50.0.4
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 20.01.2020
Version number 1
Revision: 20.01.2020
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASODUR-GH-S (A-Komp.) · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Reaction resin · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: SDB@schomburg.de SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS07 Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2 H319 Causes serious eye irritation. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS07 · Signal word Warning · Hazard statements H315 Causes skin irritation. H319 Causes serious eye irritation. · Precautionary statements P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable.
(Contd. on page 2) GB
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Trade name: ASODUR-GH-S (A-Komp.) (Contd. of page 1)
· vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Mixture of substances listed below and non-hazardous additions. · Dangerous components: CAS: 1344-09-8 Wasserglas EINECS: 215-687-4 Acute Tox. 3, H331;
50-100% Skin Irrit. 2, H315; Eye Irrit. 2, H319
CAS: 107-21-1 ethane-1,2-diol EINECS: 203-473-3 STOT RE 2, H373; Acute Tox. 4, H302 · Additional information For the wording of the listed hazard phrases refer to section 16.
2.5-10%
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. In case of unconsciousness bring patient into stable side position for transport. · After skin contact Instantly wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Show the pack or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. Use fire fighting measures that suit the environment. · 5.2 Special hazards arising from the substance or mixture No further relevant information available. · 5.3 Advice for firefighters · Protective equipment: No special measures required.
(Contd. on page 3) GB
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Trade name: ASODUR-GH-S (A-Komp.) (Contd. of page 2)
· Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. SECTION 6: Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Particular danger of slipping on leaked/spilled product. · 6.2 Environmental precautions: Do not allow to enter drainage system, surface or ground water. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Work with fresh air supply, keep doors and windows open. Keep away from heat and direct sunlight. Keep containers tightly sealed. · Information about protection against explosions and fires: The product is not flammable · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Store only in unopened original containers. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. · 7.3 Specific end use(s) No further relevant information available. SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 107-21-1 ethane-1,2-diol (2.5-10%) WEL Short-term value: 104** mg/m³, 40** ppm Long-term value: 10* 52** mg/m³, 20** ppm Sk *particulate **vapour · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures Clean skin only with cleaning agent especially for epoxy resin. Don't use solvent for skin cleaning! Clean clothes which are contaminate with epoxi resin before unsing again.
(Contd. on page 4) GB
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Trade name: ASODUR-GH-S (A-Komp.) (Contd. of page 3)
The usual precautionary measures should be adhered to in handling the chemicals. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Wash hands during breaks and at the end of the work. · Breathing equipment: Not required. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Break through time 480 min
· Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Tightly sealed safety glasses. · Body protection: Contaminated protection clothes must be cleaned carefully before reuse. Protective work clothing. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Liquid Colour: Colourless · Smell: Characteristic · Odour threshold: Not determined. · pH-value:
Not determined.
· Change in condition Melting point/freezing point: Not determined Initial boiling point and boiling range: Not determined · Flash point:
Not applicable
· Inflammability (solid, gaseous)
Not applicable.
· Decomposition temperature:
· Self-inflammability:
Product is not selfigniting.
· Explosive properties:
Product is not explosive.
· Critical values for explosion: Lower: Upper:
Not determined. Not determined.
· Steam pressure:
· Density at 20 °C · Relative density · Vapour density · Evaporation rate
1.48 g/cm³ Not determined. Not determined. Not determined. (Contd. on page 5) GB
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Trade name: ASODUR-GH-S (A-Komp.) (Contd. of page 4)
· Solubility in / Miscibility with Water:
Not miscible or difficult to mix
· Partition coefficient: n-octanol/water:
· Viscosity: dynamic at 20 °C: kinematic: · 9.2 Other information
270 mPas Not determined. No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions Reacts with acids (strongly exothermic). Formation of hydrogen due to reactions with light metals. · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 1344-09-8 Wasserglas Oral LD50 3,400 mg/kg (rats) Dermal LD50 5,000 mg/kg (rats) 107-21-1 ethane-1,2-diol Oral LD50 4,000 mg/kg (rats) Dermal LD50 10,600 mg/kg (rabbit) · Primary irritant effect: · Skin corrosion/irritation The product has an irritate-effect. Causes skin irritation. · Serious eye damage/irritation Causes serious eye irritation. · Respiratory or skin sensitisation Based on available data, the classification criteria are not met. · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. GB
(Contd. on page 6)
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Trade name: ASODUR-GH-S (A-Komp.) (Contd. of page 5)
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 1344-09-8 Wasserglas LC50/96h 260-310 mg/l (Oncorhynchus mykiss) 1,108 mg/l (zebra danio) EC50 (48h) 1,700 mg/l (daphnia magna) EC/LC50 (72h) 207 mg/l (Scenedesmus subspicatus) NOEC 348 mg/l (zebra danio) 107-21-1 ethane-1,2-diol LC50 >10,000 mg/l (Daphnia magna) >18,000 mg/l (rainbow trout) >10,000 mg/l (orfe) EC50 6,500 mg/l (Grünalge (Scenedesmus subspicatus)) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 16 00 00 WASTES NOT OTHERWISE SPECIFIED IN THE LIST 16 03 00 off-specification batches and unused products 16 03 03* inorganic wastes containing hazardous substances 15 00 00 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED 15 01 00 packaging (including separately collected municipal packaging waste) 15 01 10* packaging containing residues of or contaminated by hazardous substances · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. GB
(Contd. on page 7)
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Trade name: ASODUR-GH-S (A-Komp.) (Contd. of page 6)
SECTION 14: Transport information · 14.1 UN-Number · ADR, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards:
· 14.6 Special precautions for user
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · UN "Model Regulation":
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3 · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H331 Toxic if inhaled. H373 May cause damage to organs through prolonged or repeated exposure. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic (Contd. on page 8) GB
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Trade name: ASODUR-GH-S (A-Komp.) (Contd. of page 7) vPvB: very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity - oral – Category 4 Acute Tox. 3: Acute toxicity - inhalation – Category 3 Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2 GB