57.0.19
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 02.11.2023
Version number 10 (replaces version 9)
Revision: 02.11.2023
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: CRISTALLFUGE braun, grafit, grau, mittelgrau, titangrau · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture grout · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-Mail: SDB@schomburg.de *
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 corrosion Eye Dam. 1 H318 Causes serious eye damage.
Skin Irrit. 2 H315 Causes skin irritation. STOT SE 3 H335 May cause respiratory irritation. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the GB CLP regulation. · Hazard pictograms GHS05, GHS07 · Signal word Danger · Hazard-determining components of labelling: Cement, portland, chemicals · Hazard statements H315 Causes skin irritation. H318 Causes serious eye damage. (Contd. on page 2) GB
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Trade name: CRISTALLFUGE braun, grafit, grau, mittelgrau, titangrau (Contd. of page 1)
H335 May cause respiratory irritation. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280 Wear eye protection / face protection. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Product based on cement and mineral filler. · Dangerous components: CAS: 65997-15-1 Cement, portland, chemicals 25-50% EINECS: 266-043-4 Eye Dam. 1, H318; Skin Irrit. 2, H315; STOT SE 3, H335 · Additional information The chromate content in cement is less than 2 ppm so that the labelling with H317 is not applicable (1907/2006/EG, Annex XVII (47)). For the wording of the listed hazard phrases refer to section 16. *
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact Instantly wash with water and soap and rinse thoroughly. In case of contact with skin, remove mechanically, wash thoroughly with plenty of soap and water. · After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Show the packaging or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. GB
(Contd. on page 3)
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Trade name: CRISTALLFUGE braun, grafit, grau, mittelgrau, titangrau (Contd. of page 2)
*
SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents Product is not inflammable. · 5.2 Special hazards arising from the substance or mixture No further relevant information available. · 5.3 Advice for firefighters · Protective equipment: No special measures required. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan.
SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Avoid causing dust. Avoid eye- and skin contact. Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. · 6.3 Methods and material for containment and cleaning up: Ensure adequate ventilation. Pick up the product mechanically, avoid dust formation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal.
SECTION 7: Handling and storage · 7.1 Precautions for safe handling Prevent formation of dust. Keep away from children. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Protect against wetness and water. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Do not store in the break or recreation room. Keep container tightly sealed. · 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 65997-15-1 Cement, portland, chemicals (25-50%) WEL Long-term value: 10* 4** mg/m³ *inhalable dust **respirable dust (Contd. on page 4) GB
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Trade name: CRISTALLFUGE braun, grafit, grau, mittelgrau, titangrau (Contd. of page 3)
1317-65-3 Calciumcarbonat (25-50%) WEL Long-term value: 10* 4** mg/m³ *inhalable dust; **respirable · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Vacuum clean contaminated clothing. Do not blow or brush off contamination. Avoid contact with the skin. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: Filter P2. In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. · Hand protection Do not reuse one-way-gloves Hand Protection: Nitril-rubber-latex-gloves. In case of wearing synthetic protective gloves use cotton-gloves as underwear. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Penetration time 480 min Gloves made of: Nitrile rubber, butyl rubber. (Category 3 chemical protective gloves, recognisable by the CE mark with four-digit test number). When wearing protective gloves, cotton undergloves are recommended. The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye/face protection Tightly sealed safety glasses. · Body protection: Use an Overall of heavy cotton or non-returnable Tyvek/Saranex 23 P vleece. Contaminated protection clothes must be cleaned carefully before reuse. *
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Solid material. · Colour: Different according to colour · Smell: Light · Odour threshold: Not determined. (Contd. on page 5) GB
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Trade name: CRISTALLFUGE braun, grafit, grau, mittelgrau, titangrau (Contd. of page 4)
· Melting point/freezing point: · Boiling point or initial boiling point and boiling range · Flammability · Lower and upper explosion limit · Lower: · Upper: · Flash point: · Decomposition temperature: · pH at 20 °C · Viscosity: · Kinematic viscosity · dynamic: · Solubility · Water: · Partition coefficient n-octanol/water (log value) · Steam pressure: · Density and/or relative density · Density · Relative density · Settled apparent density · Vapour density
Not determined not apply Not determined. Not determined. Not determined. Not applicable Not determined. 11.4 (1%) Not applicable. Not applicable. miscible Not determined. Not applicable. bulk density Not determined. 1.2 kg/dm³ Not applicable.
· 9.2 Other information · Appearance: · Form: Powder · Important information on protection of health and environment, and on safety. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Solvent content: · Water: 0.0 % · Change in condition · Evaporation rate Not applicable. · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals
Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void (Contd. on page 6) GB
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Trade name: CRISTALLFUGE braun, grafit, grau, mittelgrau, titangrau (Contd. of page 5)
· Desensitised explosives
Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known *
SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 1317-65-3 Calciumcarbonat Oral LD50 >5,000 mg/kg (rats) 554-13-2 lithium carbonate Oral LD50 753 mg/kg (mouse) 525 mg/kg (rats) Dermal LD50 >3,000 mg/kg (Kan) (OECD 402) Inhalative LC50/4 h >2 mg/l (rats) (OECD 403) · Specific symptoms in biological assay: 554-13-2 lithium carbonate NOAEL 45 mg/kg (rats) (OECD 416) · Skin corrosion/irritation The product has an irritate-effect. Causes skin irritation. · Serious eye damage/irritation Causes serious eye damage. · Respiratory or skin sensitisation Sensitive People can get possibly an allergic reaction. · STOT-single exposure May cause respiratory irritation. · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed.
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 1317-65-3 Calciumcarbonat LC50/96h >10,000 mg/l (rainbow trout) EC50 (48h) >1,000 mg/l (Daphnia magna) EC50 289 mg/l /72h (Desmodesmus subspicatus) NOEC 75 mg/l /72h (Desmodesmus subspicatus) 554-13-2 lithium carbonate LC50/96h 30.3 mg/l (rainbow trout) (OECD 203) EC50 (48h) 33.2 mg/l (Daphnia magna) (OECD 202) (Contd. on page 7) GB
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Trade name: CRISTALLFUGE braun, grafit, grau, mittelgrau, titangrau (Contd. of page 6)
EC50 >400 mg/l (algae toxicity) (OECD 201) NOEC 19.1 mg/l /96h (fish toxicity) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Endocrine disrupting properties The product does not contain substances with endocrine disrupting properties. · 12.7 Other adverse effects · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. Rinse off of bigger amounts into drains or the aquatic environment may lead to increased pH-values. A high pH-value harms aquatic organisms. In the dilution of the use-level the pH-value is considerably reduced, so that after the use of the product the aqueous waste, emptied into drains, is only low water-dangerous. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleaning agent: Water, if necessary with cleaning agent. SECTION 14: Transport information · 14.1 UN number or ID number · ADR, ADN, IMDG, IATA
· 14.2 UN proper shipping name · ADR, ADN, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards:
Not applicable.
· 14.6 Special precautions for user
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. · UN "Model Regulation":
Void GB
(Contd. on page 8)
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Trade name: CRISTALLFUGE braun, grafit, grau, mittelgrau, titangrau (Contd. of page 7)
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H315 Causes skin irritation. H318 Causes serious eye damage. H335 May cause respiratory irritation. · Department issuing data specification sheet: Environment protection department. · Contact: Environment protection department. · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Dam. 1: Serious eye damage/eye irritation – Category 1 STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
· * Data compared to the previous version altered. GB