318; Skin Irrit. 2, H315; STOT SE 3, H335 · Additional information The chromate content in cement is less than 2 ppm so that the labelling with H317 is not applicable (1907/2006/EG, Annex XVII (47)). For the wording of the listed hazard phrases refer to section 16. SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Instantly remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact Instantly wash with water and soap and rinse thoroughly. Wash with water and soap. After contact, clean the skin mechanical and rinse with water and soap. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. · After swallowing Do not induce vomiting; instantly call for medical help. Drink copious amounts of water and provide fresh air. Instantly call for doctor. Show the packaging or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. (Contd. on page 3) GB
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Trade name: CRISTALLIT-FLEX MAX (Contd. of page 2)
· 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · For safety reasons unsuitable extinguishing agents Cement · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. The product may not leak out in sewerage system, stretch of water or soil. · 6.3 Methods and material for containment and cleaning up: Use neutralising agent. Ensure adequate ventilation. Pick up the product mechanically, avoid dust formation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Thorough dedusting. Prevent formation of dust. Keep away from children. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Keep dry. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. Store in a locked cabinet and out of the reach of children. · 7.3 Specific end use(s) No further relevant information available. GB
(Contd. on page 4)
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Trade name: CRISTALLIT-FLEX MAX (Contd. of page 3)
SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Components with critical values that require monitoring at the workplace: 65997-15-1 Cement, portland, chemicals (10-25%) WEL Long-term value: 10* 4** mg/m³ *inhalable dust **respirable dust 1344-28-1 aluminium oxide (2.5-10%) WEL Long-term value: 10* 4** mg/m³ *inhalable dust **respirable dust · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Vacuum clean contaminated clothing. Do not blow or brush off contamination. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. · Protection of hands: Do not reuse one-way-gloves Hand Protection: Nitril-rubber-latex-gloves. In case of wearing synthetic protective gloves use cotton-gloves as underwear. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Tightly sealed safety glasses. In case of splashing use protecting basket-glasses. · Body protection: Acid resistant protective clothing Alkaline resistant protective clothing Apron Use an Overall of heavy cotton or non-returnable Tyvek/Saranex 23 P vleece. (Contd. on page 5) GB
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Trade name: CRISTALLIT-FLEX MAX (Contd. of page 4)
Contaminated protection clothes must be cleaned carefully before reuse. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Powder Colour: grey · Smell: Characteristic · Odour threshold: Not determined. · pH-value at 20 °C:
11-12
· Change in condition Melting point/freezing point: Not determined Initial boiling point and boiling range: not apply · Flash point:
Not applicable
· Inflammability (solid, gaseous)
Not determined.
· Decomposition temperature:
· Self-inflammability:
Product is not selfigniting.
· Explosive properties:
Product is not explosive.
· Critical values for explosion: Lower: Upper:
Not determined. Not determined.
· Steam pressure:
Not applicable.
· Density at 20 °C · Relative density · Vapour density · Evaporation rate
1.1 g/cm³ bulk density Not determined. Not applicable. Not applicable.
· Solubility in / Miscibility with Water:
miscible
· Partition coefficient: n-octanol/water:
· Viscosity: dynamic: kinematic:
Not applicable. Not applicable.
· Solvent content: Solids content: · 9.2 Other information
100.0 % No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. (Contd. on page 6) GB
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Trade name: CRISTALLIT-FLEX MAX (Contd. of page 5)
· 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: No dates existing. · Primary irritant effect: · Skin corrosion/irritation Causes severe skin burns and eye damage. · Serious eye damage/irritation Causes serious eye damage. · Respiratory or skin sensitisation Based on available data, the classification criteria are not met. · Additional toxicological information: · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure May cause respiratory irritation. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: No further relevant information available. · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. Must not reach sewage water or drainage ditch undiluted or unneutralised. Rinse off of bigger amounts into drains or the aquatic environment may lead to increased pH-values. A high pH-value harms aquatic organisms. In the dilution of the use-level the pH-value is considerably reduced, so that after the use of the product the aqueous waste, emptied into drains, is only low water-dangerous. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. (Contd. on page 7) GB
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Trade name: CRISTALLIT-FLEX MAX (Contd. of page 6)
· Recommended cleaning agent: Water, if necessary with cleaning agent. SECTION 14: Transport information · 14.1 UN-Number · ADR, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards:
· 14.6 Special precautions for user
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · UN "Model Regulation":
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H315 Causes skin irritation. H318 Causes serious eye damage. H335 May cause respiratory irritation. · Department issuing data specification sheet: Environment protection department. · Contact: Environment protection department. · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Skin Corr. 1A: Skin corrosion/irritation – Category 1A Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Dam. 1: Serious eye damage/eye irritation – Category 1 STOT SE 3: Specific target organ toxicity (single exposure) – Category 3 GB