51.1.24
Page 1/7
Safety data sheet according to 1907/2006/EC, Article 31 Printing date 28.10.2020 *
Version number 12
Revision: 28.10.2020
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASO-R008 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Cleaning agent/ Cleaner · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: SDB@schomburg.de SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS07 Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2 H319 Causes serious eye irritation. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS07 · Signal word Warning · Hazard-determining components of labelling: sodium hydroxide · Hazard statements H315 Causes skin irritation. H319 Causes serious eye irritation. · Precautionary statements P264 Wash thoroughly after handling. P280 Wear protective gloves / eye protection / face protection. P302+P352 IF ON SKIN: Wash with plenty of water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332+P313 If skin irritation occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. (Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 28.10.2020
Trade name: ASO-R008 (Contd. of page 1)
· vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: aqueous combination of washing and surface active substances · Dangerous components: CAS: 111-76-2 2-butoxyethanol EINECS: 203-905-0 Acute Tox. 4, H302; Acute Tox. 4, H312; Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319 CAS: 1310-73-2 sodium hydroxide EINECS: 215-185-5 Skin Corr. 1A, H314; Acute Tox. 4, H302 Specific concentration limits: Skin Corr. 1A; H314: C ≥ 5 % Skin Corr. 1B; H314: 2 % ≤ C < 5 % Skin Irrit. 2; H315: 0.5 % ≤ C < 2 % Eye Irrit. 2; H319: 0.5 % ≤ C < 2 % · Additional information For the wording of the listed hazard phrases refer to section 16.
<2.5%
<1%
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact Instantly wash with water and soap and rinse thoroughly. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Show the pack or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. · 5.2 Special hazards arising from the substance or mixture No further relevant information available. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. GB
(Contd. on page 3)
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Trade name: ASO-R008 (Contd. of page 2)
SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Dispose of the material collected according to regulations. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Keep away from children. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. Keep dry. · Further information about storage conditions: Keep container tightly sealed. · 7.3 Specific end use(s) No further relevant information available. SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 111-76-2 2-butoxyethanol (<2.5%) WEL Short-term value: 246 mg/m³, 50 ppm Long-term value: 123 mg/m³, 25 ppm Sk, BMGV · Ingredients with biological limit values: 111-76-2 2-butoxyethanol (<2.5%) BMGV 240 mmol/mol creatinine Medium: urine Sampling time: post shift Parameter: butoxyacetic acid · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: Not required. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. (Contd. on page 4) GB
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Trade name: ASO-R008 (Contd. of page 3)
· Material of gloves Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Break through time 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Fluid Colour: Colourless · Smell: Characteristic · Odour threshold: Not determined. · pH-value at 20 °C:
11.5
· Change in condition Melting point/freezing point: Not determined Initial boiling point and boiling range: >100 °C · Flash point:
Not applicable
· Inflammability (solid, gaseous)
Not applicable.
· Ignition temperature:
>240 °C 240 °C
· Decomposition temperature:
Not determined.
· Self-inflammability:
Product is not selfigniting.
· Explosive properties:
Product is not explosive.
· Critical values for explosion: Lower: Upper:
Not determined. Not determined.
· Steam pressure at 20 °C:
23 hPa 23 mbar 20° C
· Density at 20 °C · Relative density · Vapour density · Evaporation rate
1.02 g/cm³ Not determined. Not determined. Not determined.
· Solubility in / Miscibility with Water:
miscible
· Partition coefficient: n-octanol/water:
· Viscosity: dynamic: kinematic: · 9.2 Other information
Not determined. Not determined. No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. (Contd. on page 5) GB
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Trade name: ASO-R008 (Contd. of page 4)
· 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: Acids · 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 111-76-2 2-butoxyethanol Oral LD50 1,480 mg/kg (rats) Dermal LD50 1,500 mg/kg (rabbit) Inhalative LC50/4 h 15 mg/l (rats) 1310-73-2 sodium hydroxide Oral LD50 325-500 mg/kg (rats) · Primary irritant effect: · Skin corrosion/irritation Causes skin irritation. · Serious eye damage/irritation Causes serious eye irritation. · Respiratory or skin sensitisation Based on available data, the classification criteria are not met. · Additional toxicological information: Sensitizing · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 111-76-2 2-butoxyethanol LC50/96h 1,474 mg/l (for) EC50 (48h) 1,550 mg/l (Daphnia magna) 1310-73-2 sodium hydroxide LC50 (48h) 133 mg/l (orfe) LC50/96h 35-189 mg/l (orfe) EC50 (48h) 40 mg/l (water flea (Ceriodaphnia spec) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. (Contd. on page 6) GB
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Trade name: ASO-R008 (Contd. of page 5)
Must not reach sewage water or drainage ditch undiluted or unneutralised. Rinse off of bigger amounts into drains or the aquatic environment may lead to increased pH-values. A high pH-value harms aquatic organisms. In the dilution of the use-level the pH-value is considerably reduced, so that after the use of the product the aqueous waste, emptied into drains, is only low water-dangerous. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 07 00 00 WASTES FROM ORGANIC CHEMICAL PROCESSES 07 06 00 wastes from the MFSU of fats, grease, soaps, detergents, disinfectants and cosmetics 07 06 01* aqueous washing liquids and mother liquors · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleaning agent: Water, if necessary with cleaning agent. SECTION 14: Transport information · 14.1 UN-Number · ADR, ADN, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, ADN, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards: · Marine pollutant:
No
· 14.6 Special precautions for user
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · UN "Model Regulation":
*
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. (Contd. on page 7) GB
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Trade name: ASO-R008 (Contd. of page 6)
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3 · DIRECTIVE 2011/65/EU on the restriction of the use of certain hazardous substances in electrical and electronic equipment – Annex II None of the ingredients is listed. · National regulations · Technical instructions (air): · Class Share in % · NK 1.5 · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity - oral – Category 4 Skin Corr. 1A: Skin corrosion/irritation – Category 1A Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
· * Data compared to the previous version altered. GB