54.0
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 01.02.2022 *
Version number 14
Revision: 01.02.2022
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: AQUAFIN-P1 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Reaction resin · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 email: info@schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-770 email: SDB@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Carc. 2 H351 Suspected of causing cancer. STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
Acute Tox. 4 Skin Irrit. 2 Eye Irrit. 2 Skin Sens. 1 STOT SE 3
H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation.
· 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS07, GHS08 · Signal word Danger · Hazard-determining components of labelling: diphenylmethanediisocyanate,isomeres and homologues · Hazard statements H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. (Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 01.02.2022
Trade name: AQUAFIN-P1 (Contd. of page 1)
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure. · Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P284 [In case of inadequate ventilation] wear respiratory protection. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. · Additional information: EUH204 Contains isocyanates. May produce an allergic reaction. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Preparation based on Diphenylmethan-Diisocyanat-Prepolymers. (MDI) · Dangerous components: CAS: 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues 50-100% Index number: 615-005-00-9 Resp. Sens. 1, H334; Carc. 2, H351; STOT RE 2, H373; Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335 Specific concentration limits: Eye Irrit. 2; H319: C ≥ 5 % Skin Irrit. 2; H315: C ≥ 5 % Resp. Sens. 1; H334: C ≥ 0.1 % STOT SE 3; C ≥ 5 % CAS: 78-40-0 triethyl phosphate EINECS: 201-114-5 Acute Tox. 4, H302 Index number: 015-013-00-7 · Additional information For the wording of the listed hazard phrases refer to section 16.
10-25%
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. Do not leave affected persons unsupervised. Instantly remove any clothing soiled by the product. · After inhalation Supply fresh air or oxygen; call for doctor. In case of cardiac- or breath arrest: artificial respiration and cardiac massage. Use a respiration bag or breathing device. · After skin contact Instantly wash with water and soap and rinse thoroughly. Change immediately contaminated clothes. If symptoms appearance, call the doctor. (Contd. on page 3) GB
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Trade name: AQUAFIN-P1 (Contd. of page 2)
· After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. · After swallowing Do not induce vomiting; instantly call for medical help. Show the packaging or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed Allergic reactions Asthma attacks Irritation of skin, eyes and respiratory organ. · 4.3 Indication of any immediate medical attention and special treatment needed The symptoms are to be treated. *
SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. Use fire fighting measures that suit the environment. · 5.2 Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. Wear full protective suit. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan.
SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal.
SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Keep away from children. · Information about protection against explosions and fires: Keep breathing equipment ready. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Store only in the original container. The Product reacts with water and CO2-Gas will be given off. In tight closed containers pressure may arise and the cover can burst. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. (Contd. on page 4) GB
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Trade name: AQUAFIN-P1 (Contd. of page 3)
· Further information about storage conditions: Store under dry conditions. Store container in a well ventilated position. Keep container tightly sealed. Store in a locked cabinet and out of the reach of children. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Components with critical values that require monitoring at the workplace: 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues (50-100%) WEL Short-term value: 0.07 mg/m³ Long-term value: 0.02 mg/m³ Sen; as -NCO · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Be sure to clean skin thoroughly after work and before breaks. When the material is hardened on the skin, remove it carfully mechanically. · Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. Recommended Filter type A · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Penetration time 480 min The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Tightly sealed safety glasses. · Body protection: Protective work clothing.
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Fluid Colour: Brown · Smell: Characteristic · Odour threshold: Not determined. · pH-value:
Mixture is non-soluble (in water). (Contd. on page 5) GB
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Trade name: AQUAFIN-P1 (Contd. of page 4)
· Change in condition Melting point/freezing point: Not determined Initial boiling point and boiling range: >260 °C
· Flash point:
200 °C
· Inflammability (solid, gaseous)
Not applicable.
· Decomposition temperature:
Not determined.
· Self-inflammability:
Product is not selfigniting.
· Explosive properties:
Product is not explosive.
· Critical values for explosion: Lower: Upper:
Not determined. Not determined.
· Steam pressure at 20 °C:
<5 hPa
· Density at 20 °C · Relative density · Vapour density · Evaporation rate
1.14 g/cm³ Not determined. Not determined. Not determined.
· Solubility in / Miscibility with Water:
Not miscible or difficult to mix
· Partition coefficient: n-octanol/water:
· Viscosity: dynamic at 20 °C: kinematic:
230 mPas Not determined.
· 9.2 Other information
No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: Acids Water Alkalis Amine Alkoholes · 10.6 Hazardous decomposition products: No dangerous decomposition products known
SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Harmful if inhaled. · LD/LC50 values that are relevant for classification: 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues Oral LD50 >10,000 mg/kg (rats) (OECD 401) (Contd. on page 6) GB
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Trade name: AQUAFIN-P1 (Contd. of page 5)
Dermal
LD50
>9,400 mg/kg (rabbit) (OECD 402)
78-40-0 triethyl phosphate Oral LD50 800 mg/kg (rats) Dermal LD50 20,000 mg/kg (Kan) Inhalative LC50/4 h 8,817 mg/l (rats) · Primary irritant effect: · Skin corrosion/irritation The product has an irritate-effect. Causes skin irritation. · Serious eye damage/irritation Causes serious eye irritation. · Respiratory or skin sensitisation May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. · Additional toxicological information: · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Suspected of causing cancer. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure May cause respiratory irritation. · STOT-repeated exposure May cause damage to organs through prolonged or repeated exposure. · Aspiration hazard Based on available data, the classification criteria are not met. *
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: LC50/96h >1,000 mg/l (Leuciscus idus) EC50 (48h) >1,000 mg/l (Daphnia magna) IC50 >1,000 mg/l /72h (Scenedesmus subspicatus) 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues EC 50 >1,000 mg/kg (dam) (OECD 202 (24 h)) >1,640 mg/kg (Grünalge (Scenedesmus subspicatus)) (OECD 201) LC50/96h >1,000 mg/l (zebra danio) (OECD 203) EC50 (3h) >100 mg/l (Atmungshem. von kommunalem Belebtschlamm) (OECD 209) ERC50 >1,640 mg/l (Grünalge (Scenedesmus subspicatus)) (OECD 201 (72 h)) NOEC >1,000 mg/kg (Avena sativa) (OECD 208 (14 d)) >1,000 mg/kg (Eisenia fetida) (OECD 207 (14 d)) >1,000 mg/kg (Lactuca sativa) (OECD 208 (14 d)) NOEC >10 mg/l (dam) (OECD 202 (21 d)) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. (Contd. on page 7) GB
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Trade name: AQUAFIN-P1 (Contd. of page 6)
· vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. *
SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information · 14.1 UN-Number · ADR, ADN, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, ADN, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards: · Marine pollutant:
No
· 14.6 Special precautions for user
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · UN "Model Regulation":
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · National regulations · Technical instructions (air): · Class Share in % · I 75.0 NK 21.0 · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. (Contd. on page 8) GB
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Trade name: AQUAFIN-P1 (Contd. of page 7)
· Relevant phrases H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. · Department issuing data specification sheet: Environment protection department. · Contact: Environment protection department. · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity – Category 4 Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Resp. Sens. 1: Respiratory sensitisation – Category 1 Skin Sens. 1: Skin sensitisation – Category 1 Carc. 2: Carcinogenicity – Category 2 STOT SE 3: Specific target organ toxicity (single exposure) – Category 3 STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2
· * Data compared to the previous version altered. GB