51.0.11
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 28.07.2020 *
Version number 9
Revision: 28.07.2020
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: BLANKOL-92 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture release agent · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: SDB@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS08 health hazard Asp. Tox. 1
H304 May be fatal if swallowed and enters airways.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS08 · Signal word Danger · Hazard-determining components of labelling: Hydrocarbons, C14-C18, n-alkanes, isoalkanes, cyclics, aromatics (2-30 %) White spirit (incl. Petroleum 10-25%) · Hazard statements H304 May be fatal if swallowed and enters airways. H412 Harmful to aquatic life with long lasting effects. · Precautionary statements P273 Avoid release to the environment. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P363 Wash contaminated clothing before reuse. P405 Store locked up.
(Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 28.07.2020
Trade name: BLANKOL-92 (Contd. of page 1)
P501
Dispose of contents/container in accordance with local/regional/national/international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Preparation, contains paraffinic and naphtenic hydrocarbons. · Dangerous components: EC number: 920-360-0 Hydrocarbons, C14-C18, n-alkanes, isoalkanes, cyclics, aromatics (2- 50-100% 30 %) Asp. Tox. 1, H304 White spirit (incl. Petroleum 10-25%) Asp. Tox. 1, H304 CAS: 61791-31-9 EINECS: 263-163-9
10-25%
Ethanol, 2,2'-iminobis-, N-coco alkyl derivs. Repr. 2, H361d; Skin Corr. 1B, H314; Aquatic Chronic 1, H410; Acute Tox. 4, H302 · Additional information For the wording of the listed hazard phrases refer to section 16.
<1%
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. · After inhalation Supply fresh air; consult doctor in case of symptoms. · After skin contact Instantly wash with water and soap and rinse thoroughly. · After eye contact Rinse opened eye for several minutes under running water. · After swallowing Do not induce vomiting; instantly call for medical help. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. · For safety reasons unsuitable extinguishing agents Water with a full water jet. · 5.2 Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. In case of strong heat burst- and explosion hazard, the pressure in the container will increase. In case of fire chill the container with water-spray. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Cool endangered containers with water spray jet.
(Contd. on page 3) GB
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Trade name: BLANKOL-92 (Contd. of page 2)
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. SECTION 6: Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Ensure adequate ventilation. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Keep away from children. · Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Do not spray on flames or red-hot objects. Protect against electrostatic charges. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Store in a locked cabinet and out of the reach of children. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures Wash hands during breaks and at the end of the work. The usual precautionary measures should be adhered to in handling the chemicals. Avoid contact with the eyes and skin. When the material is hardened on the skin, remove it carfully mechanically. · Breathing equipment: Not required. (Contd. on page 4) GB
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Trade name: BLANKOL-92
· Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Break through time 480 min
(Contd. of page 3)
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing. *
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Fluid Colour: Clear · Smell: Weak, characteristic · Odour threshold: Not determined. · pH-value:
Not determined.
· Change in condition Melting point/freezing point: Not determined Initial boiling point and boiling range: 182 °C · Flash point:
65 °C
· Inflammability (solid, gaseous)
Not applicable.
· Ignition temperature:
240 °C
· Decomposition temperature:
· Self-inflammability:
Product is not selfigniting.
· Explosive properties:
Product is not explosive.
· Critical values for explosion: Lower: Upper:
Not determined. Not determined.
· Steam pressure:
· Density at 20 °C · Relative density · Vapour density · Evaporation rate
0.811 g/cm³ Not determined. Not determined. Not determined.
· Solubility in / Miscibility with Water:
Not miscible or difficult to mix
· Partition coefficient: n-octanol/water:
Not determined. (Contd. on page 5) GB
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Trade name: BLANKOL-92 (Contd. of page 4)
· Viscosity: dynamic at 20 °C: kinematic: · 9.2 Other information
6.4 mPas Not determined. No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known *
SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: Hydrocarbons, C14-C18, n-alkanes, isoalkanes, cyclics, aromatics (2-30 %) Oral LD50 >4,150 mg/kg (rats) (OECD 423) Dermal LD50 >2,000 mg/kg (rats) (OECD 402) White spirit (incl. Petroleum 10-25%) Oral LD50 >5,000 mg/kg (rats) (OECD 401) Dermal LD50 >5,000 mg/kg (rabbit) (OECD 402) 61791-31-9 Ethanol, 2,2'-iminobis-, N-coco alkyl derivs. Oral LD50 1,500 mg/kg (rats) · Primary irritant effect: No irritant action known. · Skin corrosion/irritation It is possible to irritate the skin. · Serious eye damage/irritation Based on available data, the classification criteria are not met. · Respiratory or skin sensitisation Based on available data, the classification criteria are not met. · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard May be fatal if swallowed and enters airways. GB
(Contd. on page 6)
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Trade name: BLANKOL-92 (Contd. of page 5)
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: White spirit (incl. Petroleum 10-25%) EL 50 >1,000 mg/l /48h (Daphnia magna) (OECD 202) >1,000 mg/l /72h (Pseudokirchneriella subcapitata) (OECD 201) LL50 >1,000 mg/l /48h (Daphnia magna) (OECD 202) >1,000 mg/l /48h (Oncorhynchus mykiss) (OECD 203) 61791-31-9 Ethanol, 2,2'-iminobis-, N-coco alkyl derivs. LC50/96h 0.28 mg/l (Brachydanio rerio) EC50 (48h) 0.84 mg/l (Daphnia magna) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 07 00 00 WASTES FROM ORGANIC CHEMICAL PROCESSES 07 01 00 wastes from the manufacture, formulation, supply and use (MFSU) of basic organic chemicals 07 01 04* other organic solvents, washing liquids and mother liquors · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information · 14.1 UN-Number · ADR, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, IMDG, IATA
Void (Contd. on page 7) GB
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Trade name: BLANKOL-92 (Contd. of page 6)
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards:
· 14.6 Special precautions for user
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · UN "Model Regulation":
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3 · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H361d Suspected of damaging the unborn child. H410 Very toxic to aquatic life with long lasting effects. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity - oral – Category 4 Skin Corr. 1B: Skin corrosion/irritation – Category 1B Repr. 2: Reproductive toxicity – Category 2 Asp. Tox. 1: Aspiration hazard – Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered.
GB